File name: Pandora283s1_LaPaz_20250203_L2Fit_fout2c4d20241004p1-8.txt File generation date: 20250624T083057.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 283 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora283_OF_v3d20231025.txt Instrument calibration file used: Pandora283s1_CF_v4d20241004.txt Level 1 file used: Pandora283s1_LaPaz_20250203_L1_smca1c4d20241004p1-8.txt Full location name: Laboratory for Atmospheric Physics, UMSA, La Paz Short location name: LaPaz Country of location: Bolivia Location latitude [deg]: -16.5389 Location longitude [deg]: -68.0661 Location altitude [m]: 3420 Local noon date: 20250203 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 203 345 Nominal wavelengths inside fitting window [nm]: 305.0638 305.2044 305.3451 305.4858 305.6264 305.7671 305.9077 306.0483 306.1889 306.3295 306.4701 306.6107 306.7513 306.8918 307.0324 307.1729 307.3134 307.4539 307.5944 307.7349 307.8754 308.0158 308.1563 308.2967 308.4371 308.5776 308.7180 308.8584 308.9988 309.1391 309.2795 309.4198 309.5602 309.7005 309.8408 309.9811 310.1214 310.2617 310.4020 310.5422 310.6825 310.8227 310.9630 311.1032 311.2434 311.3836 311.5237 311.6639 311.8041 311.9442 312.0844 312.2245 312.3646 312.5047 312.6448 312.7849 312.9249 313.0650 313.2050 313.3451 313.4851 313.6251 313.7651 313.9051 314.0451 314.1851 314.3250 314.4650 314.6049 314.7448 314.8847 315.0246 315.1645 315.3044 315.4442 315.5841 315.7239 315.8638 316.0036 316.1434 316.2832 316.4230 316.5627 316.7025 316.8423 316.9820 317.1217 317.2614 317.4011 317.5408 317.6805 317.8202 317.9598 318.0995 318.2391 318.3787 318.5184 318.6580 318.7976 318.9371 319.0767 319.2163 319.3558 319.4953 319.6348 319.7744 319.9139 320.0533 320.1928 320.3323 320.4717 320.6112 320.7506 320.8900 321.0294 321.1688 321.3082 321.4476 321.5869 321.7263 321.8656 322.0049 322.1442 322.2835 322.4228 322.5621 322.7014 322.8406 322.9799 323.1191 323.2583 323.3975 323.5367 323.6759 323.8151 323.9543 324.0934 324.2325 324.3717 324.5108 324.6499 324.7890 324.9281 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20250203T112925.9Z 9165.478772 411 1 29.52 2 75.34 103.07 141.17 94.64 0.00 1 0.00 1 0 25 2.955e-01 1.177e-01 3.012e-02 3.231e-03 4.485140e-01 1.586523e-03 5.030963e-03 -6.000000e+00 1.630056e-01 224.11 -2.00 3.03 -2.00 318.52 0.00e+00 3.919558e-02 3.304645e-04 1.732053e-03 -6.000000e+00 7.076221e-03 275.41 -2.00 20.00 -2.00 317.98 0.00e+00 3.878 0.000 302.00 328.00 3 4.4910e+00 4.1913e-03 4.1535e-02 -6.0000e+00 4.0294e-01 5.2266e-01 4.7587e-03 5.4101e-02 -6.0000e+00 4.3943e-01 -2.9946e-01 3.5179e-03 2.3353e-02 -6.0000e+00 2.6124e-01 5.2107e-02 1.9223e-03 3.4514e-02 -6.0000e+00 1.1203e-01 1.8531e-04 -2.2878e-03 8.0452e-05 2.4517e-04 -6.0000e+00 7.4870e-03 