File name: Pandora283s1_LaPaz_20241226_L2Fit_fout2c4d20241004p1-8.txt File generation date: 20250624T082602.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 283 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora283_OF_v3d20231025.txt Instrument calibration file used: Pandora283s1_CF_v4d20241004.txt Level 1 file used: Pandora283s1_LaPaz_20241226_L1_smca1c4d20241004p1-8.txt Full location name: Laboratory for Atmospheric Physics, UMSA, La Paz Short location name: LaPaz Country of location: Bolivia Location latitude [deg]: -16.5389 Location longitude [deg]: -68.0661 Location altitude [m]: 3420 Local noon date: 20241226 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 203 345 Nominal wavelengths inside fitting window [nm]: 305.0638 305.2044 305.3451 305.4858 305.6264 305.7671 305.9077 306.0483 306.1889 306.3295 306.4701 306.6107 306.7513 306.8918 307.0324 307.1729 307.3134 307.4539 307.5944 307.7349 307.8754 308.0158 308.1563 308.2967 308.4371 308.5776 308.7180 308.8584 308.9988 309.1391 309.2795 309.4198 309.5602 309.7005 309.8408 309.9811 310.1214 310.2617 310.4020 310.5422 310.6825 310.8227 310.9630 311.1032 311.2434 311.3836 311.5237 311.6639 311.8041 311.9442 312.0844 312.2245 312.3646 312.5047 312.6448 312.7849 312.9249 313.0650 313.2050 313.3451 313.4851 313.6251 313.7651 313.9051 314.0451 314.1851 314.3250 314.4650 314.6049 314.7448 314.8847 315.0246 315.1645 315.3044 315.4442 315.5841 315.7239 315.8638 316.0036 316.1434 316.2832 316.4230 316.5627 316.7025 316.8423 316.9820 317.1217 317.2614 317.4011 317.5408 317.6805 317.8202 317.9598 318.0995 318.2391 318.3787 318.5184 318.6580 318.7976 318.9371 319.0767 319.2163 319.3558 319.4953 319.6348 319.7744 319.9139 320.0533 320.1928 320.3323 320.4717 320.6112 320.7506 320.8900 321.0294 321.1688 321.3082 321.4476 321.5869 321.7263 321.8656 322.0049 322.1442 322.2835 322.4228 322.5621 322.7014 322.8406 322.9799 323.1191 323.2583 323.3975 323.5367 323.6759 323.8151 323.9543 324.0934 324.2325 324.3717 324.5108 324.6499 324.7890 324.9281 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241226T112216.2Z 9126.473799 186 1 55.24 2 72.53 109.86 21.51 100.19 0.00 1 0.00 1 0 17 1.055e-01 7.928e-02 8.437e-03 1.905e-03 3.737829e-01 9.319154e-04 4.090101e-03 -6.000000e+00 5.840018e-02 224.62 -2.00 3.03 -2.00 317.69 0.00e+00 1.540585e-02 1.505465e-04 8.037408e-04 -6.000000e+00 2.524028e-03 275.00 -2.00 20.00 -2.00 317.13 0.00e+00 3.287 0.000 302.00 328.00 3 4.8518e+00 2.4466e-03 2.9242e-02 -6.0000e+00 1.4455e-01 2.4805e-01 2.7581e-03 2.6576e-02 -6.0000e+00 1.5754e-01 -9.3009e-02 1.7876e-03 1.0669e-02 -6.0000e+00 9.3598e-02 -8.9281e-03 9.3416e-04 1.2953e-02 -6.0000e+00 4.0123e-02 2.4780e-04 -1.8158e-05 5.0060e-05 9.8091e-05 -6.0000e+00 2.6737e-03 -1.2375e-04 0.0000e+00 12 9 8 11 8 0 80.60 24.39 0.12 -0.00012 -0.00026 21 2 1 5 0 2630.390 33.25 20.10 24.39 20.93 3.5 902.41 21580 14108 36814 17885 10649 9402 -6904 -7904 372 -9116 -17333 -21560 -5420 3255 14736 10609 16157 19499 17403 15697 23514 8985 10060 7005 704 -4128 -7686 -9128 -280 7385 8326 11521 16412 15405 7473 7193 9873 7307 2994 1317 -772 -1407 660 4443 5175 8978 10800 10189 12214 10621 11351 10665 -80629 9566 7488 3392 3326 -613 139 1603 5245 6582 6217 9388 7530 7220 5678 5315 5319 5579 3953 4035 2579 2067 1533 110 -103 -1368 1024 2807 2318 2844 2110 -429 309 -195 941 878 1291 1836 607 759 -901 -1396 599 198 1897 2667 2691 1921 1234 451 -1852 -1463 -2020 -2316 -2648 -1903 -2014 -331 96 -102 18 -1289 -1132 -764 -968 -339 -597 -431 -854 -1144 -889 -1637 -1139 -1441 -1166 42 476 359 750 720 568 729 667 479 712 888 581 530 -249 77 -197 1387 1127 2482 1385 779 637 -544 -659 30 -804 -1607 -2243 -604 430 1963 1720 2701 3385 3274 3128 4388 1866 2008 1427 152 -941 -1813 -2139 -60 1545 1980 3062 4670 4623 2246 2065 2943 2350 1181 603 -360 -693 335 2254 2674 4607 5504 5244 6159 5519 6223 6376 -87086 5960 4839 2280 2236 -421 92 1053 3480 4736 4674 7490 6270 5640 4173 3811 4059 4544 3576 3777 2420 1854 1276 88 -75 -1043 763 2377 2113 2697 2156 -467 334 -227 1080 1040 1525 2200 681 819 -902 -1365 617 218 2327 3461 3591 2574 1633 541 -2203 -1755 -2503 -3047 -3464 -2594 -2916 -486 145 -158 27 -1935 -1637 -1031 -1300 -473 -850 -653 -1320 -1734 -1299 -2436 -1605 -1948 -1564 56 652 514 1147 1143 881 1176 1093 831 1261 1604 1018 947 -428 131 -326 SS 20241226T112757.1Z 9126.477744 190 1 54.57 2 71.25 109.60 20.19 100.48 0.00 1 0.00 1 0 17 8.291e-02 6.675e-02 6.256e-03 1.732e-03 3.534395e-01 8.503806e-04 3.810370e-03 -6.000000e+00 4.588657e-02 224.62 -2.00 3.03 -2.00 317.39 0.00e+00 1.069956e-02 1.253825e-04 5.098262e-04 -6.000000e+00 1.982710e-03 275.00 -2.00 20.00 -2.00 316.82 0.00e+00 3.075 0.000 302.00 328.00 3 4.8746e+00 2.2217e-03 2.6588e-02 -6.0000e+00 1.1358e-01 1.9496e-01 2.5024e-03 2.1038e-02 -6.0000e+00 1.2377e-01 -6.7359e-02 1.5645e-03 9.0245e-03 -6.0000e+00 7.3537e-02 -1.1975e-02 7.9966e-04 8.9744e-03 -6.0000e+00 3.1533e-02 2.9632e-04 3.9792e-04 4.5890e-05 6.8090e-05 -6.0000e+00 2.1001e-03 -1.8960e-03 0.0000e+00 12 8 8 10 0 0 78.33 24.41 0.08 -0.00190 0.00109 22 2 1 5 0 2480.320 33.25 20.08 24.41 22.26 3.6 913.99 14649 2967 25470 11312 4312 4298 -5204 -9819 -5318 -9890 -15233 -16650 -6243 -1074 8718 8606 12548 12338 11193 10764 17530 8027 6877 2717 -409 -2405 -4651 -5624 -1522 3321 6923 10641 11986 10899 4207 3588 5937 4519 2628 1178 -1021 -1198 316 2889 4180 6178 7076 7011 9096 6969 8577 7866 -69845 7556 5773 3367 2724 -152 1023 1643 4417 5957 5295 7313 6163 4989 3756 3581 4201 4805 3527 