File name: Pandora283s1_LaPaz_20250318_L2Fit_fout2c4d20241004p1-8.txt File generation date: 20250624T083622.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 283 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora283_OF_v3d20231025.txt Instrument calibration file used: Pandora283s1_CF_v4d20241004.txt Level 1 file used: Pandora283s1_LaPaz_20250318_L1_smca1c4d20241004p1-8.txt Full location name: Laboratory for Atmospheric Physics, UMSA, La Paz Short location name: LaPaz Country of location: Bolivia Location latitude [deg]: -16.5389 Location longitude [deg]: -68.0661 Location altitude [m]: 3420 Local noon date: 20250318 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 203 345 Nominal wavelengths inside fitting window [nm]: 305.0638 305.2044 305.3451 305.4858 305.6264 305.7671 305.9077 306.0483 306.1889 306.3295 306.4701 306.6107 306.7513 306.8918 307.0324 307.1729 307.3134 307.4539 307.5944 307.7349 307.8754 308.0158 308.1563 308.2967 308.4371 308.5776 308.7180 308.8584 308.9988 309.1391 309.2795 309.4198 309.5602 309.7005 309.8408 309.9811 310.1214 310.2617 310.4020 310.5422 310.6825 310.8227 310.9630 311.1032 311.2434 311.3836 311.5237 311.6639 311.8041 311.9442 312.0844 312.2245 312.3646 312.5047 312.6448 312.7849 312.9249 313.0650 313.2050 313.3451 313.4851 313.6251 313.7651 313.9051 314.0451 314.1851 314.3250 314.4650 314.6049 314.7448 314.8847 315.0246 315.1645 315.3044 315.4442 315.5841 315.7239 315.8638 316.0036 316.1434 316.2832 316.4230 316.5627 316.7025 316.8423 316.9820 317.1217 317.2614 317.4011 317.5408 317.6805 317.8202 317.9598 318.0995 318.2391 318.3787 318.5184 318.6580 318.7976 318.9371 319.0767 319.2163 319.3558 319.4953 319.6348 319.7744 319.9139 320.0533 320.1928 320.3323 320.4717 320.6112 320.7506 320.8900 321.0294 321.1688 321.3082 321.4476 321.5869 321.7263 321.8656 322.0049 322.1442 322.2835 322.4228 322.5621 322.7014 322.8406 322.9799 323.1191 323.2583 323.3975 323.5367 323.6759 323.8151 323.9543 324.0934 324.2325 324.3717 324.5108 324.6499 324.7890 324.9281 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20250318T120009.0Z 9208.500104 321 1 26.21 2 70.67 84.84 65.01 255.68 0.00 1 0.00 1 0 17 9.456e-02 8.075e-02 9.371e-03 2.784e-03 3.438070e-01 1.367218e-03 3.765243e-03 -6.000000e+00 5.234081e-02 224.99 -2.00 3.03 -2.00 317.25 0.00e+00 1.190883e-02 1.938977e-04 6.002121e-04 -6.000000e+00 2.262822e-03 275.21 -2.00 20.00 -2.00 316.68 0.00e+00 2.989 0.000 302.00 328.00 3 4.9892e+00 3.5582e-03 2.6178e-02 -6.0000e+00 1.2965e-01 2.3515e-01 4.0031e-03 2.1840e-02 -6.0000e+00 1.4130e-01 -7.5541e-02 2.4806e-03 8.9885e-03 -6.0000e+00 8.3937e-02 -2.1574e-02 1.2568e-03 9.6044e-03 -6.0000e+00 3.5923e-02 2.7821e-04 -3.7510e-04 7.4037e-05 7.4250e-05 -6.0000e+00 2.3965e-03 