File name: Pandora283s1_LaPaz_20250107_L2Fit_fout2c2d20240531p1-8.txt File generation date: 20250108T044501.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 283 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora283_OF_v3d20231025.txt Instrument calibration file used: Pandora283s1_CF_v2d20240531.txt Level 1 file used: Pandora283s1_LaPaz_20250107_L1_smca1c2d20240531p1-8.txt Full location name: Laboratory for Atmospheric Physics, UMSA, La Paz Short location name: LaPaz Country of location: Bolivia Location latitude [deg]: -16.5389 Location longitude [deg]: -68.0661 Location altitude [m]: 3420 Local noon date: 20250107 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 203 345 Nominal wavelengths inside fitting window [nm]: 305.0233 305.1640 305.3046 305.4453 305.5860 305.7266 305.8672 306.0078 306.1485 306.2891 306.4296 306.5702 306.7108 306.8513 306.9919 307.1324 307.2729 307.4134 307.5539 307.6944 307.8349 307.9754 308.1158 308.2563 308.3967 308.5371 308.6775 308.8179 308.9583 309.0987 309.2390 309.3794 309.5197 309.6600 309.8004 309.9407 310.0810 310.2213 310.3615 310.5018 310.6420 310.7823 310.9225 311.0627 311.2029 311.3431 311.4833 311.6235 311.7636 311.9038 312.0439 312.1840 312.3242 312.4643 312.6044 312.7444 312.8845 313.0246 313.1646 313.3046 313.4447 313.5847 313.7247 313.8647 314.0046 314.1446 314.2846 314.4245 314.5644 314.7044 314.8443 314.9842 315.1241 315.2639 315.4038 315.5437 315.6835 315.8233 315.9631 316.1029 316.2427 316.3825 316.5223 316.6621 316.8018 316.9416 317.0813 317.2210 317.3607 317.5004 317.6401 317.7797 317.9194 318.0590 318.1987 318.3383 318.4779 318.6175 318.7571 318.8967 319.0362 319.1758 319.3153 319.4549 319.5944 319.7339 319.8734 320.0129 320.1524 320.2918 320.4313 320.5707 320.7101 320.8495 320.9890 321.1283 321.2677 321.4071 321.5465 321.6858 321.8251 321.9645 322.1038 322.2431 322.3824 322.5216 322.6609 322.8002 322.9394 323.0786 323.2178 323.3570 323.4962 323.6354 323.7746 323.9138 324.0529 324.1920 324.3312 324.4703 324.6094 324.7485 324.8876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250107T131039.4Z 9138.549068 139 1 54.10 2 49.16 105.45 146.41 93.86 0.00 1 0.00 1 0 17 4.439e-02 4.757e-02 2.252e-03 1.595e-03 1.843437e-01 7.947052e-04 2.020434e-03 -6.000000e+00 2.456644e-02 224.23 -2.00 3.03 -2.00 314.72 0.00e+00 3.007155e-03 6.442461e-05 1.805305e-04 -6.000000e+00 1.064762e-03 275.19 -2.00 20.00 -2.00 314.28 0.00e+00 1.527 0.000 302.00 328.00 3 5.9323e+00 2.0173e-03 1.3217e-02 -6.0000e+00 6.0746e-02 1.1249e-01 2.2465e-03 9.2127e-03 -6.0000e+00 6.6212e-02 -2.4462e-02 1.2918e-03 4.1494e-03 -6.0000e+00 3.9355e-02 -1.5776e-02 5.7638e-04 2.4425e-03 -6.0000e+00 1.6885e-02 4.0237e-04 2.9694e-04 4.2700e-05 1.9923e-05 -6.0000e+00 