File name: Pandora283s1_LaPaz_20250102_L2Fit_fout2c4d20241004p1-8.txt File generation date: 20250624T082410.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 283 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora283_OF_v3d20231025.txt Instrument calibration file used: Pandora283s1_CF_v4d20241004.txt Level 1 file used: Pandora283s1_LaPaz_20250102_L1_smca1c4d20241004p1-8.txt Full location name: Laboratory for Atmospheric Physics, UMSA, La Paz Short location name: LaPaz Country of location: Bolivia Location latitude [deg]: -16.5389 Location longitude [deg]: -68.0661 Location altitude [m]: 3420 Local noon date: 20250102 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 203 345 Nominal wavelengths inside fitting window [nm]: 305.0638 305.2044 305.3451 305.4858 305.6264 305.7671 305.9077 306.0483 306.1889 306.3295 306.4701 306.6107 306.7513 306.8918 307.0324 307.1729 307.3134 307.4539 307.5944 307.7349 307.8754 308.0158 308.1563 308.2967 308.4371 308.5776 308.7180 308.8584 308.9988 309.1391 309.2795 309.4198 309.5602 309.7005 309.8408 309.9811 310.1214 310.2617 310.4020 310.5422 310.6825 310.8227 310.9630 311.1032 311.2434 311.3836 311.5237 311.6639 311.8041 311.9442 312.0844 312.2245 312.3646 312.5047 312.6448 312.7849 312.9249 313.0650 313.2050 313.3451 313.4851 313.6251 313.7651 313.9051 314.0451 314.1851 314.3250 314.4650 314.6049 314.7448 314.8847 315.0246 315.1645 315.3044 315.4442 315.5841 315.7239 315.8638 316.0036 316.1434 316.2832 316.4230 316.5627 316.7025 316.8423 316.9820 317.1217 317.2614 317.4011 317.5408 317.6805 317.8202 317.9598 318.0995 318.2391 318.3787 318.5184 318.6580 318.7976 318.9371 319.0767 319.2163 319.3558 319.4953 319.6348 319.7744 319.9139 320.0533 320.1928 320.3323 320.4717 320.6112 320.7506 320.8900 321.0294 321.1688 321.3082 321.4476 321.5869 321.7263 321.8656 322.0049 322.1442 322.2835 322.4228 322.5621 322.7014 322.8406 322.9799 323.1191 323.2583 323.3975 323.5367 323.6759 323.8151 323.9543 324.0934 324.2325 324.3717 324.5108 324.6499 324.7890 324.9281 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250102T120718.3Z 9133.505072 98 1 54.32 2 63.15 107.69 95.97 112.57 0.00 1 0.00 1 0 17 8.657e-02 9.051e-02 4.660e-03 2.175e-03 2.743911e-01 1.073590e-03 3.086191e-03 -6.000000e+00 4.784263e-02 224.41 -2.00 3.03 -2.00 316.22 0.00e+00 9.472391e-03 1.179932e-04 5.137445e-04 -6.000000e+00 2.071040e-03 275.10 -2.00 20.00 -2.00 315.67 0.00e+00 2.203 0.000 302.00 328.00 3 5.9280e+00 2.7599e-03 2.0063e-02 -6.0000e+00 1.1836e-01 2.4873e-01 3.0895e-03 1.7604e-02 -6.0000e+00 1.2903e-01 -6.1738e-02 1.8188e-03 6.9438e-03 -6.0000e+00 7.6674e-02 -3.1590e-02 8.6853e-04 7.2785e-03 -6.0000e+00 3.2872e-02 2.0363e-04 -1.2976e-04 5.8134e-05 5.5713e-05 -6.0000e+00 2.1933e-03 