File name: Pandora283s1_LaPaz_20250123_L2Fit_fout2c4d20241004p1-8.txt File generation date: 20250624T082920.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 283 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora283_OF_v3d20231025.txt Instrument calibration file used: Pandora283s1_CF_v4d20241004.txt Level 1 file used: Pandora283s1_LaPaz_20250123_L1_smca1c4d20241004p1-8.txt Full location name: Laboratory for Atmospheric Physics, UMSA, La Paz Short location name: LaPaz Country of location: Bolivia Location latitude [deg]: -16.5389 Location longitude [deg]: -68.0661 Location altitude [m]: 3420 Local noon date: 20250123 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 203 345 Nominal wavelengths inside fitting window [nm]: 305.0638 305.2044 305.3451 305.4858 305.6264 305.7671 305.9077 306.0483 306.1889 306.3295 306.4701 306.6107 306.7513 306.8918 307.0324 307.1729 307.3134 307.4539 307.5944 307.7349 307.8754 308.0158 308.1563 308.2967 308.4371 308.5776 308.7180 308.8584 308.9988 309.1391 309.2795 309.4198 309.5602 309.7005 309.8408 309.9811 310.1214 310.2617 310.4020 310.5422 310.6825 310.8227 310.9630 311.1032 311.2434 311.3836 311.5237 311.6639 311.8041 311.9442 312.0844 312.2245 312.3646 312.5047 312.6448 312.7849 312.9249 313.0650 313.2050 313.3451 313.4851 313.6251 313.7651 313.9051 314.0451 314.1851 314.3250 314.4650 314.6049 314.7448 314.8847 315.0246 315.1645 315.3044 315.4442 315.5841 315.7239 315.8638 316.0036 316.1434 316.2832 316.4230 316.5627 316.7025 316.8423 316.9820 317.1217 317.2614 317.4011 317.5408 317.6805 317.8202 317.9598 318.0995 318.2391 318.3787 318.5184 318.6580 318.7976 318.9371 319.0767 319.2163 319.3558 319.4953 319.6348 319.7744 319.9139 320.0533 320.1928 320.3323 320.4717 320.6112 320.7506 320.8900 321.0294 321.1688 321.3082 321.4476 321.5869 321.7263 321.8656 322.0049 322.1442 322.2835 322.4228 322.5621 322.7014 322.8406 322.9799 323.1191 323.2583 323.3975 323.5367 323.6759 323.8151 323.9543 324.0934 324.2325 324.3717 324.5108 324.6499 324.7890 324.9281 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250123T140939.0Z 9154.590035 1793 1 23.30 2 36.79 100.28 37.02 254.49 0.00 1 0.00 1 0 17 3.173e-02 3.341e-02 2.610e-03 2.049e-03 1.548701e-01 1.027458e-03 1.698601e-03 -6.000000e+00 1.752124e-02 224.00 -2.00 3.03 -2.00 314.12 0.00e+00 1.706544e-03 7.433350e-05 1.074424e-04 -6.000000e+00 7.600237e-04 275.37 -2.00 20.00 -2.00 313.72 0.00e+00 1.248 0.000 302.00 328.00 3 5.8795e+00 2.5957e-03 1.0853e-02 -6.0000e+00 4.3303e-02 8.0410e-02 2.8827e-03 7.2927e-03 -6.0000e+00 4.7209e-02 -1.3744e-02 1.6602e-03 3.4372e-03 -6.0000e+00 2.8067e-02 -1.2350e-02 7.2808e-04 1.5520e-03 -6.0000e+00 1.2054e-02 5.4946e-04 4.3456e-04 5.4420e-05 1.4536e-05 -6.0000e+00 8.0374e-04 -1.3549e-03 0.0000e+00 12 9 9 12 9 1 97.99 24.31 0.02 -0.00135 0.00191 6 2 1 5 0 3327.280 33.25 20.11 24.31 18.73 3.7 883.92 659 -977 897 -878 -2789 -1388 -1019 -712 -1150 -1729 -3959 -4760 -2226 -1254 1802 1409 1406 2345 2209 2380 3735 1351 1807 1133 1033 608 290 -1191 -622 914 1697 3183 3197 1258 -1235 -1654 -147 287 69 818 -350 239 265 567 722 936 949 575 1091 1727 2382 2573 -33389 3157 2336 1490 2425 1338 1181 613 1478 2088 2568 3306 1417 847 -100 525 1092 2537 1402 1198 996 973 631 140 -546 -1612 -834 -172 -165 -537 -1053 -913 -585 -90 638 453 636 768 542 298 -689 -118 757 197 1000 1341 949 330 -2 -803 -1274 -1168 -929 -1076 -1232 -645 -707 289 331 396 364 -158 -244 -373 -476 29 129 -113 -1 -352 -388 -598 -118 -164 -445 535 669 516 220 405 -138 224 230 542 447 488 503 129 -362 -431 -963 297 -445 401 -394 -1105 -547 -385 -300 -536 -772 -1859 -2231 -1037 -653 952 802 812 1361 1316 1454 2283 825 1096 717 638 387 182 -754 -360 534 947 1856 1988 809 -745 -956 -90 191 52 663 -310 205 233 498 630 811 841 490 886 1446 1936 2217 -36919 2780 2108 1368 2232 1234 1067 552 1357 2038 2554 3442 1486 850 -91 473 1028 2534 1472 1251 1041 1035 631 133 -488 -1423 -744 -161 -163 -554 -1155 -988 -672 -106 788 554 778 949 621 323 -708 -119 788 214 1129 1584 1199 414 -3 -910 -1437 -1297 -1126 -1322 -1577 -816 -927 380 454 546 479 -201 -293 -437 -549 35 159 -143 -1 -464 -498 -772 -143 -199 -507 621 778 641 273 510 -175 292 303 754 613 686 716 181 -496 -595 -1300 SS 20250123T141257.4Z 9154.592331 1796 1 55.26 2 36.02 100.23 37.77 254.52 0.00 1 0.00 1 0 17 2.075e-02 2.008e-02 1.139e-03 9.144e-04 1.493664e-01 4.584533e-04 1.622179e-03 -6.000000e+00 1.145532e-02 224.00 -2.00 3.03 -2.00 313.97 0.00e+00 1.047094e-03 3.237883e-05 5.310752e-05 -6.000000e+00 4.968955e-04 275.37 -2.00 20.00 -2.00 313.59 0.00e+00 1.235 0.000 302.00 328.00 3 5.3633e+00 1.1576e-03 1.0556e-02 -6.0000e+00 2.8311e-02 5.2626e-02 1.2860e-03 6.7318e-03 -6.0000e+00 3.0865e-02 -8.7244e-03 7.4002e-04 3.2715e-03 -6.0000e+00 1.8350e-02 -7.7433e-03 3.2320e-04 1.1706e-03 -6.0000e+00 7.8809e-03 9.4858e-04 3.0233e-04 2.4084e-05 1.2669e-05 -6.0000e+00 5.2547e-04 -1.4230e-03 0.0000e+00 12 9 8 11 8 0 98.70 24.31 0.04 -0.00142 0.00085 29 3 1 5 0 1905.150 33.25 20.02 24.31 18.82 3.7 884.86 709 -373 916 -2025 -2420 -2001 -1096 350 24 -1029 -3032 -2854 -1612 -728 1220 947 849 1009 1448 2081 2245 854 1486 1140 806 447 110 -523 -517 1253 1179 2356 2442 880 -1755 -2140 -1663 -608 -29 382 -383 -101 -300 55 336 524 311 -47 383 847 1693 1770 -20869 1861 1514 1243 1446 896 859 510 1011 1623 2013 2445 1075 212 -287 -191 686 1442 988 923 804 864 290 -154 -694 -1506 -1014 -539 -679 -697 -1361 -1540 -598 -408 85 669 685 745 353 104 -147 -234 446 137 560 1128 938 114 -119 -813 -1337 -882 -778 -953 -1269 -564 -427 322 494 535 401 32 -163 -332 -215 -36 118 321 27 -234 151 40 293 195 -83 387 440 371 146 56 -169 107 293 253 221 423 269 56 -424 -612 -822 322 -183 444 -926 -1031 -791 -448 158 11 -501 -1440 -1335 -813 -384 704 552 502 603 882 1294 1415 533 921 737 516 295 72 -337 -305 738 713 1402 1547 575 -1077 -1337 -1048 -417 -23 322 -335 -91 -264 48 292 474 273 -40 324 696 1429 1510 -21305 1722 1366 1136 1336 827 775 457 927 1581 2012 2565 1130 204 -271 -170 637 1443 1041 972 848 922 292 -146 -615 -1302 -887 -499 -669 -719 -1436 -1688 -665 -487 102 833 856 901 412 114 -151 -236 464 150 640 1353 1155 139 -142 -932 -1454 -988 -914 -1144 -1591 -729 -551 435 670 730 544 42 -199 -393 -250 -42 147 416 36 -304 197 50 361 229 -95 433 519 447 184 69 -210 137 379 347 300 587 379 79 -573 -832 -1089 SS 20250123T141510.7Z 9154.593873 1798 1 53.91 2 35.49 100.20 38.28 254.54 0.00 1 0.00 1 0 17 9.001e-03 7.391e-03 1.122e-03 9.068e-04 1.422467e-01 4.541902e-04 1.522614e-03 -6.000000e+00 4.969942e-03 224.00 -2.00 3.03 -2.00 313.94 0.00e+00 3.943010e-04 3.188609e-05 8.782821e-06 -6.000000e+00 2.155606e-04 275.37 -2.00 20.00 -2.00 313.55 0.00e+00 1.227 0.000 302.00 328.00 3 5.3520e+00 1.1468e-03 1.0248e-02 -6.0000e+00 1.2283e-02 2.2062e-02 1.2745e-03 6.1965e-03 -6.0000e+00 1.3390e-02 -1.7202e-03 7.3288e-04 3.0728e-03 -6.0000e+00 7.9610e-03 -3.2211e-03 3.1977e-04 9.0420e-04 -6.0000e+00 3.4194e-03 9.8910e-04 2.9593e-04 2.3822e-05 1.1278e-05 -6.0000e+00 2.2795e-04 -2.0498e-03 0.0000e+00 11 9 0 11 40 0 99.28 24.32 0.11 -0.00205 0.00017 30 3 1 5 0 1796.900 33.25 20.14 24.32 18.85 3.7 885.70 453 107 459 -1838 -2692 -1470 -707 721 717 -113 -1501 -2063 -966 -552 1050 535 224 439 608 785 1568 582 1075 1150 1067 865 540 -460 -603 548 942 929 1336 90 -2620 -2914 -2119 -1578 -672 -365 -696 -763 -660 -420 -276 -118 -228 -747 -796 -162 591 625 747 965 888 767 1133 547 475 347 615 1035 1550 1760 525 -231 -1079 -985 -175 876 247 592 559 480 362 -233 -877 -1755 -1355 -1125 -1230 -1320 -1637 -1799 -888 -677 -2 348 732 838 310 274 -122 -206 163 -22 365 755 645 -54 -311 -771 -1257 -692 -695 -664 -908 -393 -248 557 666 741 454 301 -218 -187 -282 -43 150 442 345 109 488 466 589 357 26 632 440 436 62 -145 -328 -85 105 158 -2 234 172 -52 -513 -541 -937 211 53 227 -852 -1168 -588 -294 332 343 -56 -722 -982 -494 -295 614 316 134 265 375 497 1000 366 674 751 690 577 356 -300 -360 327 573 561 855 59 -1621 -1726 -1342 -1095 -525 -297 -614 -665 -585 -373 -242 -103 -202 -635 -679 -135 503 538 672 859 806 705 1052 507 432 313 568 1016 1559 1783 532 -222 -981 -886 -164 880 262 626 593 494 366 -222 -782 -1526 -1192 -1047 -1220 -1373 -1733 -1979 -992 -783 -2 420 919 1018 364 303 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