File name: Pandora283s1_LaPaz_20250107_L2Fit_fwvt1c4d20241004p1-8.txt File generation date: 20250624T082124.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 283 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora283_OF_v3d20231025.txt Instrument calibration file used: Pandora283s1_CF_v4d20241004.txt Level 1 file used: Pandora283s1_LaPaz_20250107_L1_smca1c4d20241004p1-8.txt Full location name: Laboratory for Atmospheric Physics, UMSA, La Paz Short location name: LaPaz Country of location: Bolivia Location latitude [deg]: -16.5389 Location longitude [deg]: -68.0661 Location altitude [m]: 3420 Local noon date: 20250107 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1625 1775 Nominal wavelengths inside fitting window [nm]: 492.0155 492.1365 492.2574 492.3783 492.4991 492.6200 492.7408 492.8616 492.9824 493.1032 493.2240 493.3447 493.4655 493.5862 493.7069 493.8276 493.9483 494.0689 494.1896 494.3102 494.4308 494.5514 494.6719 494.7925 494.9130 495.0335 495.1540 495.2745 495.3950 495.5154 495.6359 495.7563 495.8767 495.9971 496.1175 496.2378 496.3581 496.4785 496.5988 496.7190 496.8393 496.9596 497.0798 497.2000 497.3202 497.4404 497.5606 497.6807 497.8008 497.9209 498.0410 498.1611 498.2812 498.4012 498.5213 498.6413 498.7613 498.8813 499.0012 499.1212 499.2411 499.3610 499.4809 499.6008 499.7206 499.8405 499.9603 500.0801 500.1999 500.3197 500.4395 500.5592 500.6789 500.7986 500.9183 501.0380 501.1577 501.2773 501.3969 501.5165 501.6361 501.7557 501.8753 501.9948 502.1143 502.2338 502.3533 502.4728 502.5922 502.7117 502.8311 502.9505 503.0699 503.1892 503.3086 503.4279 503.5472 503.6665 503.7858 503.9051 504.0243 504.1436 504.2628 504.3820 504.5012 504.6203 504.7395 504.8586 504.9777 505.0968 505.2159 505.3350 505.4540 505.5730 505.6920 505.8110 505.9300 506.0490 506.1679 506.2868 506.4057 506.5246 506.6435 506.7624 506.8812 507.0000 507.1188 507.2376 507.3564 507.4751 507.5939 507.7126 507.8313 507.9500 508.0686 508.1873 508.3059 508.4245 508.5431 508.6617 508.7803 508.8988 509.0173 509.1359 509.2543 509.3728 509.4913 509.6097 509.7282 509.8466 509.9649 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250107T125743.1Z 9138.540082 131 1 54.45 2 52.15 105.69 149.34 95.22 0.00 1 0.00 1 0 15 4.012e-03 4.002e-03 8.341e-04 8.327e-04 1.247541e+03 4.436913e+01 8.431796e+01 -6.000000e+00 2.058661e+02 275.19 -2.00 20.00 -2.00 505.26 0.00e+00 6.903097e-04 2.202303e-05 3.703937e-05 -6.000000e+00 1.083847e-04 275.19 -2.00 20.00 -2.00 500.43 0.00e+00 2.906263e-02 1.596616e-02 1.301279e-02 -6.000000e+00 7.745269e-02 224.23 -2.00 3.03 -2.00 502.03 0.00e+00 1.626 0.000 489.00 513.00 1 7.7168e+00 1.2187e-03 2.0759e-03 -6.0000e+00 5.9120e-03 2.5783e-03 3.1951e-04 2.7968e-04 -6.0000e+00 1.5523e-03 7.3822e-04 1.5970e-03 6.8944e-05 1.5863e-05 -6.0000e+00 3.3851e-04 2.5287e-03 -7.9535e-05 11 8 0 10 0 0 95.93 24.54 0.71 0.00253 0.01361 15 2 1 4 0 3629.500 33.50 20.02 24.54 23.31 3.5 915.94 -771 -603 -332 5 -274 688 634 487 355 336 483 158 -43 -222 -154 -388 -208 28 136 -99 233 156 72 145 342 433 376 584 -327 -102 -247 -560 -580 320 -52 179 40 177 -267 -389 -7 -235 206 313 -12 344 391 510 255 -114 -347 -817 -651 -874 -181 -68 -273 -56 51 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152 -69 -149 443 159 388 303 156 -114 -542 -434 -454 SQ 20250107T130208.3Z 9138.543152 134 1 53.78 2 51.13 105.60 148.34 94.74 0.00 1 0.00 1 0 15 3.269e-03 3.241e-03 4.701e-04 4.694e-04 1.471552e+03 2.516648e+01 1.245301e+02 -6.000000e+00 1.677848e+02 275.19 -2.00 20.00 -2.00 505.26 0.00e+00 5.338179e-04 1.240160e-05 2.786998e-05 -6.000000e+00 8.831159e-05 275.19 -2.00 20.00 -2.00 500.47 0.00e+00 -9.205449e-03 8.989989e-03 9.366581e-03 -6.000000e+00 6.307294e-02 224.23 -2.00 3.03 -2.00 502.06 0.00e+00 1.590 0.000 489.00 513.00 1 6.6048e+00 6.8585e-04 1.8510e-03 -6.0000e+00 4.8150e-03 -2.7904e-03 1.7980e-04 2.5871e-04 -6.0000e+00 1.2631e-03 2.2627e-03 6.3145e-04 3.8771e-05 1.9591e-05 -6.0000e+00 2.7583e-04 -2.6099e-03 4.1988e-06 10 0 0 10 0 0 95.66 24.56 0.76 -0.00261 0.00177 40 4 1 4 0 1344.260 33.50 20.01 24.56 23.56 3.5 918.83 -672 -618 -361 7 128 431 513 477 428 330 418 137 -140 -167 -253 -382 -216 71 119 -7 191 190 114 269 338 331 371 475 -198 -375 -299 -546 -341 142 62 97 175 57 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90 197 98 297 179 94 240 454 152 33 11 -164 -472 -182 -154 -73 -69 253 -36 53 314 222 429 356 15 -300 -395 -478 -438 SQ 20250107T130618.7Z 9138.546050 137 1 54.03 2 50.16 105.52 147.39 94.30 0.00 1 0.00 1 0 15 3.261e-03 3.229e-03 4.878e-04 4.871e-04 1.496727e+03 2.612605e+01 1.267734e+02 -6.000000e+00 1.673484e+02 275.19 -2.00 20.00 -2.00 505.26 0.00e+00 5.395332e-04 1.286652e-05 2.775575e-05 -6.000000e+00 8.808224e-05 275.19 -2.00 20.00 -2.00 500.46 0.00e+00 -2.208171e-02 9.332150e-03 9.453457e-03 -6.000000e+00 6.290989e-02 224.23 -2.00 3.03 -2.00 502.06 0.00e+00 1.558 0.000 489.00 513.00 1 6.6832e+00 7.1202e-04 1.8296e-03 -6.0000e+00 4.8026e-03 -2.7571e-03 1.8674e-04 2.6139e-04 -6.0000e+00 1.2599e-03 2.1002e-03 6.9037e-04 4.0284e-05 1.9823e-05 -6.0000e+00 2.7511e-04 -2.8497e-03 4.4218e-06 10 0 0 10 0 0 93.43 24.58 0.85 -0.00285 0.00194 46 5 1 4 0 1174.490 33.50 20.00 24.58 23.96 3.5 922.47 -718 -642 -286 -120 -98 434 490 399 456 313 420 311 -160 -184 -409 -256 -110 83 162 -99 212 115 137 305 244 335 410 500 -235 -376 -198 -399 -348 161 105 43 181 90 -253 -208 -35 -195 42 213 234 272 273 365 243 -84 -308 -599 -778 -697 -367 -186 -116 -22 -26 89 201 309 243 303 254 158 128 142 -15 -464 -356 -151 -176 36 103 -155 -248 -101 -302 -462 -444 -333 -483 -208 -124 -143 -2 -71 -146 -30 205 241 489 430 307 560 495 22 -341 -646 -860 -706 -516 -148 -187 -161 28 -361 -313 -199 -151 -145 59 212 329 504 604 577 245 364 212 142 97 255 10 320 216 126 343 519 221 -52 -68 -75 -427 -191 -288 -176 51 209 49 143 293 146 410 296 7 -322 -514 -438 -563 -690 -622 -285 -122 -101 444 512 415 476 330 434 317 -164 -186 -410 -257 -112 84 169 -104 222 121 143 319 257 353 431 521 -242 -380 -197 -396 -351 164 109 45 187 94 -260 -211 -36 -198 43 221 241 282 282 380 249 -84 -306 -589 -751 -671 -361 -186 -117 -23 -26 91 204 316 250 307 261 160 127 142 -15 -455 -350 -148 -171 36 101 -153 -245 -97 -293 -447 -431 -320 -469 -202 -123 -140 -2 -70 -144 -30 203 240 488 435 309 553 489 22 -328 -621 -817 -675 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