1.1305e-03 3.5307e-02 -1.4495e-04 12 9 9 12 9 1 97.84 24.60 0.00 0.03531 0.03754 14 2 1 5 0 3606.240 33.50 20.00 24.60 24.42 3.5 926.47 2349 -669 3173 -1597 -3008 -1387 -1373 -1838 -1638 -5725 -6060 -6888 -3374 -2157 2316 1231 2133 3532 3490 2553 4342 1297 2717 1592 1107 -124 -533 -2500 -555 2385 2159 3676 4953 3673 299 -483 1172 1263 1454 1243 153 140 363 1430 1581 1903 2075 772 2623 2526 3856 3232 -46386 3394 3582 1888 2650 1509 1458 1690 2361 3140 3179 4093 2310 1536 511 477 2236 3086 2050 1924 1507 1309 579 261 -635 -1551 -141 354 423 217 -32 -944 61 -20 794 802 671 1145 249 417 -486 -411 743 416 1257 1519 962 480 9 -702 -1799 -1045 -1287 -1499 -1784 -1152 -1228 273 448 273 461 -266 -331 -505 -423 -224 -200 -42 -275 -546 -585 -664 -308 -813 -632 311 195 463 394 78 86 835 971 484 550 689 477 216 -335 -441 -735 810 -257 1180 -573 -952 -439 -451 -618 -603 -2243 -2284 -2625 -1383 -924 1075 626 1100 1836 1868 1318 2403 722 1484 843 611 -71 -301 -1350 -293 1188 1124 2021 2885 2044 170 -265 680 791 1011 934 126 118 296 1163 1360 1630 1728 627 2015 1913 2993 2687 -53065 2885 3090 1671 2352 1342 1267 1455 2078 2941 3041 4107 2341 1510 457 430 1966 3055 2118 2071 1626 1366 569 244 -566 -1297 -119 334 420 223 -35 -1023 70 -23 973 1015 852 1400 299 451 -502 -425 747 460 1441 1819 1235 612 10 -812 -1978 -1176 -1585 -1864 -2316 -1471 -1633 378 621 382 648 -347 -411 -614 -507 -279 -254 -54 -371 -737 -767 -878 -385 -1021 -743 357 237 570 510 103 114 1136 1330 704 785 1006 706 315 -476 -634 -1029 SS 20250107T134252.3Z 9138.571439 158 1 55.48 2 41.71 105.16 139.08 91.01 0.00 1 0.00 1 0 9 4.418e-02 4.796e-02 2.049e-03 1.547e-03 1.670050e-01 7.735551e-04 1.838800e-03 -6.000000e+00 2.445011e-02 224.23 -2.00 3.03 -2.00 314.35 0.00e+00 2.599744e-03 5.841523e-05 1.476747e-04 -6.000000e+00 1.059863e-03 275.19 -2.00 20.00 -2.00 313.93 0.00e+00 1.338 0.000 302.00 328.00 3 6.1156e+00 1.9576e-03 1.1775e-02 -6.0000e+00 6.0458e-02 1.1928e-01 2.1767e-03 8.3454e-03 -6.0000e+00 6.5901e-02 -2.7005e-02 1.2528e-03 3.7486e-03 -6.0000e+00 3.9169e-02 -1.4596e-02 5.5193e-04 2.0906e-03 -6.0000e+00 1.6805e-02 3.9386e-04 3.4880e-05 4.1323e-05 1.6562e-05 -6.0000e+00 1.1255e-03 3.4054e-02 -2.2368e-04 12 9 8 11 8 0 99.92 24.75 0.10 0.03405 0.03432 17 2 1 5 0 3263.340 33.50 20.01 24.75 27.49 3.4 947.43 2146 -1060 3520 -1790 -2757 -707 -1869 -2252 -1998 -4343 -6629 -5748 -2875 -1500 2210 2066 2002 3007 3224 2465 3967 823 2249 1616 1217 -91 -295 -2331 -988 1890 2031 3543 5204 3000 -477 -349 660 1572 1657 1537 94 473 583 1324 1275 1546 1937 1008 1824 2158 3436 3254 -46687 3420 3339 1695 2544 1310 1697 1766 1992 3126 2869 4366 2134 1456 360 408 2129 3373 2042 1922 1626 1137 842 109 -763 -1025 -418 239 175 308 -47 -932 -73 -111 645 783 635 1075 447 140 -561 -652 662 177 1091 1475 803 351 512 -897 -1701 -1445 -1442 -1363 -1553 -1162 -1019 181 384 472 621 -367 -274 -583 -530 -128 -308 145 -207 -526 -158 -628 -341 -627 -793 110 384 430 307 439 166 846 788 567 550 512 512 217 -381 -629 -751 857 -470 1493 -734 -991 -253 -642 -865 -839 -1906 -2844 -2437 -1309 -708 1130 1139 1125 1703 1869 1374 2205 460 1328 919 721 -56 -178 -1343 -559 1001 1112 2038 3146 1878 -283 -198 398 1014 1187 1188 79 411 518 1173 1124 1355 1644 829 1522 1762 2868 2709 -53549 3082 3058 1590 2390 1235 1556 1606 1859 2906 2885 4565 2132 1406 335 360 1938 3238 2171 2011 1704 1157 852 106 -663 -881 -365 217 168 322 -50 -1021 -85 -130 798 950 774 1326 513 154 -586 -642 669 197 1248 1752 1023 444 604 -1033 -1861 -1627 -1679 -1683 -1998 -1469 -1336 248 522 647 854 -469 -334 -696 -623 -157 -382 193 -274 -695 -212 -815 -418 -773 -918 124 455 544 386 560 213 1112 1042 795 794 720 729 306 -548 -876 -1017 SS 20250107T134815.4Z 9138.575179 161 1 55.89 2 40.47 105.16 137.85 90.59 0.00 1 0.00 1 0 9 4.297e-02 4.710e-02 1.981e-03 1.504e-03 1.636130e-01 7.541929e-04 1.808651e-03 -6.000000e+00 2.378153e-02 224.23 -2.00 3.03 -2.00 314.34 0.00e+00 2.625354e-03 5.625455e-05 1.431054e-04 -6.000000e+00 1.030867e-03 275.19 -2.00 20.00 -2.00 313.90 0.00e+00 1.313 0.000 302.00 328.00 3 6.1018e+00 1.9084e-03 1.1564e-02 -6.0000e+00 5.8804e-02 1.1591e-01 2.1223e-03 8.2325e-03 -6.0000e+00 6.4099e-02 -2.6221e-02 1.2227e-03 3.6838e-03 -6.0000e+00 3.8098e-02 -1.4785e-02 5.3708e-04 2.0878e-03 -6.0000e+00 1.6346e-02 4.0921e-04 -4.6528e-05 4.0035e-05 1.6371e-05 -6.0000e+00 1.0947e-03 3.4054e-02 -2.1928e-04 12 9 8 11 8 0 99.85 24.77 -0.03 0.03405 0.03370 15 2 1 5 0 3725.470 33.50 20.01 24.77 28.04 3.5 953.51 1785 -1052 3163 -1489 -2677 -1248 -1687 -1426 -1255 -4858 -6034 -5558 -2468 -1800 2060 2194 1954 2979 3405 2832 3813 1557 2618 1897 1471 388 -833 -2104 -82 1988 2341 3653 4844 2522 -1356 -20 333 1108 1005 1624 201 516 313 1345 1259 1397 1836 1077 2362 1960 3537 3451 -45253 3455 3044 2212 2690 1126 1431 1306 2310 3043 3051 4027 2361 1588 674 649 1950 3343 2154 2148 1828 1279 741 400 -809 -1296 -521 355 1 323 35 -814 -8 -246 560 821 607 1077 430 63 -604 -547 559 151 1106 1667 887 549 233 -989 -1901 -1238 -1399 -1621 -1483 -880 -1130 263 482 474 512 -161 -514 -507 -318 -3 -155 320 -357 -580 -423 -500 -430 -576 -783 173 161 463 263 277 81 713 796 325 530 651 485 543 -498 -403 -760 748 -450 1299 -636 -1005 -429 -604 -566 -545 -2234 -2683 -2448 -1074 -885 1096 1164 1059 1625 1897 1630 2200 895 1482 1115 900 246 -525 -1252 -48 1088 1320 2165 2814 1520 -778 -12 193 739 747 1290 174 434 270 1154 1075 1188 1605 910 1889 1544 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