3293 2179 1951 1126 -206 -318 -1739 421 1821 1490 1516 1098 -559 519 -116 957 984 962 1790 701 379 -531 -1095 241 215 1556 2239 2171 1581 561 -469 -1877 -1513 -1601 -1919 -2098 -1275 -1503 -131 71 7 -29 -548 -830 -528 -1060 -130 -441 -421 -615 -755 -850 -1392 -977 -1275 -1362 44 235 388 580 372 244 774 855 516 599 617 573 570 -136 -19 -310 1202 311 2237 1081 389 359 -484 -1031 -572 -1129 -1785 -2103 -869 -162 1450 1646 2485 2606 2526 2538 3921 1914 1635 682 -108 -658 -1299 -1532 -388 836 1890 3186 3623 3467 1325 1087 1886 1685 1095 572 -551 -631 171 1569 2278 3373 3839 3790 4792 3796 4884 4886 -73738 4892 3885 2335 1913 -108 702 1117 3040 4411 4104 6054 5260 4014 2828 2801 3265 4241 3247 3153 2089 1788 1021 -169 -252 -1339 338 1557 1371 1548 1138 -612 566 -136 1115 1181 1156 2169 794 414 -533 -1137 250 238 1909 2906 2900 2112 741 -564 -2223 -1815 -1985 -2526 -2748 -1738 -2074 -193 106 11 -44 -813 -1187 -705 -1409 -179 -622 -632 -943 -1136 -1238 -1962 -1366 -1708 -1812 58 318 548 873 582 372 1224 1375 879 1045 1054 989 1001 -229 -31 -506 SS 20241226T113323.3Z 9126.481519 193 1 53.76 2 70.02 109.37 18.93 100.83 0.00 1 0.00 1 0 17 6.870e-02 5.835e-02 5.060e-03 1.612e-03 3.334723e-01 7.927487e-04 3.569296e-03 -6.000000e+00 3.801659e-02 224.62 -2.00 3.03 -2.00 317.10 0.00e+00 8.225965e-03 1.091199e-04 3.828690e-04 -6.000000e+00 1.642736e-03 275.00 -2.00 20.00 -2.00 316.54 0.00e+00 2.898 0.000 302.00 328.00 3 4.9046e+00 2.0649e-03 2.4781e-02 -6.0000e+00 9.4098e-02 1.5718e-01 2.3201e-03 1.8286e-02 -6.0000e+00 1.0255e-01 -4.8139e-02 1.4176e-03 8.0160e-03 -6.0000e+00 6.0925e-02 -1.4807e-02 7.1359e-04 6.8561e-03 -6.0000e+00 2.6123e-02 3.3982e-04 4.7792e-04 4.2899e-05 5.1498e-05 -6.0000e+00 1.7400e-03 -1.5676e-03 0.0000e+00 12 9 8 11 8 0 81.91 24.43 0.08 -0.00157 0.00202 23 2 1 5 0 2337.040 33.25 19.93 24.43 23.56 3.5 921.26 10873 1448 20068 7158 153 2361 -4714 -7410 -4311 -7565 -12985 -12186 -7444 -2859 4801 5973 8674 8394 9372 7730 13394 4500 4411 2188 -289 -1941 -4346 -4993 -1469 2839 4195 6679 9144 7903 1646 1898 3989 2343 1976 1952 -1199 -792 209 2170 2843 4557 5282 4499 5854 5724 7147 5956 -62061 5771 4777 2505 3003 536 1046 1310 3284 4814 5048 6020 4907 4315 3029 2654 3865 4131 2739 2928 2004 1467 937 52 -497 -1385 382 1224 975 1382 759 -484 327 -196 853 1051 1083 1456 529 282 -739 -955 317 427 1394 1961 1767 884 426 -387 -1755 -1508 -1707 -1790 -1949 -1348 -1387 107 101 248 0 -530 -733 -648 -654 -138 -190 -218 -526 -981 -561 -965 -545 -1082 -935 256 436 447 363 441 274 785 513 481 439 603 579 344 10 -232 -514 1084 163 2143 818 16 232 -511 -902 -551 -1021 -1803 -1769 -1125 -508 949 1328 2005 2059 2397 2090 3477 1242 1211 577 -80 -561 -1283 -1423 -425 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