6.8749e-03 0.0000e+00 12 9 9 12 1 1 93.30 24.30 -0.08 0.00687 -0.01032 10 2 1 5 0 2682.580 33.00 19.87 24.30 21.71 3.7 904.58 94931 77259 156454 68363 64739 66688 40822 15415 25142 1802 -24261 -12267 262 15378 40987 52277 60200 65694 61745 53821 76800 52913 46635 23405 14517 -10025 -13486 -8713 3947 29223 31056 41714 44699 43660 36719 36845 26837 22959 11211 6534 -3188 -805 1915 7401 14438 20131 29211 27163 32174 30837 30919 26853 -102774 22952 15928 6612 4174 -2002 -1093 2529 8526 12407 14338 17093 17384 17674 15167 12989 10184 10102 7848 6694 4737 1711 1321 -106 491 -1220 2931 5880 4969 5843 4077 1430 606 -58 1140 1201 957 2956 1715 868 -2333 -2730 -1277 -527 2303 3491 4223 5278 4422 2893 -563 -2861 -3625 -3852 -3996 -2477 -3062 -1104 -1291 -225 -877 -1549 -2180 -2517 -1693 -1018 -1440 -1016 -198 -1411 -1148 -1744 -1463 -1944 -1996 -743 -458 662 1364 1146 925 1174 699 622 318 511 1270 1162 375 119 -207 2453 2922 2958 3038 2591 2228 1518 666 911 75 -1208 -603 16 1221 3475 4959 6052 6935 7316 7175 8108 6570 5526 3054 1825 -1510 -2087 -1332 581 3886 5079 7532 8234 8581 7122 7269 5459 5301 3228 2143 -1109 -286 716 2838 5524 7830 10932 10765 12353 12204 12927 12602 -123652 12158 8263 3610 2250 -1104 -583 1334 4578 7237 9374 12183 12029 12502 10240 8656 7318 7636 6596 5448 3843 1440 1022 -74 335 -831 2104 4507 4151 5390 4088 1422 637 -65 1254 1366 1096 3422 1863 863 -2328 -2661 -1333 -590 2719 4397 5798 7216 5692 3568 -646 -3329 -4567 -4862 -5272 -3400 -4284 -1661 -2008 -361 -1389 -2328 -3205 -3487 -2443 -1448 -2197 -1557 -305 -2135 -1754 -2583 -2060 -2784 -2716 -1005 -681 1029 2166 1910 1586 1993 1264 1135 595 973 2424 2171 672 212 -355 SU 20250203T113137.6Z 9165.480296 414 1 53.99 2 74.83 102.94 140.67 94.43 0.00 1 0.00 1 0 17 4.716e-02 7.858e-03 1.226e-02 1.659e-03 4.165214e-01 8.138563e-04 4.271458e-03 -6.000000e+00 2.604378e-02 224.11 -2.00 3.03 -2.00 318.40 0.00e+00 1.411042e-03 1.605329e-04 2.275072e-04 -6.000000e+00 1.129604e-03 275.41 -2.00 20.00 -2.00 317.82 0.00e+00 3.755 0.000 302.00 328.00 3 4.3508e+00 2.1845e-03 3.0856e-02 -6.0000e+00 6.4380e-02 -3.6552e-04 2.4895e-03 1.8182e-02 -6.0000e+00 7.0185e-02 -7.4574e-03 1.7432e-03 9.1927e-03 -6.0000e+00 4.1724e-02 9.8319e-05 9.3247e-04 2.9997e-03 -6.0000e+00 1.7913e-02 3.2972e-04 1.0508e-04 4.4164e-05 2.8412e-05 -6.0000e+00 1.1944e-03 -4.3216e-04 0.0000e+00 11 9 0 11 8 0 99.94 24.30 0.26 -0.00043 0.00036 52 5 1 5 0 1038.200 33.00 20.12 24.30 21.86 3.6 905.51 -5435 -21804 27573 -18735 -19500 -6742 -15286 -10321 -1292 2169 -7236 -8885 -8398 -7570 -3911 -3214 -1632 2452 1045 -7725 6817 311 543 -469 1376 1887 -2275 -5581 -4194 -661 -1681 -1028 -595 1163 -5409 -4847 -3420 -1330 -2061 -987 -1859 130 -45 462 659 933 1580 -1858 488 350 1670 2200 1238 