File name: Pandora283s1_LaPaz_20250201_L2Fit_fout2c4d20241004p1-8.txt File generation date: 20250624T083313.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 283 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora283_OF_v3d20231025.txt Instrument calibration file used: Pandora283s1_CF_v4d20241004.txt Level 1 file used: Pandora283s1_LaPaz_20250201_L1_smca1c4d20241004p1-8.txt Full location name: Laboratory for Atmospheric Physics, UMSA, La Paz Short location name: LaPaz Country of location: Bolivia Location latitude [deg]: -16.5389 Location longitude [deg]: -68.0661 Location altitude [m]: 3420 Local noon date: 20250201 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 203 345 Nominal wavelengths inside fitting window [nm]: 305.0638 305.2044 305.3451 305.4858 305.6264 305.7671 305.9077 306.0483 306.1889 306.3295 306.4701 306.6107 306.7513 306.8918 307.0324 307.1729 307.3134 307.4539 307.5944 307.7349 307.8754 308.0158 308.1563 308.2967 308.4371 308.5776 308.7180 308.8584 308.9988 309.1391 309.2795 309.4198 309.5602 309.7005 309.8408 309.9811 310.1214 310.2617 310.4020 310.5422 310.6825 310.8227 310.9630 311.1032 311.2434 311.3836 311.5237 311.6639 311.8041 311.9442 312.0844 312.2245 312.3646 312.5047 312.6448 312.7849 312.9249 313.0650 313.2050 313.3451 313.4851 313.6251 313.7651 313.9051 314.0451 314.1851 314.3250 314.4650 314.6049 314.7448 314.8847 315.0246 315.1645 315.3044 315.4442 315.5841 315.7239 315.8638 316.0036 316.1434 316.2832 316.4230 316.5627 316.7025 316.8423 316.9820 317.1217 317.2614 317.4011 317.5408 317.6805 317.8202 317.9598 318.0995 318.2391 318.3787 318.5184 318.6580 318.7976 318.9371 319.0767 319.2163 319.3558 319.4953 319.6348 319.7744 319.9139 320.0533 320.1928 320.3323 320.4717 320.6112 320.7506 320.8900 321.0294 321.1688 321.3082 321.4476 321.5869 321.7263 321.8656 322.0049 322.1442 322.2835 322.4228 322.5621 322.7014 322.8406 322.9799 323.1191 323.2583 323.3975 323.5367 323.6759 323.8151 323.9543 324.0934 324.2325 324.3717 324.5108 324.6499 324.7890 324.9281 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250201T112531.7Z 9163.476061 62 1 55.72 2 76.06 103.87 115.87 102.36 0.00 1 0.00 1 0 28 3.465e-01 1.264e-01 2.551e-02 2.490e-03 4.635999e-01 1.221688e-03 5.358296e-03 -6.000000e+00 1.912051e-01 224.09 -2.00 3.03 -2.00 318.66 0.00e+00 4.600505e-02 2.617564e-04 2.466547e-03 -6.000000e+00 8.299689e-03 275.41 -2.00 20.00 -2.00 318.12 0.00e+00 4.066 0.000 302.00 328.00 3 4.4706e+00 3.2374e-03 4.6991e-02 -6.0000e+00 4.7263e-01 6.2446e-01 3.6797e-03 6.5135e-02 -6.0000e+00 5.1540e-01 -3.8113e-01 2.7623e-03 2.7116e-02 -6.0000e+00 3.0640e-01 7.9265e-02 1.5135e-03 4.1439e-02 -6.0000e+00 1.3143e-01 1.5601e-04 -2.6365e-03 6.1254e-05 2.9978e-04 -6.0000e+00 8.7804e-03 