File name: Pandora283s1_LaPaz_20250306_L2Fit_fout2c2d20240531p1-8.txt File generation date: 20250307T101018.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 283 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora283_OF_v3d20231025.txt Instrument calibration file used: Pandora283s1_CF_v2d20240531.txt Level 1 file used: Pandora283s1_LaPaz_20250306_L1_smca1c2d20240531p1-8.txt Full location name: Laboratory for Atmospheric Physics, UMSA, La Paz Short location name: LaPaz Country of location: Bolivia Location latitude [deg]: -16.5389 Location longitude [deg]: -68.0661 Location altitude [m]: 3420 Local noon date: 20250306 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 203 345 Nominal wavelengths inside fitting window [nm]: 305.0233 305.1640 305.3046 305.4453 305.5860 305.7266 305.8672 306.0078 306.1485 306.2891 306.4296 306.5702 306.7108 306.8513 306.9919 307.1324 307.2729 307.4134 307.5539 307.6944 307.8349 307.9754 308.1158 308.2563 308.3967 308.5371 308.6775 308.8179 308.9583 309.0987 309.2390 309.3794 309.5197 309.6600 309.8004 309.9407 310.0810 310.2213 310.3615 310.5018 310.6420 310.7823 310.9225 311.0627 311.2029 311.3431 311.4833 311.6235 311.7636 311.9038 312.0439 312.1840 312.3242 312.4643 312.6044 312.7444 312.8845 313.0246 313.1646 313.3046 313.4447 313.5847 313.7247 313.8647 314.0046 314.1446 314.2846 314.4245 314.5644 314.7044 314.8443 314.9842 315.1241 315.2639 315.4038 315.5437 315.6835 315.8233 315.9631 316.1029 316.2427 316.3825 316.5223 316.6621 316.8018 316.9416 317.0813 317.2210 317.3607 317.5004 317.6401 317.7797 317.9194 318.0590 318.1987 318.3383 318.4779 318.6175 318.7571 318.8967 319.0362 319.1758 319.3153 319.4549 319.5944 319.7339 319.8734 320.0129 320.1524 320.2918 320.4313 320.5707 320.7101 320.8495 320.9890 321.1283 321.2677 321.4071 321.5465 321.6858 321.8251 321.9645 322.1038 322.2431 322.3824 322.5216 322.6609 322.8002 322.9394 323.0786 323.2178 323.3570 323.4962 323.6354 323.7746 323.9138 324.0529 324.1920 324.3312 324.4703 324.6094 324.7485 324.8876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20250306T124918.6Z 9196.534243 1014 1 56.14 2 58.33 86.16 145.08 65.42 0.00 1 0.00 1 0 17 6.512e-02 7.257e-02 3.115e-03 1.788e-03 2.338161e-01 8.864339e-04 2.568901e-03 -6.000000e+00 3.609207e-02 224.72 -2.00 3.03 -2.00 315.59 0.00e+00 5.784656e-03 8.458970e-05 2.912957e-04 -6.000000e+00 1.562781e-03 275.31 -2.00 20.00 -2.00 315.07 0.00e+00 1.898 0.000 302.00 328.00 3 5.8391e+00 2.2664e-03 1.6835e-02 -6.0000e+00 8.9338e-02 1.8220e-01 2.5294e-03 1.3034e-02 -6.0000e+00 9.7356e-02 -4.1758e-02 1.4672e-03 5.4853e-03 -6.0000e+00 5.7848e-02 -2.5945e-02 6.7752e-04 4.4402e-03 -6.0000e+00 2.4787e-02 3.0344e-04 2.9359e-04 4.8031e-05 3.3002e-05 -6.0000e+00 