File name: Pandora283s1_LaPaz_20241123_L2Fit_fout2c4d20241004p1-8.txt File generation date: 20250624T082332.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 283 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora283_OF_v3d20231025.txt Instrument calibration file used: Pandora283s1_CF_v4d20241004.txt Level 1 file used: Pandora283s1_LaPaz_20241123_L1_smca1c4d20241004p1-8.txt Full location name: Laboratory for Atmospheric Physics, UMSA, La Paz Short location name: LaPaz Country of location: Bolivia Location latitude [deg]: -16.5389 Location longitude [deg]: -68.0661 Location altitude [m]: 3420 Local noon date: 20241123 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 203 345 Nominal wavelengths inside fitting window [nm]: 305.0638 305.2044 305.3451 305.4858 305.6264 305.7671 305.9077 306.0483 306.1889 306.3295 306.4701 306.6107 306.7513 306.8918 307.0324 307.1729 307.3134 307.4539 307.5944 307.7349 307.8754 308.0158 308.1563 308.2967 308.4371 308.5776 308.7180 308.8584 308.9988 309.1391 309.2795 309.4198 309.5602 309.7005 309.8408 309.9811 310.1214 310.2617 310.4020 310.5422 310.6825 310.8227 310.9630 311.1032 311.2434 311.3836 311.5237 311.6639 311.8041 311.9442 312.0844 312.2245 312.3646 312.5047 312.6448 312.7849 312.9249 313.0650 313.2050 313.3451 313.4851 313.6251 313.7651 313.9051 314.0451 314.1851 314.3250 314.4650 314.6049 314.7448 314.8847 315.0246 315.1645 315.3044 315.4442 315.5841 315.7239 315.8638 316.0036 316.1434 316.2832 316.4230 316.5627 316.7025 316.8423 316.9820 317.1217 317.2614 317.4011 317.5408 317.6805 317.8202 317.9598 318.0995 318.2391 318.3787 318.5184 318.6580 318.7976 318.9371 319.0767 319.2163 319.3558 319.4953 319.6348 319.7744 319.9139 320.0533 320.1928 320.3323 320.4717 320.6112 320.7506 320.8900 321.0294 321.1688 321.3082 321.4476 321.5869 321.7263 321.8656 322.0049 322.1442 322.2835 322.4228 322.5621 322.7014 322.8406 322.9799 323.1191 323.2583 323.3975 323.5367 323.6759 323.8151 323.9543 324.0934 324.2325 324.3717 324.5108 324.6499 324.7890 324.9281 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20241123T123053.5Z 9093.521453 891 1 54.86 2 53.92 103.63 36.51 318.98 0.00 1 0.00 1 0 17 4.367e-02 4.410e-02 2.197e-03 1.422e-03 2.053355e-01 7.113644e-04 2.218721e-03 -6.000000e+00 2.429686e-02 226.08 -2.00 3.03 -2.00 315.15 0.00e+00 2.802809e-03 6.177039e-05 1.619069e-04 -6.000000e+00 1.041903e-03 274.46 -2.00 20.00 -2.00 314.68 0.00e+00 1.694 0.000 302.00 328.00 3 5.7257e+00 1.8194e-03 1.4657e-02 -6.0000e+00 6.0349e-02 9.1851e-02 2.0268e-03 9.8995e-03 -6.0000e+00 6.5704e-02 -2.0347e-02 1.1660e-03 4.5898e-03 -6.0000e+00 3.8981e-02 -1.4610e-02 5.2530e-04 2.3987e-03 -6.0000e+00 1.6655e-02 4.2618e-04 3.0536e-04 3.7932e-05 2.0070e-05 -6.0000e+00 1.1064e-03 -1.6439e-03 0.0000e+00 12 9 8 11 8 0 99.63 24.39 -0.00 -0.00164 0.00065 19 2 1 5 0 2887.190 33.25 20.12 24.39 22.92 3.7 916.98 209 -559 4342 -1665 -3635 -1361 -2739 -3706 -1324 -4638 -6985 -6002 -1584 -2126 2674 2690 1819 3160 2862 2819 5048 2282 2310 1623 1050 -115 -1438 -1624 -788 1863 2368 3331 4218 3854 -113 -955 859 1434 415 983 200 -606 318 1464 853 1904 2364 1422 2498 2599 3459 2855 -45698 3789 3182 1689 2002 1162 1462 915 2550 2411 2679 3962 2328 1371 836 1271 1978 2581 2185 1653 1573 1290 1060 -3 -249 -1454 -284 522 -236 104 -221 -847 -387 -127 598 887 928 1280 493 -67 -386 -806 415 452 1144 1611 1210 206 -30 -845 -1584 -1103 -866 -1421 -1678 -998 -736 297 269 314 264 -55 -680 -586 -162 36 44 6 -476 -686 -326 -516 -488 -667 -959 21 465 540 560 -51 107 351 827 497 566 699 577 322 -262 -589 -693 61 -180 1349 -508 -984 -367 -778 -1088 -418 -1557 -2309 -1975 -559 -803 1097 1203 844 1485 1393 1415 2519 1143 1155 786 533 -61 -760 -806 -388 868 1152 1729 2175 2039 -57 -501 443 856 279 713 149 -472 252 1157 676 1494 1803 1124 1889 1940 2668 2227 -49226 3205 2761 1503 1799 1044 1279 798 2253 2162 2599 3822 2274 1301 763 1101 1793 2501 2206 1748 1663 1320 1072 -3 -216 -1260 -235 482 -233 107 -242 -917 -444 -149 738 1076 1128 1571 593 -73 -400 -840 423 505 1336 1972 1517 258 -37 -1002 -1774 -1266 -1032 -1806 -2126 -1307 -1002 405 387 458 369 -74 -883 -706 -202 44 58 8 -672 -964 -443 -676 -634 -827 -1175 26 588 698 724 -68 143 483 1150 733 857 1036 868 477 -394 -854 -979 SU 20241123T123300.7Z 9093.522924 894 1 55.53 2 53.43 103.57 36.84 318.31 0.00 1 0.00 1 0 17 4.220e-02 4.311e-02 2.186e-03 1.432e-03 2.040458e-01 7.155258e-04 2.193987e-03 -6.000000e+00 2.347902e-02 226.08 -2.00 3.03 -2.00 315.11 0.00e+00 2.825020e-03 6.174604e-05 1.511178e-04 -6.000000e+00 1.006800e-03 274.46 -2.00 20.00 -2.00 314.64 0.00e+00 1.674 0.000 302.00 328.00 3 5.7605e+00 1.8299e-03 1.4514e-02 -6.0000e+00 5.8317e-02 9.8875e-02 2.0374e-03 9.8401e-03 -6.0000e+00 6.3492e-02 -2.0755e-02 1.1711e-03 4.5427e-03 -6.0000e+00 3.7669e-02 -1.4810e-02 5.2741e-04 2.3812e-03 -6.0000e+00 1.6094e-02 4.1681e-04 3.9157e-04 3.8243e-05 1.9261e-05 -6.0000e+00 1.0691e-03 -1.8642e-03 0.0000e+00 12 8 8 10 0 0 99.72 24.40 0.12 -0.00186 0.00108 19 2 1 5 0 2922.420 33.25 19.95 24.40 23.06 3.7 918.30 1677 72 4558 -1361 -3694 -4032 -3003 -3315 -1365 -5212 -6360 -5949 -2436 -2367 1805 2970 2147 3176 2531 3128 5198 2574 2431 1849 911 -135 -1252 -1843 -908 1641 2259 3121 4015 3346 -19 -1020 858 1547 446 1237 233 -479 717 928 935 1956 2285 1426 2065 2621 3433 3053 -43613 3792 3048 1741 2652 1066 1495 955 2537 2666 3027 3951 2360 1360 915 987 2152 2420 2234 1833 1386 1198 968 -41 -331 -1074 -532 173 -412 189 -134 -734 -379 -234 567 649 751 1001 484 18 -643 -987 207 445 1172 1690 1122 285 212 -958 -1344 -1290 -931 -1290 -1548 -910 -634 185 354 429 222 -249 -608 -636 -258 -19 112 118 -306 -420 -310 -608 -344 -616 -913 68 270 520 288 232 250 368 746 511 550 470 607 297 -365 -461 -812 492 23 1427 -417 -1101 -1125 -863 -978 -435 -1773 -2104 -1970 -872 -976 751 1330 997 1498 1241 1571 2598 1289 1218 965 464 -71 -662 -917 -448 767 1100 1624 2073 1777 -10 -535 442 921 300 893 184 -372 564 734 737 1528 1845 1122 1560 1945 2634 2511 -48012 3186 2630 1537 2350 951 1298 826 2224 2366 2903 3990 2284 1278 826 849 1928 2325 2230 1914 1452 1213 969 -39 -283 -916 -464 158 -402 191 -144 -825 -430 -271 690 816 945 1214 574 21 -658 -1014 220 491 1347 2034 1451 367 255 -1118 -1554 -1459 -1146 -1611 -2017 -1170 -847 260 500 612 304 -333 -774 -789 -315 -24 145 157 -423 -576 -413 -819 -438 -785 -1096 79 335 657 383 315 342 496 1061 737 815 713 931 449 -537 -654 -1174 SU 20241123T123534.0Z 9093.524700 897 1 53.70 2 52.83 103.50 37.24 317.53 0.00 1 0.00 1 0 17 3.526e-02 3.478e-02 1.909e-03 1.285e-03 1.976082e-01 6.434823e-04 2.113955e-03 -6.000000e+00 1.962086e-02 226.08 -2.00 3.03 -2.00 314.99 0.00e+00 2.254087e-03 5.413920e-05 1.152643e-04 -6.000000e+00 8.413471e-04 274.46 -2.00 20.00 -2.00 314.53 0.00e+00 1.651 0.000 302.00 328.00 3 5.5755e+00 1.6424e-03 1.4153e-02 -6.0000e+00 4.8734e-02 7.1240e-02 1.8275e-03 9.2653e-03 -6.0000e+00 5.3058e-02 -1.4746e-02 1.0509e-03 4.3566e-03 -6.0000e+00 3.1479e-02 -1.1721e-02 4.7071e-04 2.0043e-03 -6.0000e+00 1.3450e-02 5.2100e-04 3.3342e-04 3.4220e-05 1.7476e-05 -6.0000e+00 8.9337e-04 -1.9627e-03 0.0000e+00 12 8 8 10 0 0 97.60 24.41 0.22 -0.00196 0.00054 19 2 1 5 0 2826.140 33.25 19.95 24.41 23.20 3.7 920.57 1621 -574 3402 -1758 -4535 -1366 -2401 -2934 -359 -3745 -5733 -4640 -2039 -1345 1822 2149 1446 2308 2254 2561 4211 1909 2050 1837 1021 -1 -1002 -983 -962 1693 2121 2701 3198 2633 -953 -1670 -91 553 254 711 415 -618 300 646 374 1391 1860 1205 1670 1678 2288 2517 -36561 3392 2573 1525 2305 1101 1027 891 2184 2228 2509 3255 1818 902 487 422 1628 2159 1838 1653 1347 1202 660 -147 -419 -1234 -784 5 -663 -110 -615 -1134 -484 -324 414 614 918 1029 480 135 -421 -646 230 96 845 1561 891 153 11 -839 -1481 -1185 -968 -1268 -1221 -896 -607 351 368 525 224 -83 -395 -566 -67 48 -6 330 -65 -211 -181 -377 -310 -663 -473 174 439 643 251 65 -77 199 719 382 284 651 423 108 -474 -433 -676 522 -189 1180 -592 -1367 -373 -690 -949 -125 -1283 -2087 -1675 -738 -554 827 981 682 1105 1115 1302 2140 970 1040 971 530 0 -540 -530 -480 798 1040 1416 1797 1419 -523 -884 -51 336 174 527 315 -492 243 525 303 1117 1450 966 1286 1276 1801 1993 -38509 2915 2274 1305 1984 952 916 789 1964 2035 2353 3218 1814 871 426 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