6.6142e-03 0.0000e+00 12 9 9 12 9 1 99.94 24.23 0.02 0.00661 0.00380 8 2 1 5 0 2911.090 33.00 20.21 24.23 22.78 3.7 912.53 22526 9306 29618 8522 12150 3382 -1364 -10291 -6722 -8316 -19344 -18022 -4666 -1984 9617 9341 10613 13815 13157 14692 18595 9283 7786 5701 -509 -5052 -7344 -5904 -434 4756 7356 10806 12767 13752 5896 8592 6090 7166 2880 1481 -432 -759 659 3061 5673 6338 9254 8700 10339 10074 10694 10070 -76676 9435 6302 3450 4045 576 1748 1366 4394 6021 6775 7854 7319 6499 5769 4638 5243 5811 4182 3847 2814 1788 1902 571 578 -523 998 2776 2815 2757 1836 383 795 624 1198 1309 1334 1372 255 686 -1325 -1397 851 970 1431 2408 2602 1494 1327 -399 -1516 -2112 -1927 -2244 -2643 -1871 -1473 -829 -188 -108 -336 -1072 -1090 -1249 -320 -436 -241 -334 -1179 -1284 -1084 -1444 -1608 -1653 -1492 116 134 238 584 438 295 974 1093 558 863 899 868 656 -10 -105 -52 1920 1028 2798 937 1131 318 -135 -1193 -799 -1011 -2547 -2495 -694 -329 1728 1932 2331 3126 3163 3615 4456 2360 1971 1482 -142 -1496 -2217 -1700 -116 1253 2126 3430 4058 4486 1921 2844 2032 2732 1251 746 -240 -412 368 1718 3157 3585 5096 4795 5994 5918 6148 6294 -88929 6572 4300 2429 2839 412 1205 944 3073 4530 5256 6554 6237 5186 4565 3602 4315 5089 3824 3655 2671 1634 1703 462 450 -395 792 2335 2692 2751 1863 409 899 716 1441 1622 1652 1639 284 731 -1388 -1421 906 1095 1714 3041 3534 2035 1685 -490 -1736 -2477 -2452 -2878 -3550 -2489 -2064 -1190 -287 -169 -512 -1536 -1500 -1691 -427 -608 -342 -482 -1751 -1871 -1598 -2055 -2288 -2249 -1914 155 184 340 886 658 452 1543 1757 952 1444 1535 1496 1109 -18 -170 -86 SU 20250318T120315.5Z 9208.502263 327 1 7.66 2 69.93 84.59 65.71 255.54 0.00 1 0.00 1 0 17 6.780e-02 5.962e-02 1.490e-02 5.046e-03 3.230028e-01 2.477174e-03 3.432928e-03 -6.000000e+00 3.756642e-02 224.99 -2.00 3.03 -2.00 317.00 0.00e+00 8.382632e-03 3.309876e-04 2.575525e-04 -6.000000e+00 1.622656e-03 275.21 -2.00 20.00 -2.00 316.44 0.00e+00 2.885 0.000 302.00 328.00 3 4.8432e+00 6.4485e-03 2.4357e-02 -6.0000e+00 9.3052e-02 1.5040e-01 7.2418e-03 1.7607e-02 -6.0000e+00 1.0138e-01 -4.2732e-02 4.3895e-03 7.8808e-03 -6.0000e+00 6.0224e-02 -1.8847e-02 2.1930e-03 6.8714e-03 -6.0000e+00 2.5804e-02 3.7128e-04 7.3380e-04 1.3431e-04 5.3879e-05 -6.0000e+00 1.7175e-03 -7.0708e-04 0.0000e+00 12 9 9 12 1 1 999.00 24.24 0.08 -0.00071 0.00481 2 2 1 5 0 2553.130 33.00 20.20 24.24 22.97 3.7 914.32 12584 924 3394 1096 3612 335 -4921 3559 734 -7686 -13700 -16214 -4950 -3953 2782 9960 7010 6693 5419 9633 8370 8234 6771 1693 -156 -4038 -3549 -5745 1038 3970 2833 4643 9867 10650 1537 1728 2715 4941 -1070 5 -61 362 74 1190 2762 4009 5868 4113 7231 7175 6840 5966 -63219 5480 4583 2483 2323 501 2348 1145 4902 5212 4040 5359 4760 4388 3562 2785 4115 4318 3363 3132 1775 