2427 1617 339 2102 520 764 -122 987 1603 2063 2935 760 71 -897 -744 43 1116 85 782 603 171 440 -869 -1084 -2226 -1946 -1125 -1267 -1520 -1233 -2086 -1592 -795 180 433 542 1250 611 645 -375 -307 866 -168 291 525 324 90 -478 -756 -1575 -1125 -815 -996 -1066 -394 -29 492 658 699 537 246 -12 -246 -260 -15 -76 152 474 237 498 236 617 98 -6 744 567 843 165 -15 -570 -115 29 159 -108 261 337 -134 -372 -615 -691 -203 -1086 879 -900 -842 -247 -655 -484 -63 108 -398 -529 -592 -645 -386 -361 -195 300 138 -1058 911 44 78 -74 208 299 -377 -910 -706 -109 -285 -198 -128 259 -1208 -1043 -792 -358 -627 -352 -743 54 -19 202 289 412 692 -842 217 161 753 1084 663 1372 961 195 1221 306 436 -74 568 998 1423 2056 560 50 -635 -521 30 892 71 678 522 142 359 -643 -781 -1567 -1462 -906 -1100 -1485 -1223 -2188 -1674 -889 211 495 619 1446 661 677 -367 -295 889 -186 343 661 442 123 -614 -925 -1890 -1365 -1017 -1321 -1406 -543 -40 744 1026 1129 852 369 -17 -354 -371 -21 -116 233 734 359 762 349 868 139 -9 997 832 1296 262 -25 -930 -195 50 290 -194 478 621 -251 -665 -1092 -1185 SU 20250203T113340.4Z 9165.481717 417 1 54.52 2 74.35 102.83 140.20 94.23 0.00 1 0.00 1 0 17 2.970e-02 7.409e-03 5.089e-03 1.000e-03 4.063372e-01 4.916286e-04 4.189399e-03 -6.000000e+00 1.640357e-02 224.11 -2.00 3.03 -2.00 317.92 0.00e+00 1.302976e-03 8.366864e-05 2.345629e-04 -6.000000e+00 7.114905e-04 275.41 -2.00 20.00 -2.00 317.34 0.00e+00 3.647 0.000 302.00 328.00 3 3.5349e+00 1.3044e-03 2.9987e-02 -6.0000e+00 4.0550e-02 -7.9547e-03 1.4741e-03 1.7657e-02 -6.0000e+00 4.4206e-02 -9.6237e-03 9.6472e-04 8.8738e-03 -6.0000e+00 2.6280e-02 1.8267e-03 5.0746e-04 2.8024e-03 -6.0000e+00 1.1282e-02 8.1412e-04 9.1967e-05 2.6509e-05 2.7251e-05 -6.0000e+00 7.5233e-04 -2.7261e-04 0.0000e+00 11 8 0 10 0 0 99.86 24.30 0.27 -0.00027 0.00042 71 7 1 5 0 767.830 33.25 20.02 24.30 21.93 3.6 906.02 -8211 -8329 6907 -6830 -13002 -10834 -12595 -9544 -5445 -1135 -6444 -11696 -5781 -4049 -1382 -1639 30 1463 450 -1195 3667 -880 2478 1352 1619 286 -1112 -3218 -2237 -1626 -783 -50 -798 432 -3834 -4019 -3146 -1599 -323 -8 -875 -373 -17 323 645 1039 1011 -441 -359 711 1068 1125 122 1589 1573 858 1673 488 405 338 1078 1540 2283 2615 1073 51 -501 -692 9 909 512 657 338 83 143 -831 -1132 -2391 -2098 -1092 -1445 -1405 -1573 -1837 -1351 -663 -1 391 676 996 694 284 -241 -563 -64 -257 326 763 420 -58 -543 -994 -1373 -1100 -938 -939 -903 -342 12 594 695 853 631 385 -168 -159 47 202 187 220 75 146 497 547 254 335 166 633 618 457 136 133 -350 -190 -74 -36 12 195 108 -74 -437 -518 -610 -473 -542 404 -434 -783 -613 -780 -659 -408 -87 -520 -1055 -583 -443 -176 -239 5 238 78 -221 663 -165 461 274 323 61 -240 -674 -481 -352 -171 -12 -224 126 -1091 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