5.5426e-03 0.0000e+00 12 9 8 11 8 0 98.61 24.20 -0.24 0.00554 -0.01427 20 2 1 5 0 2785.580 33.25 20.07 24.20 19.72 3.5 889.67 99892 91010 193146 95118 76774 81608 25193 6830 9847 8183 -31664 -46369 13647 15481 51043 61082 65008 77320 70515 58700 92666 58164 51322 30587 12291 -2281 -14928 -14836 8364 39137 35873 46328 50153 57431 43280 36085 31203 25545 14658 5875 -2554 -1051 4638 14177 18329 27048 35906 31891 38579 36564 35566 29087 -108465 25519 19953 6253 5461 -3212 -742 2936 10609 15515 16598 20743 19324 20501 18177 15182 11616 11269 8016 7051 4153 3008 1261 55 1246 -1953 2259 6638 6795 6465 5463 1975 673 -340 566 976 988 3401 2295 1060 -1883 -3460 -1970 -1439 2353 3912 4927 5485 5969 3524 -348 -2941 -3399 -3983 -4421 -3153 -3390 -1459 -1059 -1002 -872 -1685 -1782 -2625 -1532 -1076 -1454 -1090 -460 -1334 -1495 -1688 -2000 -2095 -1381 -894 -411 600 1494 1970 1034 1404 783 396 215 282 858 1303 524 546 -483 2620 3249 2768 3557 2983 2517 1126 315 392 292 -1523 -2883 686 1181 3868 5340 6347 7455 7878 7655 8529 6922 5721 3528 1445 -284 -2077 -2165 1083 4439 5384 7820 9476 10684 8524 7002 6441 5454 3799 1780 -875 -370 1673 5096 6843 10068 13025 12596 14574 14321 14825 12745 -131475 12473 10116 3442 2885 -1766 -388 1528 5567 8814 9898 13369 13328 13362 11287 9351 7724 8484 6285 5710 3373 2315 972 38 780 -1242 1520 5091 5609 5967 5073 1953 704 -381 620 1102 1121 3663 2473 1047 -1869 -3390 -1929 -1620 2775 4908 6748 7545 7637 4368 -400 -3420 -4253 -4994 -5811 -4327 -4718 -2189 -1633 -1613 -1378 -2675 -2617 -3867 -2221 -1538 -2227 -1674 -710 -2128 -2295 -2500 -2834 -3020 -1879 -1217 -615 941 2389 3292 1791 2400 1427 728 406 540 1652 2444 989 974 -833 SS 20250201T113620.3Z 9163.483568 65 1 54.55 2 73.55 103.26 113.45 101.33 0.00 1 0.00 1 0 25 1.505e-01 9.275e-02 1.173e-02 2.020e-03 4.067235e-01 9.885184e-04 4.517744e-03 -6.000000e+00 8.309338e-02 224.09 -2.00 3.03 -2.00 318.02 0.00e+00 2.188709e-02 1.768897e-04 1.076311e-03 -6.000000e+00 3.605003e-03 275.41 -2.00 20.00 -2.00 317.46 0.00e+00 3.478 0.000 302.00 328.00 3 4.7201e+00 2.6057e-03 3.2576e-02 -6.0000e+00 2.0540e-01 3.2629e-01 2.9454e-03 3.4105e-02 -6.0000e+00 2.2394e-01 -1.5004e-01 2.0039e-03 1.4002e-02 -6.0000e+00 1.3313e-01 5.2258e-03 1.0696e-03 1.8978e-02 -6.0000e+00 5.7142e-02 2.2746e-04 -4.4334e-04 5.2497e-05 1.3852e-04 -6.0000e+00 3.8125e-03 1.2986e-03 0.0000e+00 12 8 8 10 0 0 87.22 24.23 0.09 0.00130 -0.00203 24 2 1 5 0 2272.780 33.25 19.82 24.23 21.35 3.5 903.55 41524 23651 67781 31810 11213 25726 6287 -10966 1108 -503 -19477 -28733 -2862 -383 21743 22568 26365 32049 31634 21112 40077 21244 17229 9265 -254 -5392 -9374 -11267 2544 15326 17089 21438 23122 25580 17554 12658 12001 10162 4793 1267 -2066 -2017 868 6531 7559 11830 17139 13582 