File name: Pandora283s1_LaPaz_20241120_L2Fit_fout2c4d20241004p1-8.txt File generation date: 20250624T082219.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 283 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora283_OF_v3d20231025.txt Instrument calibration file used: Pandora283s1_CF_v4d20241004.txt Level 1 file used: Pandora283s1_LaPaz_20241120_L1_smca1c4d20241004p1-8.txt Full location name: Laboratory for Atmospheric Physics, UMSA, La Paz Short location name: LaPaz Country of location: Bolivia Location latitude [deg]: -16.5389 Location longitude [deg]: -68.0661 Location altitude [m]: 3420 Local noon date: 20241120 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 203 345 Nominal wavelengths inside fitting window [nm]: 305.0638 305.2044 305.3451 305.4858 305.6264 305.7671 305.9077 306.0483 306.1889 306.3295 306.4701 306.6107 306.7513 306.8918 307.0324 307.1729 307.3134 307.4539 307.5944 307.7349 307.8754 308.0158 308.1563 308.2967 308.4371 308.5776 308.7180 308.8584 308.9988 309.1391 309.2795 309.4198 309.5602 309.7005 309.8408 309.9811 310.1214 310.2617 310.4020 310.5422 310.6825 310.8227 310.9630 311.1032 311.2434 311.3836 311.5237 311.6639 311.8041 311.9442 312.0844 312.2245 312.3646 312.5047 312.6448 312.7849 312.9249 313.0650 313.2050 313.3451 313.4851 313.6251 313.7651 313.9051 314.0451 314.1851 314.3250 314.4650 314.6049 314.7448 314.8847 315.0246 315.1645 315.3044 315.4442 315.5841 315.7239 315.8638 316.0036 316.1434 316.2832 316.4230 316.5627 316.7025 316.8423 316.9820 317.1217 317.2614 317.4011 317.5408 317.6805 317.8202 317.9598 318.0995 318.2391 318.3787 318.5184 318.6580 318.7976 318.9371 319.0767 319.2163 319.3558 319.4953 319.6348 319.7744 319.9139 320.0533 320.1928 320.3323 320.4717 320.6112 320.7506 320.8900 321.0294 321.1688 321.3082 321.4476 321.5869 321.7263 321.8656 322.0049 322.1442 322.2835 322.4228 322.5621 322.7014 322.8406 322.9799 323.1191 323.2583 323.3975 323.5367 323.6759 323.8151 323.9543 324.0934 324.2325 324.3717 324.5108 324.6499 324.7890 324.9281 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241120T131704.1Z 9090.553520 329 1 54.02 2 42.98 101.62 79.21 300.50 0.00 1 0.00 1 0 17 6.113e-02 7.134e-02 2.813e-03 2.000e-03 1.915325e-01 1.002471e-03 2.123268e-03 -6.000000e+00 3.402389e-02 226.23 -2.00 3.03 -2.00 314.68 0.00e+00 4.209863e-03 7.976937e-05 2.688401e-04 -6.000000e+00 1.458203e-03 274.41 -2.00 20.00 -2.00 314.25 0.00e+00 1.365 0.000 302.00 328.00 3 6.4809e+00 2.5514e-03 1.2955e-02 -6.0000e+00 8.4537e-02 2.0267e-01 2.8336e-03 1.0537e-02 -6.0000e+00 9.2036e-02 -4.0019e-02 1.6318e-03 4.4340e-03 -6.0000e+00 5.4596e-02 -2.3068e-02 7.2413e-04 3.2801e-03 -6.0000e+00 2.3313e-02 2.4592e-04 4.4392e-04 5.3232e-05 2.3535e-05 -6.0000e+00 1.5489e-03 -4.2938e-04 0.0000e+00 12 9 8 11 8 0 99.90 24.43 -0.44 -0.00043 0.00291 17 2 1 5 0 3176.930 33.25 20.07 24.43 24.09 3.5 924.93 -106 -468 5583 -1179 -3966 -2260 -3594 -5689 -3983 -6821 -9641 -8196 -4384 -2147 2961 4204 3554 3642 4701 4822 7187 3923 3728 2311 1048 -759 -1723 -3203 -267 3272 3118 5170 6566 5858 1796 111 1927 3076 1839 2591 725 55 1595 2402 2023 3352 4110 3438 4403 4136 5636 4898 -62499 5863 4867 3066 4101 2702 2060 1838 3994 3744 3506 5607 3132 2741 1963 2073 3424 4176 3683 2643 2331 1986 1399 13 -285 -1573 298 1557 68 1403 1276 240 739 169 1296 1227 797 1773 193 -421 -863 -1454 995 417 1663 2007 1324 663 729 -1257 -2259 -2015 -1045 -1842 -2158 -1531 -1350 64 509 132 224 -444 -746 -792 -556 -69 -446 -110 -362 -884 -1239 -1104 -1343 -1499 -1575 77 529 949 344 523 575 1279 1201 843 873 597 986 457 -485 -446 -708 -39 -170 2100 -436 -1308 -680 -1128 -2012 -1509 -2706 -3754 -3158 -1826 -925 1380 2103 1834 1921 2526 2660 3918 2145 2024 1304 570 -429 -967 -1850 -140 1605 1605 2800 3768 3440 1004 60 1102 1859 1337 1991 610 45 1316 1981 1669 2925 3469 2814 3435 3183 4435 4128 -79558 5305 4208 2711 3616 2387 1786 1585 3472 3499 3552 5522 3134 2663 1730 1856 3179 4077 3696 2783 2451 2018 1422 12 -251 -1301 249 1438 67 1483 1338 263 858 200 1595 1560 1018 2164 234 -463 -911 -1460 1017 441 1916 2391 1691 841 861 -1464 -2494 -2287 -1281 -2268 -2771 -2028 -1857 87 720 189 306 -597 -911 -954 -659 -85 -555 -147 -501 -1220 -1667 -1423 -1743 -1853 -1828 87 627 1199 431 666 736 1679 1670 1173 1248 875 1457 667 -691 -611 -1002 SS 20241120T132949.9Z 9090.562383 338 1 2.46 2 39.99 101.41 81.77 299.33 0.00 1 0.00 1 0 17 9.429e-03 7.817e-03 3.226e-03 2.618e-03 1.516045e-01 1.324380e-03 1.582931e-03 -6.000000e+00 5.256095e-03 226.23 -2.00 3.03 -2.00 313.92 0.00e+00 3.771884e-04 9.161307e-05 9.726425e-06 -6.000000e+00 2.248147e-04 274.41 -2.00 20.00 -2.00 313.54 0.00e+00 1.304 0.000 302.00 328.00 3 4.0590e+00 3.3585e-03 1.0915e-02 -6.0000e+00 1.3061e-02 2.6782e-02 3.7214e-03 6.5824e-03 -6.0000e+00 1.4210e-02 -1.7422e-04 2.1405e-03 3.2381e-03 -6.0000e+00 8.4295e-03 -4.5253e-03 9.2993e-04 9.4129e-04 -6.0000e+00 3.6073e-03 3.3429e-03 1.4620e-03 6.8982e-05 1.1577e-05 -6.0000e+00 2.3869e-04 -1.3358e-02 0.0000e+00 12 9 1 12 1 1 63.43 24.48 0.24 -0.01336 -0.00237 3 9 1 5 0 613.630 33.50 20.03 24.48 24.89 3.4 929.72 -610 412 -322 -1539 -2750 -1441 -439 412 1655 -457 -1297 -1048 -976 471 605 255 -225 909 735 1229 2162 494 1879 835 599 1171 255 -611 -1209 106 504 2016 1626 -616 -2484 -2956 -1527 -1755 -245 -861 -812 -658 -235 -263 -743 -280 -512 -892 -866 -364 533 511 1567 1544 551 941 793 387 945 438 626 993 1528 2025 823 -251 -673 -1253 41 495 -151 216 792 521 286 -288 -975 -1619 -1179 -1180 -1489 -1647 -1992 -1534 -1298 -562 -40 303 834 940 738 -163 -179 -537 340 -67 72 1008 705 77 -318 -767 -852 -448 -311 -672 -867 -583 -194 684 597 813 525 379 -136 -55 -202 220 408 385 205 371 -56 706 459 225 -240 372 183 367 -229 146 -557 -94 -82 -264 260 68 325 -10 -200 -644 -597 -288 196 -154 -722 -1194 -610 -192 190 796 -232 -637 -505 -486 259 353 153 -137 555 461 754 1337 304 1142 535 386 774 168 -393 -748 65 299 1245 1028 -406 -1597 -1821 -998 -1229 -187 -711 -701 -587 -206 -231 -651 -252 -447 -774 -719 -306 442 450 1382 1418 504 867 743 362 860 397 581 948 1514 2107 832 -248 -617 -1130 38 489 -155 231 843 540 288 -279 -873 -1391 -1023 -1101 -1458 -1714 -2140 -1703 -1488 -650 -49 372 1022 1147 859 -184 -185 -541 352 -71 81 1211 857 95 -383 -873 -942 -510 -364 -817 -1070 -745 -249 895 818 1092 694 488 -164 -65 -234 264 497 493 267 481 -73 900 570 266 -276 428 216 446 -285 184 -708 -119 -107 -355 359 95 452 -15 -273 -878 -791 SS 20241120T133746.6Z 9090.567900 344 1 54.37 2 38.12 101.31 83.37 298.64 0.00 1 0.00 1 0 17 9.231e-03 7.329e-03 1.191e-03 9.307e-04 1.489237e-01 4.695758e-04 1.581150e-03 -6.000000e+00 5.140434e-03 226.23 -2.00 3.03 -2.00 314.17 0.00e+00 4.695066e-04 3.381777e-05 1.446047e-05 -6.000000e+00 2.201851e-04 274.41 -2.00 20.00 -2.00 313.77 0.00e+00 1.270 0.000 302.00 328.00 3 5.3088e+00 1.1938e-03 1.0708e-02 -6.0000e+00 1.2772e-02 3.6626e-02 1.3238e-03 6.5449e-03 -6.0000e+00 1.3903e-02 -2.2568e-03 7.5976e-04 3.2234e-03 -6.0000e+00 8.2471e-03 -2.7431e-03 3.3233e-04 9.5645e-04 -6.0000e+00 3.5239e-03 9.8213e-04 2.8113e-04 2.4704e-05 1.1599e-05 -6.0000e+00 2.3383e-04 -4.2232e-03 0.0000e+00 11 9 0 11 8 0 99.99 24.51 0.20 -0.00422 -0.00211 91 9 1 5 0 597.360 33.50 19.98 24.51 25.07 3.4 930.31 253 -177 1080 -1160 -3352 -2130 -653 -69 1369 273 -1930 -1789 -434 -229 1036 431 512 412 778 1103 1885 336 1005 1234 1111 929 357 -683 -744 62 726 980 938 -349 -2846 -3263 -2118 -1067 -763 -201 -786 -648 -632 -209 -573 -224 -200 -675 -544 -446 302 487 832 880 867 623 1154 408 318 140 909 1007 1509 1744 604 -312 -845 -870 118 724 425 447 482 645 418 -149 -743 -1417 -1409 -794 -1530 -1287 -1552 -1673 -932 -668 49 443 769 857 663 215 -90 -400 288 -155 506 895 540 -125 -241 -696 -1226 -932 -627 -753 -965 -561 -243 583 609 567 364 190 -120 -119 -244 50 42 403 207 134 386 559 414 424 208 571 473 424 53 -22 -288 95 150 88 60 231 265 -210 -513 -613 -826 113 -79 476 -516 -1320 -836 -244 -29 626 121 -901 -821 -198 -117 543 243 293 238 460 667 1150 204 605 773 684 590 225 -431 -429 36 430 571 583 -223 -1713 -1879 -1298 -707 -568 -163 -692 -558 -556 -184 -501 -194 -177 -574 -442 -354 246 421 751 781 785 572 1069 379 288 126 833 984 1502 1827 634 -299 -767 -788 111 728 447 467 506 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