1968 1336 485 -255 -1698 454 1085 870 2049 205 -1300 780 -677 890 1050 266 539 550 570 -1251 -1463 324 521 1427 1665 1443 623 131 -943 -991 -1111 -1863 -1742 -2565 -1163 -972 -133 702 927 30 -997 -521 -1071 -635 392 -59 377 -715 -1114 -111 -628 -179 -1154 -974 -431 172 197 68 -68 359 1182 751 752 507 969 15 390 -468 -137 -396 1344 113 422 144 407 36 -579 420 96 -1120 -2063 -2401 -786 -764 602 2277 1759 1781 1409 2497 2231 2332 1932 477 -46 -1265 -1102 -1748 311 1179 865 1567 3504 3883 567 612 1027 1962 -538 3 -35 218 43 707 1635 2383 3411 2409 4351 4361 4129 3926 -66000 3776 3255 1817 1718 373 1672 822 3523 4069 3316 4702 4252 3644 2921 2234 3275 3920 3183 3084 1757 1858 1175 407 -206 -1333 370 948 817 1997 217 -1382 864 -776 1061 1289 330 642 637 630 -1283 -1537 339 577 1675 2081 1944 839 165 -1138 -1164 -1337 -2343 -2211 -3423 -1603 -1350 -189 1057 1426 46 -1476 -735 -1421 -832 532 -82 560 -1050 -1613 -160 -880 -248 -1542 -1285 -565 232 276 102 -101 539 1830 1192 1260 840 1633 25 653 -787 -219 -616 SU 20250318T120640.3Z 9208.504633 333 1 26.22 2 69.11 84.32 66.48 255.38 0.00 1 0.00 1 0 17 9.663e-02 8.744e-02 9.143e-03 3.081e-03 3.261628e-01 1.512729e-03 3.611515e-03 -6.000000e+00 5.347230e-02 224.99 -2.00 3.03 -2.00 317.02 0.00e+00 1.184332e-02 2.014911e-04 6.330994e-04 -6.000000e+00 2.312075e-03 275.21 -2.00 20.00 -2.00 316.44 0.00e+00 2.780 0.000 302.00 328.00 3 5.2954e+00 3.9283e-03 2.4771e-02 -6.0000e+00 1.3245e-01 2.5426e-01 4.4124e-03 2.1505e-02 -6.0000e+00 1.4437e-01 -7.2520e-02 2.6949e-03 8.4906e-03 -6.0000e+00 8.5759e-02 -2.7242e-02 1.3450e-03 9.3417e-03 -6.0000e+00 3.6693e-02 2.3897e-04 -5.5250e-04 8.2289e-05 6.8585e-05 -6.0000e+00 2.4491e-03 8.2456e-03 0.0000e+00 12 9 9 12 9 1 99.39 24.25 -0.15 0.00825 0.00409 6 2 1 5 0 3745.110 33.00 20.18 24.25 23.21 3.7 916.42 19858 8307 22991 3513 4192 7426 -8492 -1344 -11408 -13456 -15409 -22306 -3434 -3803 9397 11981 9590 14319 14279 16042 18157 10281 6643 4030 -1134 -5480 -4991 -6341 173 7535 6948 10854 12648 13747 5863 5987 6834 5871 2158 2047 -767 -1904 866 3596 5268 6524 9025 8222 11545 9276 10782 10148 -81952 9947 6587 4268 4243 1371 1474 1317 4333 5584 7683 7714 6863 6197 5756 5062 5782 6537 4639 4972 2579 2986 1009 371 1227 -644 1774 2947 3036 2940 2274 26 1286 -52 1704 1352 922 1728 464 655 -1557 -767 666 1141 1576 2967 2138 1368 1045 -354 -2062 -1717 -2238 -2029 -2800 -1651 -1548 -798 -350 24 -289 -1081 -805 -1441 -300 -117 -539 -726 -897 -1538 -1697 -1812 -1160 -2029 -1826 -382 -51 1127 271 453 723 890 856 809 682 1245 964 935 -254 403 -412 2011 1068 2667 465 484 765 -1031 -162 -1618 -1957 -2209 -3633 -565 -715 1876 2664 2339 3532 3709 4250 4766 2819 1851 1156 -345 -1763 -1590 -1978 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