2.7162e-03 0.0000e+00 12 8 8 10 0 0 98.70 24.67 -0.36 0.00272 0.00174 14 1 1 5 0 3879.600 33.50 20.00 24.67 24.65 3.4 927.75 10364 1476 19589 6260 2211 1182 -4064 -6956 -7972 -11360 -17494 -18148 -6567 -6003 6195 6531 7386 9777 9562 7415 13575 6099 5610 2539 -1244 -2695 -5861 -5271 -1451 4693 5537 9616 11190 11525 5255 4398 7127 5174 3049 2500 -529 -451 808 4076 4624 5824 6704 5449 9146 7905 10457 8189 -78781 8595 7038 4626 4860 1333 2328 3034 4686 6084 6001 8486 6445 5854 4462 4508 4970 6832 4822 4238 3394 2914 1831 388 -107 -1353 1283 3065 3020 3031 2737 565 1370 29 1461 1301 921 1513 182 493 -968 -1010 1296 657 2362 2709 2326 1306 559 -170 -2167 -2248 -2080 -2568 -3045 -1562 -2374 -283 -302 57 -41 -1010 -902 -987 -1410 -634 -489 -331 -1077 -1554 -1575 -1931 -1475 -1914 -2217 -430 -81 329 573 759 515 1574 1258 1109 1318 1076 869 745 19 -245 -119 1763 278 3503 1195 384 191 -699 -1328 -1645 -2446 -3848 -3790 -1447 -1601 1736 2049 2424 3278 3356 2749 4791 2243 2035 957 -494 -1100 -2448 -2093 -533 1638 2094 3875 4870 4714 2294 1846 3114 2437 1733 1508 -354 -315 576 2874 3275 4134 4675 3776 5980 5219 7059 6059 -100035 6438 5430 3660 3848 1077 1815 2340 3690 5123 5175 7674 5982 5024 3792 3673 4260 6101 4794 4391 3515 2901 1709 351 -87 -1055 1020 2724 2828 3126 2820 616 1573 34 1781 1638 1165 1835 206 536 -1028 -1027 1362 723 2853 3416 2982 1674 712 -198 -2532 -2686 -2541 -3335 -3907 -2062 -3314 -413 -444 84 -58 -1439 -1239 -1264 -1795 -835 -651 -471 -1585 -2264 -2224 -2630 -2008 -2495 -2730 -549 -105 457 792 1077 743 2327 1875 1748 2130 1693 1384 1227 30 -376 -177 SS 20250102T121156.1Z 9133.508288 101 1 54.45 2 62.09 107.54 94.99 112.21 0.00 1 0.00 1 0 17 4.947e-02 4.805e-02 2.851e-03 1.497e-03 2.455541e-01 7.386852e-04 2.642410e-03 -6.000000e+00 2.735989e-02 224.41 -2.00 3.03 -2.00 315.91 0.00e+00 4.135959e-03 7.602306e-05 1.929084e-04 -6.000000e+00 1.183585e-03 275.10 -2.00 20.00 -2.00 315.39 0.00e+00 2.127 0.000 302.00 328.00 3 5.4529e+00 1.8968e-03 1.7998e-02 -6.0000e+00 6.7686e-02 1.0004e-01 2.1218e-03 1.2120e-02 -6.0000e+00 7.3770e-02 -2.4086e-02 1.2325e-03 5.5481e-03 -6.0000e+00 4.3839e-02 -1.6940e-02 5.7740e-04 3.4110e-03 -6.0000e+00 1.8809e-02 3.8920e-04 4.7948e-04 4.0116e-05 2.6319e-05 -6.0000e+00 1.2530e-03 -2.2027e-03 0.0000e+00 12 9 8 11 8 0 69.01 24.68 -0.05 -0.00220 0.00140 24 2 1 5 0 2268.380 33.50 20.00 24.68 25.24 3.5 932.20 2894 -1130 7877 -773 -2966 -1181 -2670 -2723 -3272 -4981 -8247 -7723 -3360 -1920 2967 1974 2721 4602 5035 3827 6194 2172 2796 1141 293 -753 -1730 -2806 -1126 1555 2568 4385 5263 4367 112 -172 1232 1345 948 622 -7 60 462 1597 1645 2453 2448 2043 3195 3068 4226 4129 -50696 4276 3533 1862 2198 982 1225 956 2356 3351 3537 4496 2937 2252 1189 1641 2563 3454 2410 2488 