File name: Pandora283s1_LaPaz_20241202_L2Fit_fout2c4d20241004p1-8.txt File generation date: 20250624T082617.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 283 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora283_OF_v3d20231025.txt Instrument calibration file used: Pandora283s1_CF_v4d20241004.txt Level 1 file used: Pandora283s1_LaPaz_20241202_L1_smca1c4d20241004p1-8.txt Full location name: Laboratory for Atmospheric Physics, UMSA, La Paz Short location name: LaPaz Country of location: Bolivia Location latitude [deg]: -16.5389 Location longitude [deg]: -68.0661 Location altitude [m]: 3420 Local noon date: 20241202 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 203 345 Nominal wavelengths inside fitting window [nm]: 305.0638 305.2044 305.3451 305.4858 305.6264 305.7671 305.9077 306.0483 306.1889 306.3295 306.4701 306.6107 306.7513 306.8918 307.0324 307.1729 307.3134 307.4539 307.5944 307.7349 307.8754 308.0158 308.1563 308.2967 308.4371 308.5776 308.7180 308.8584 308.9988 309.1391 309.2795 309.4198 309.5602 309.7005 309.8408 309.9811 310.1214 310.2617 310.4020 310.5422 310.6825 310.8227 310.9630 311.1032 311.2434 311.3836 311.5237 311.6639 311.8041 311.9442 312.0844 312.2245 312.3646 312.5047 312.6448 312.7849 312.9249 313.0650 313.2050 313.3451 313.4851 313.6251 313.7651 313.9051 314.0451 314.1851 314.3250 314.4650 314.6049 314.7448 314.8847 315.0246 315.1645 315.3044 315.4442 315.5841 315.7239 315.8638 316.0036 316.1434 316.2832 316.4230 316.5627 316.7025 316.8423 316.9820 317.1217 317.2614 317.4011 317.5408 317.6805 317.8202 317.9598 318.0995 318.2391 318.3787 318.5184 318.6580 318.7976 318.9371 319.0767 319.2163 319.3558 319.4953 319.6348 319.7744 319.9139 320.0533 320.1928 320.3323 320.4717 320.6112 320.7506 320.8900 321.0294 321.1688 321.3082 321.4476 321.5869 321.7263 321.8656 322.0049 322.1442 322.2835 322.4228 322.5621 322.7014 322.8406 322.9799 323.1191 323.2583 323.3975 323.5367 323.6759 323.8151 323.9543 324.0934 324.2325 324.3717 324.5108 324.6499 324.7890 324.9281 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241202T104404.5Z 9102.447274 57 1 54.95 2 78.88 109.93 90.80 119.58 0.00 1 0.00 1 0 17 3.101e-01 1.646e-02 9.408e-02 2.403e-03 5.401914e-01 1.198473e-03 5.420073e-03 -6.000000e+00 1.722626e-01 225.65 -2.00 3.03 -2.00 319.61 0.00e+00 2.741682e-03 3.401706e-04 4.488938e-04 -6.000000e+00 7.403204e-03 274.60 -2.00 20.00 -2.00 319.09 0.00e+00 5.017 0.000 302.00 328.00 3 4.0687e+00 3.3658e-03 4.0993e-02 -6.0000e+00 4.2742e-01 1.5685e-02 3.9913e-03 2.3939e-02 -6.0000e+00 4.6548e-01 -6.9584e-02 3.4332e-03 1.2515e-02 -6.0000e+00 2.7628e-01 3.0861e-02 1.8167e-03 4.7760e-03 -6.0000e+00 1.1817e-01 1.6905e-04 -1.6329e-04 6.3024e-05 4.4243e-05 -6.0000e+00 7.8558e-03 -1.7102e-03 0.0000e+00 12 8 8 10 0 0 96.48 24.30 0.24 -0.00171 -0.00294 37 4 1 5 0 1484.900 33.25 19.89 24.30 19.17 3.5 886.09 -13363 -109778 256489 -56485 -127526 -86400 -54901 -69839 -33360 10019 -45406 -51954 -6764 -60325 -1640 -4960 -12254 -19658 -16687 -22053 36425 -14551 -14647 5297 1884 2059 -8285 -15075 -9987 2870 -19804 -3830 -11568 10080 -11066 -14427 1327 8004 -3338 49 -3306 -5177 1396 6858 1244 4256 7291 -2362 84 -2381 3301 2266 57857 4899 4390 -2201 3770 307 815 -782 4553 1548 600 5164 200 676 165 -55 -221 692 445 461 -1 -140 331 -176 230 -2821 -2309 -990 -2793 -684 -585 -2867 -1774 -2605 347 -163 399 1158 1095 1207 -223 -1028 466 -699 348 143 -246 -381 -164 -850 -1740 -1171 -580 -1347 -901 -245 -1046 472 577 877 1200 234 -124 -219 -452 249 -133 224 419 351 610 499 486 493 97 1372 1035 578 164 17 -287 51 429 -311 -70 241 205 -118 -804 -622 -774 -150 -3755 601 -1165 -4811 -2085 -1042 -1767 -664 139 -1117 -1497 -154 -2968 -56 -206 -606 -1142 -1013 -1488 1408 -927 -964 310 124 142 -643 -1204 -735 194 -1954 -380 -1431 1075 -1379 -1805 155 1041 -599 9 -722 -1233 327 1554 301 1020 1716 -624 22 -678 975 753 13218 1865 1768 -900 1632 126 352 -336 1908 671 297 2733 117 377 88 -30 -131 434 310 336 -1 -97 209 -108 130 -1611 -1434 -660 -2206 -558 -521 -2751 -1675 -2656 363 -177 432 1200 1057 1153 -203 -942 462 -751 397 187 -331 -518 -208 -1036 -1945 -1309 -700 -1740 -1141 -327 -1516 705 897 1432 1944 366 -191 -319 -658 375 -214 360 676 548 965 765 713 734 138 1952 1550 924 287 29 -523 98 829 -612 -141 490 420 -236 -1596 -1160 -1456 SS 20241202T105410.7Z 9102.454290 63 1 11.12 2 76.60 109.39 88.76 118.91 0.00 1 0.00 1 0 25 3.601e-01 1.141e-01 8.449e-02 5.953e-03 4.836583e-01 2.939191e-03 5.448276e-03 -6.000000e+00 1.996174e-01 225.65 -2.00 3.03 -2.00 318.81 0.00e+00 4.146062e-02 6.491327e-04 2.189855e-03 -6.000000e+00 8.591185e-03 274.60 -2.00 20.00 -2.00 318.27 0.00e+00 4.219 0.000 302.00 328.00 3 4.2729e+00 7.8724e-03 4.5820e-02 -6.0000e+00 4.9528e-01 5.6457e-01 8.9564e-03 5.8072e-02 -6.0000e+00 5.3977e-01 -3.8346e-01 6.9300e-03 2.6001e-02 -6.0000e+00 3.2036e-01 9.6784e-02 3.8025e-03 3.7291e-02 -6.0000e+00 1.3672e-01 1.7505e-04 -3.5003e-03 1.4752e-04 2.7283e-04 -6.0000e+00 9.1294e-03 1.2263e-02 0.0000e+00 12 9 9 12 9 1 -283.25 24.32 0.11 0.01226 -0.01404 3 2 1 5 0 2779.720 33.25 20.02 24.32 19.63 3.5 890.61 137650 65647 224111 70575 54777 64132 47294 27606 5054 16609 -17619 -18120 17619 27788 75834 74904 80259 74956 69507 72648 90034 60405 47433 26105 7975 -1086 -10844 -5535 15402 33715 27616 51375 37794 57171 44010 36449 31726 32544 15399 9122 1983 -5619 4805 9488 19210 29096 32441 31169 34713 32492 28594 28645 -106111 23640 15630 6390 1859 -4730 -2557 2534 9709 13901 13742 18662 18473 18120 17621 