17019 16747 17621 14547 -88733 13073 10003 3771 3926 -1398 231 1611 5290 8872 9422 11912 9679 9956 8972 7512 6387 7579 4942 4660 3461 1934 1327 -68 593 -1848 1466 3425 3930 3379 2535 806 747 148 1126 1011 951 2162 1152 689 -926 -1496 386 433 1954 2519 3115 2860 2260 913 -1443 -2288 -2460 -3088 -3080 -1979 -2212 -653 -298 -216 -504 -1210 -1396 -1282 -1070 -496 -594 -550 -614 -1576 -1530 -1285 -1498 -1746 -1406 -43 237 785 717 996 510 941 844 683 420 699 766 889 -46 208 -329 1840 1472 2910 1873 711 1267 358 -747 68 -31 -1369 -2422 -244 -43 2505 3076 3832 4778 4594 3546 6173 3420 2746 1531 -45 -985 -1779 -2171 437 2774 3259 4606 5544 6270 4309 3087 3111 3041 1606 496 -897 -920 408 3045 3621 5670 7975 6643 8098 8128 9015 7672 -100501 7735 6158 2441 2513 -856 146 1014 3390 5644 6702 9123 7302 7551 6387 5276 4819 6009 4389 4016 3169 1703 1081 -53 422 -1309 1088 2714 3554 3206 2595 819 803 171 1278 1186 1118 2428 1281 743 -928 -1469 402 482 2306 3167 4232 3890 2881 1116 -1743 -2649 -3087 -3908 -4069 -2720 -3084 -976 -456 -342 -781 -1865 -1985 -1797 -1489 -718 -874 -858 -926 -2457 -2301 -1857 -2175 -2432 -1848 -59 337 1168 1093 1576 831 1590 1448 1184 748 1266 1399 1583 -82 352 -541 SS 20250201T114653.0Z 9163.490891 68 1 31.71 2 71.08 102.69 111.09 100.38 0.00 1 0.00 1 0 17 9.159e-02 7.404e-02 9.349e-03 2.452e-03 3.603626e-01 1.201329e-03 3.941155e-03 -6.000000e+00 5.056329e-02 224.09 -2.00 3.03 -2.00 317.48 0.00e+00 1.213471e-02 1.817044e-04 5.900589e-04 -6.000000e+00 2.193951e-03 275.41 -2.00 20.00 -2.00 316.91 0.00e+00 3.051 0.000 302.00 328.00 3 4.9238e+00 3.1369e-03 2.6943e-02 -6.0000e+00 1.2499e-01 2.0899e-01 3.5337e-03 2.2629e-02 -6.0000e+00 1.3627e-01 -7.7197e-02 2.2311e-03 9.4838e-03 -6.0000e+00 8.1015e-02 -1.2744e-02 1.1495e-03 1.0057e-02 -6.0000e+00 3.4768e-02 2.8110e-04 -9.1584e-05 6.4907e-05 7.8429e-05 -6.0000e+00 2.3204e-03 2.2278e-03 0.0000e+00 12 9 9 12 1 1 59.69 24.26 -0.01 0.00223 0.00154 10 2 1 5 0 2882.520 33.25 19.88 24.26 22.34 3.4 908.38 17969 8115 32209 11095 2433 6123 -650 -8536 -2587 -6214 -16207 -19463 -4108 -2183 9764 11937 12931 14806 13219 7804 19041 10956 9689 5118 85 -4411 -4806 -7105 1308 6831 8260 9312 12276 12215 5613 5820 6437 5111 2966 550 -979 -1063 905 3016 4681 7526 9601 7780 9638 10624 10587 9988 -74502 7971 6624 2581 3863 -180 1237 1865 4152 6002 5811 8928 6107 7074 5446 4175 4801 5625 3750 3819 2512 1963 899 -91 -84 -846 1049 2737 2280 2253 1552 33 -42 239 1074 767 832 1606 496 780 -776 -1050 404 838 1174 2320 2543 1733 1221 -406 -1999 -1629 -1857 -2330 -2317 -1830 -1561 -156 -203 -97 -212 -694 -982 -1241 -427 -478 -507 -621 -385 -1213 -1176 -1031 -1101 -1575 -1146 -69 647 790 383 896 243 723 659 655 496 710 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