1790 1470 1145 28 -640 -1558 -274 816 207 309 103 -880 99 -285 698 805 777 932 376 124 -404 -732 658 147 1187 1728 1345 544 -19 -661 -1529 -1187 -1319 -1631 -1635 -786 -817 50 256 374 204 -387 -573 -553 -507 34 19 -21 -430 -679 -473 -590 -689 -748 -882 158 288 416 333 170 131 539 535 476 526 676 474 337 -192 -160 -598 599 -268 1742 -173 -594 -217 -517 -587 -779 -1241 -2052 -1951 -929 -564 961 713 1016 1747 1978 1574 2529 901 1151 457 123 -329 -755 -1167 -468 621 1084 1834 2377 2045 50 -74 566 720 566 402 -5 44 327 1130 1164 1732 1812 1478 2227 2131 3044 2995 -53625 3412 2901 1572 1763 790 1019 791 1984 2836 3259 4147 2758 2067 1003 1405 2167 3302 2408 2586 1867 1481 1078 25 -552 -1274 -230 721 196 322 108 -973 110 -340 831 990 957 1163 437 138 -430 -745 696 164 1381 2115 1770 715 -23 -784 -1797 -1357 -1648 -2063 -2156 -1072 -1114 72 373 554 292 -539 -763 -719 -652 43 26 -30 -622 -974 -658 -789 -916 -949 -1106 195 378 560 452 237 184 783 789 742 808 1059 752 527 -303 -242 -884 SS 20250102T121719.5Z 9133.512031 104 1 55.12 2 60.86 107.36 93.84 111.79 0.00 1 0.00 1 0 17 4.248e-02 4.128e-02 2.396e-03 1.350e-03 2.366693e-01 6.676899e-04 2.548286e-03 -6.000000e+00 2.349101e-02 224.41 -2.00 3.03 -2.00 315.70 0.00e+00 3.312225e-03 6.513928e-05 1.601759e-04 -6.000000e+00 1.016261e-03 275.10 -2.00 20.00 -2.00 315.18 0.00e+00 2.045 0.000 302.00 328.00 3 5.3580e+00 1.7114e-03 1.7274e-02 -6.0000e+00 5.8115e-02 8.4803e-02 1.9134e-03 1.1326e-02 -6.0000e+00 6.3339e-02 -2.1304e-02 1.1068e-03 5.2864e-03 -6.0000e+00 3.7640e-02 -1.4189e-02 5.1235e-04 2.8368e-03 -6.0000e+00 1.6149e-02 4.6240e-04 4.0535e-04 3.6056e-05 2.3437e-05 -6.0000e+00 1.0759e-03 -1.9221e-03 0.0000e+00 12 8 8 10 0 0 94.36 24.71 0.09 -0.00192 0.00112 25 3 1 5 0 2204.470 33.50 20.00 24.71 25.95 3.4 938.70 2265 -623 5429 338 -3039 -747 -2210 -3015 -2021 -3997 -6494 -7707 -4276 -2595 2124 2351 2410 4073 3751 2389 5078 1739 2722 1841 999 -58 -1130 -2254 -1145 1369 1953 4010 4837 3884 -257 -1359 890 467 881 955 -434 -276 162 1080 1394 2016 2352 1422 2247 2281 3749 3506 -43410 3675 3504 2346 2253 775 1218 951 2035 3100 3003 4230 2382 1567 1122 574 1920 2754 2075 2080 1471 1250 876 -202 -694 -1316 -357 370 352 105 -44 -1052 -187 -289 578 866 848 1239 383 369 -644 -529 566 317 1002 1603 1109 547 30 -1076 -1710 -1036 -1044 -1598 -1625 -953 -958 275 436 488 367 -122 -643 -405 -495 -162 -145 16 -359 -422 -429 -537 -323 -577 -804 191 326 399 336 58 -7 723 583 373 299 752 483 166 -324 -329 -509 537 -152 1391 84 -687 -154 -483 -742 -543 -1034 -1817 -2032 -1237 -861 775 869 924 1586 1521 1015 2136 739 1146 812 464 -28 -546 -1037 -486 557 839 1837 2388 1845 -126 -646 446 255 535 630 -314 -208 118 786 1011 1458 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