1.6591e-03 3.6431e-02 -2.0832e-04 12 9 8 11 8 0 80.11 24.39 -0.06 0.03643 0.03864 16 2 1 5 0 3508.620 33.25 20.05 24.39 25.07 3.7 929.84 2022 2570 5178 1400 -2838 499 -5065 -5365 -7434 -8138 -10619 -10024 -3291 -1750 4293 3035 4369 5960 5298 6204 9213 3836 3846 1820 46 -2610 -3286 -4817 506 2411 3901 6141 7743 6559 2148 1855 2769 4556 2771 2165 510 -422 1222 2516 2846 3862 5488 4170 5873 5029 6987 6320 -64580 6032 4740 3834 4479 1503 1977 2128 3632 4474 5076 5782 4103 3332 3721 3166 4312 5113 3374 3508 2371 2423 1236 523 -240 -766 124 1641 1589 1954 793 78 532 251 1001 868 814 970 210 80 -1364 -817 1106 872 1345 1963 1545 946 269 -885 -1713 -1529 -1747 -1947 -2131 -1335 -1559 -74 -66 5 244 -579 -925 -665 -184 -36 -161 -244 -190 -1347 -1237 -1339 -1294 -1431 -1694 32 281 517 509 176 280 1025 1049 672 1112 971 856 748 -165 -519 -537 489 677 1352 351 -648 103 -1134 -1326 -2033 -2274 -2927 -2816 -993 -613 1503 1184 1748 2428 2253 2698 3933 1680 1670 825 22 -1298 -1623 -2282 215 994 1694 2847 3831 3345 1052 874 1391 2410 1773 1482 382 -310 908 1870 2114 2855 4200 3143 4228 3628 5168 4692 -80740 4905 3966 3257 3808 1300 1661 1775 3086 3812 4681 5643 4057 3034 3266 2675 3816 4781 3296 3550 2412 2366 1207 490 -203 -610 101 1498 1528 2057 843 87 590 299 1254 1063 997 1208 243 88 -1470 -836 1167 959 1542 2477 1981 1205 340 -1025 -1984 -1818 -2141 -2533 -2738 -1773 -2169 -103 -97 7 346 -807 -1177 -829 -226 -46 -210 -342 -259 -1841 -1726 -1796 -1735 -1830 -2043 40 351 695 682 242 389 1462 1506 1023 1733 1475 1316 1131 -256 -773 -778 SU 20250306T125146.6Z 9196.535956 1017 1 33.45 2 57.74 85.96 144.57 65.58 0.00 1 0.00 1 0 17 3.906e-02 3.886e-02 2.728e-03 1.703e-03 2.151829e-01 8.447732e-04 2.308964e-03 -6.000000e+00 2.165156e-02 224.72 -2.00 3.03 -2.00 315.32 0.00e+00 2.694699e-03 7.650632e-05 1.281240e-04 -6.000000e+00 9.374419e-04 275.31 -2.00 20.00 -2.00 314.82 0.00e+00 1.867 0.000 302.00 328.00 3 5.3262e+00 2.1572e-03 1.5729e-02 -6.0000e+00 5.3594e-02 7.7683e-02 2.4073e-03 1.0140e-02 -6.0000e+00 5.8402e-02 -1.6607e-02 1.3895e-03 4.7661e-03 -6.0000e+00 3.4702e-02 -1.4514e-02 6.3241e-04 2.3416e-03 -6.0000e+00 1.4870e-02 5.6034e-04 2.4846e-04 4.5660e-05 1.9923e-05 -6.0000e+00 9.9516e-04 3.6648e-02 -1.7921e-04 12 9 9 12 1 1 99.79 24.40 0.26 0.03665 0.03851 13 2 1 5 0 2388.720 33.25 20.04 24.40 25.22 3.7 932.28 306 202 2401 -1564 -2734 -1172 -2837 -1730 -2797 -3101 -5038 -6169 -2399 -932 1853 1812 2086 2781 3241 3327 5131 1621 2309 2040 262 -444 -1006 -2915 57 2010 2419 3820 3050 2682 -163 -517 511 1592 865 1224 -109 -467 77 326 1140 1216 2081 1321 1964 1763 3148 2943 -40880 3275 2559 2095 2524 1157 962 1054 1875 2774 2706 3652 2174 1348 794 796 2303 2750 1870 2182 1266 1177 595 -75 -384 -1464 -239 -5 159 182 -521 -954 -288 -60 381 255 562 870 474 247 -421 -453 463 470 705 1167 945 302 -117 -655 -1242 -1178 -954 -1222 -1351 -864 -779 145 247 412 215 -279 -477 -409 -170 -101 -56 269 -128 -511 -310 -440 -235 -270 -420 288 416 556 207 28 -128 764 420 304 535 550 447 203 -256 -388 -913 85 61 715 -447 -691 -299 -769 -476 -856 -978 -1563 -1961 -826 -338 745 795 941 1190 1428 1512 2324 744 1054 971 133 -232 -523 -1447 26 930 1175 1838 1598 1437 -83 -253 268 899 553 846 -82 -370 59 250 916 977 1620 1004 1436 1282 2359 2364 -43319 2717 2181 1817 2207 1016 827 899 1635 2441 2588 3495 2101 1263 715 686 2073 2658 1895 2295 1340 1202 570 -68 -330 -1260 -198 -5 157 188 -550 -1049 -320 -72 459 317 698 1041 551 273 -442 -453 481 512 810 1412 1223 389 -148 -757 -1422 -1390 -1170 -1524 -1759 -1165 -1050 206 354 598 300 -377 -614 -511 -209 -129 -74 365 -180 -714 -420 -599 -303 -345 -506 357 522 717 282 37 -173 1056 593 453 819 829 682 306 -388 -566 -1303 SU 20250306T125409.0Z 9196.537605 1020 1 54.46 2 57.17 85.76 144.07 65.72 0.00 1 0.00 1 0 17 9.910e-03 7.159e-03 1.798e-03 1.158e-03 1.990731e-01 5.767467e-04 2.100939e-03 -6.000000e+00 5.494880e-03 224.72 -2.00 3.03 -2.00 315.20 0.00e+00 5.698044e-04 5.081044e-05 1.900677e-05 -6.000000e+00 2.378316e-04 275.31 -2.00 20.00 -2.00 314.70 0.00e+00 1.839 0.000 302.00 328.00 3 5.2204e+00 1.4730e-03 1.4984e-02 -6.0000e+00 1.3602e-02 1.8057e-03 1.6433e-03 8.6686e-03 -6.0000e+00 1.4820e-02 2.9706e-04 9.4428e-04 4.2927e-03 -6.0000e+00 8.8060e-03 -4.2697e-03 4.2710e-04 1.2785e-03 -6.0000e+00 3.7746e-03 6.7525e-04 3.2406e-04 3.1018e-05 1.5029e-05 -6.0000e+00 2.5241e-04 3.5914e-02 -1.1360e-04 11 9 0 11 32 0 95.56 24.41 0.36 0.03591 0.03835 26 3 1 5 0 2094.240 33.25 19.90 24.41 25.50 3.7 934.56 878 -657 989 -1611 -3918 -2080 -1444 -87 123 -852 -2151 -2523 401 -255 1312 488 259 172 530 1232 1978 404 904 1134 1232 1046 105 -738 -391 436 930 960 1422 -101 -2894 -3404 -2182 -961 -828 33 -525 -678 -674 -377 -317 -345 -101 -1015 -681 71 397 593 871 1158 685 569 1336 401 184 62 983 1341 1663 1887 279 -462 -624 -751 67 951 581 640 244 583 510 -94 -828 -1530 -1597 -1317 -1223 -1269 -1731 -1725 -942 -254 -46 398 513 792 573 406 -403 -409 271 30 284 692 541 -36 -388 -818 -1296 -748 -760 -652 -804 -432 -349 378 479 856 508 33 -214 -42 -196 165 29 271 309 144 414 539 532 344 134 650 397 707 204 -22 -249 79 30 -241 144 151 174 -153 -397 -550 -849 260 -214 319 -491 -1069 -524 -382 -26 41 -292 -723 -854 135 -98 562 212 116 79 249 594 963 196 440 578 618 543 54 -385 -188 200 443 491 727 -54 -1558 -1770 -1131 -577 -561 24 -397 -534 -544 -305 -254 -277 -79 -770 -498 54 296 473 729 958 582 492 1167 351 158 53 853 1182 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