13595 11538 9809 8993 6959 2877 3530 1185 1145 1841 -994 2796 6536 5552 5817 4667 1037 128 -1503 794 125 1770 2883 1577 422 -2307 -3993 -1971 -1931 1409 2819 3796 5592 5138 2764 -1410 -1923 -2197 -3901 -4765 -2160 -2266 -1659 -999 -438 44 -873 -1768 -2250 -2309 -1239 -1295 -678 -655 -1523 -1355 -1070 -1502 -1409 -739 -269 -69 1036 1004 1833 1513 1435 1370 -481 59 133 1156 1255 -530 537 -1011 2078 2515 1951 2786 2194 1973 1455 913 191 501 -685 -789 777 1678 3962 5000 5870 6440 6819 7169 7422 6172 4901 2879 917 -127 -1379 -694 1726 3699 4088 7456 7306 9658 7818 6432 5986 6612 3722 2542 621 -1987 1656 3395 6701 9934 11351 11531 12695 12397 11011 11903 -119158 11230 7954 3410 996 -2597 -1340 1293 4988 7754 8137 11858 12423 11716 10701 8323 7553 6870 6913 5601 2356 2694 846 785 1143 -626 1871 5017 4648 5067 4406 1047 128 -1621 882 144 2026 3171 1631 428 -2197 -3774 -1989 -2113 1628 3689 5128 7502 6477 3365 -1701 -2297 -2655 -5080 -6173 -2884 -3250 -2467 -1532 -699 69 -1374 -2601 -3302 -3373 -1778 -1985 -1042 -1015 -2433 -2075 -1575 -2237 -2013 -997 -363 -103 1625 1628 3100 2642 2492 2524 -909 113 260 2258 2394 -976 968 -1770 SS 20241202T105851.6Z 9102.457542 66 1 54.44 2 75.54 109.15 87.81 118.62 0.00 1 0.00 1 0 17 3.915e-02 7.059e-03 2.113e-03 4.012e-04 4.337379e-01 1.980905e-04 4.434650e-03 -6.000000e+00 2.174721e-02 225.65 -2.00 3.03 -2.00 318.03 0.00e+00 1.219205e-03 3.440211e-05 2.297197e-04 -6.000000e+00 9.345597e-04 274.60 -2.00 20.00 -2.00 317.46 0.00e+00 3.928 0.000 302.00 328.00 3 1.5426e+00 5.2741e-04 3.2283e-02 -6.0000e+00 5.3960e-02 -1.6925e-02 5.9636e-04 1.8937e-02 -6.0000e+00 5.8764e-02 -1.1233e-02 3.9419e-04 9.4788e-03 -6.0000e+00 3.4878e-02 2.4229e-03 2.0734e-04 2.9622e-03 -6.0000e+00 1.4919e-02 4.8325e-03 1.8861e-04 1.0580e-05 2.8774e-05 -6.0000e+00 9.9168e-04 -2.1232e-03 0.0000e+00 11 8 0 10 0 0 86.83 24.33 0.29 -0.00212 -0.00071 530 54 1 5 0 102.700 33.25 19.85 24.33 20.01 3.5 894.46 -13228 -11043 -5906 -11947 -17095 -18262 -14838 -11316 -9860 -8332 -11818 -11366 -7130 -4959 -2136 -479 -109 318 974 1595 2314 223 1092 1242 688 768 364 -1481 -2077 -558 239 1516 1549 210 -2797 -3928 -2722 -1557 -408 190 -262 -232 130 225 566 523 376 262 -249 80 1165 1244 900 1491 1343 1159 914 552 226 -12 674 1456 2011 2226 1056 225 -362 -625 50 679 633 509 253 335 40 -528 -1079 -1790 -1661 -1290 -1297 -1351 -1887 -1998 -1272 -577 -101 299 765 866 693 351 -187 -347 -57 -204 263 716 522 -150 -588 -979 -1231 -789 -777 -1009 -904 -481 -34 504 674 718 442 218 -143 45 5 295 314 320 49 226 513 641 450 309 134 554 578 360 137 12 -326 -133 -119 -65 27 249 158 -179 -419 -487 -648 -722 -671 -358 -732 -987 -1027 -871 -739 -721 -640 -948 -969 -633 -527 -266 -67 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