File name: Pandora283s1_LaPaz_20250403_L2Fit_fout2c2d20240531p1-8.txt File generation date: 20250404T044050.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 283 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora283_OF_v3d20231025.txt Instrument calibration file used: Pandora283s1_CF_v2d20240531.txt Level 1 file used: Pandora283s1_LaPaz_20250403_L1_smca1c2d20240531p1-8.txt Full location name: Laboratory for Atmospheric Physics, UMSA, La Paz Short location name: LaPaz Country of location: Bolivia Location latitude [deg]: -16.5389 Location longitude [deg]: -68.0661 Location altitude [m]: 3420 Local noon date: 20250403 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 203 345 Nominal wavelengths inside fitting window [nm]: 305.0233 305.1640 305.3046 305.4453 305.5860 305.7266 305.8672 306.0078 306.1485 306.2891 306.4296 306.5702 306.7108 306.8513 306.9919 307.1324 307.2729 307.4134 307.5539 307.6944 307.8349 307.9754 308.1158 308.2563 308.3967 308.5371 308.6775 308.8179 308.9583 309.0987 309.2390 309.3794 309.5197 309.6600 309.8004 309.9407 310.0810 310.2213 310.3615 310.5018 310.6420 310.7823 310.9225 311.0627 311.2029 311.3431 311.4833 311.6235 311.7636 311.9038 312.0439 312.1840 312.3242 312.4643 312.6044 312.7444 312.8845 313.0246 313.1646 313.3046 313.4447 313.5847 313.7247 313.8647 314.0046 314.1446 314.2846 314.4245 314.5644 314.7044 314.8443 314.9842 315.1241 315.2639 315.4038 315.5437 315.6835 315.8233 315.9631 316.1029 316.2427 316.3825 316.5223 316.6621 316.8018 316.9416 317.0813 317.2210 317.3607 317.5004 317.6401 317.7797 317.9194 318.0590 318.1987 318.3383 318.4779 318.6175 318.7571 318.8967 319.0362 319.1758 319.3153 319.4549 319.5944 319.7339 319.8734 320.0129 320.1524 320.2918 320.4313 320.5707 320.7101 320.8495 320.9890 321.1283 321.2677 321.4071 321.5465 321.6858 321.8251 321.9645 322.1038 322.2431 322.3824 322.5216 322.6609 322.8002 322.9394 323.0786 323.2178 323.3570 323.4962 323.6354 323.7746 323.9138 324.0529 324.1920 324.3312 324.4703 324.6094 324.7485 324.8876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250403T113000.3Z 9224.479170 94 1 5.11 2 78.61 80.68 147.12 62.97 0.00 1 0.00 1 0 25 8.668e-02 7.870e-03 1.839e-02 2.224e-03 4.879255e-01 1.100091e-03 4.959705e-03 -6.000000e+00 4.811404e-02 225.22 -2.00 3.03 -2.00 318.63 0.00e+00 1.522648e-03 2.291049e-04 4.453965e-04 -6.000000e+00 2.077303e-03 275.01 -2.00 20.00 -2.00 318.05 0.00e+00 4.908 0.000 302.00 328.00 3 1.7318e+00 2.9744e-03 3.8948e-02 -6.0000e+00 1.1924e-01 8.9072e-03 3.4000e-03 2.1364e-02 -6.0000e+00 1.2992e-01 -2.1849e-02 2.4687e-03 1.0823e-02 -6.0000e+00 7.7153e-02 6.9568e-03 1.3233e-03 3.4864e-03 -6.0000e+00 3.3003e-02 1.9927e-03 -1.0772e-04 5.8284e-05 3.3581e-05 -6.0000e+00 2.2087e-03 3.9361e-02 -1.7487e-04 12 9 1 12 1 1 -47.01 24.20 0.33 0.03936 0.03855 20 23 1 5 0 242.990 33.25 19.76 24.20 19.62 3.6 887.00 -36061 -22039 -12877 -31331 -47095 -27489 -37577 -23482 -16084 -14527 -31218 -17390 -12298 -11622 -7646 -1901 1120 -2079 905 724 1078 -4130 2059 -2389 -4202 -2993 -2199 -5128 -2999 -1867 -859 1376 2580 1082 -4404 -4559 -2134 -2084 124 2046 62 495 -310 1115 1925 462 1312 -476 -394 527 850 1860 1996 2086 1019 1452 689 597 54 266 1489 1459 2224 2731 1086 396 -353 -476 516 894 423 1267 95 276 -582 -364 -669 -1262 -1159 -995 -1441 -1539 -1857 -2388 -1305 -1025 -334 207 448 1121 996 228 -322 -692 -228 18 165 340 292 -213 -664 -1073 -1497 -467 -1121 -978 -913 -458 -3 619 502 609 333 350 177 112 29 462 124 323 298 546 621 478 566 350 183 389 554 348 123 -121 -344 -63 8 -121 226 271 -101 -44 -634 -379 -688 -1282 -779 -438 -1223 -1940 -906 -1491 -937 -677 -643 -1665 -882 -723 -844 -652 -178 101 -210 95 80 122 -489 238 -314 -611 -453 -332 -764 -422 -269 -140 256 495 223 -904 -916 -460 -537 36 684 22 185 -122 442 762 189 535 -199 -168 217 382 916 998 1120 547 803 395 342 30 146 832 892 1431 1835 769 268 -242 -328 364 691 345 1071 81 223 -458 -269 -454 -891 -843 -803 -1228 -1417 -1786 -2430 -1346 -1130 -372 236 510 1222 1051 233 -322 -693 -238 19 198 430 387 -285 -861 -1299 -1733 -543 -1375 -1271 -1199 -612 -4 908 778 957 518 533 259 160 41 682 190 507 470 835 944 704 820 504 250 538 817 539 200 -202 -591 -110 15 -226 420 513 -193 -83 -1150 -683 -1200 SS 20250403T113425.6Z 9224.482241 97 1 54.41 2 77.57 80.32 146.22 63.35 0.00 1 0.00 1 0 25 4.865e-02 6.956e-03 1.875e-03 3.004e-04 4.551729e-01 1.480963e-04 4.649886e-03 -6.000000e+00 2.700268e-02 225.22 -2.00 3.03 -2.00 318.28 0.00e+00 1.198579e-03 2.762504e-05 3.092024e-04 -6.000000e+00 1.165861e-03 275.01 -2.00 20.00 -2.00 317.70 0.00e+00 4.524 0.000 302.00 328.00 3 4.5482e-01 3.9663e-04 3.6023e-02 -6.0000e+00 6.6922e-02 -8.0689e-04 4.5028e-04 1.9880e-02 -6.0000e+00 7.2914e-02 -1.9743e-02 3.0681e-04 9.9592e-03 -6.0000e+00 4.3300e-02 6.1551e-03 1.6289e-04 3.0679e-03 -6.0000e+00 1.8522e-02 9.5481e-03 -2.1054e-04 7.8948e-06 2.9633e-05 -6.0000e+00 1.2397e-03 3.9119e-02 -1.9558e-04 11 8 0 10 0 0 5.70 24.21 0.31 0.03912 0.03754 1090 112 1 5 0 49.910 33.25 19.96 24.21 19.75 3.5 888.68 -15914 -13479 -9974 -16782 -21489 -20068 -18891 -14898 -13124 -12619 -13779 -13939 -9170 -5955 -2602 -985 -667 17 557 886 667 -597 -273 -288 -116 -212 -1124 -2450 -2320 -1041 73 1239 1820 -183 -3192 -3483 -2717 -960 44 229 150 183 252 487 896 802 503 306 -72 373 1067 1211 1357 1430 1092 1085 895 375 249 85 785 1609 2250 2243 1075 120 -491 -591 319 837 690 515 324 293 -68 -603 -1333 -1918 -1520 -1281 -1263 -1350 -1902 -1914 -1226 -550 -118 303 745 728 706 212 -218 -319 -95 -226 274 624 429 -108 -640 -1075 -1155 -722 -899 -959 -863 -462 -27 479 627 667 421 218 -119 36 98 372 271 295 125 405 530 642 513 293 243 477 410 297 41 -61 -314 -154 -112 -68 101 257 113 -93 -342 -507 -693 -711 -667 -500 -855 -1032 -922 -931 -816 -801 -816 -914 -1002 -757 -532 -272 -117 -86 2 81 135 104 -94 -44 -47 -20 -39 -210 -442 -400 -182 14 277 422 -45 -772 -824 -700 -290 15 87 63 76 110 215 397 360 227 139 -33 178 518 649 741 836 636 653 555 233 151 51 479 1009 1568 1642 784 87 -341 -410 239 658 574 449 281 253 -54 -453 -964 -1360 -1161 -1038 -1129 -1306 -1929 -1965 -1287 -615 -135 342 866 817 763 219 -219 -318 -100 -250 330 792 575 -146 -834 -1308 -1338 -847 -1112 -1221 -1149 -627 -38 693 957 1031 660 333 -175 51 138 530 401 451 193 624 789 948 746 409 331 656 601 457 65 -100 -520 -260 -198 -123 187 472 210 -171 -617 -889 -1176 SS 20250403T113949.8Z 9224.485993 100 1 54.40 2 76.29 79.89 145.12 63.76 0.00 1 0.00 1 0 25 3.312e-02 6.813e-03 1.184e-03 2.540e-04 4.194157e-01 1.252783e-04 4.309917e-03 -6.000000e+00 1.838697e-02 225.22 -2.00 3.03 -2.00 317.89 0.00e+00 1.026197e-03 2.092129e-05 2.288520e-04 -6.000000e+00 7.938423e-04 275.01 -2.00 20.00 -2.00 317.31 0.00e+00 4.129 0.000 302.00 328.00 3 4.2203e-01 3.3240e-04 3.2979e-02 -6.0000e+00 4.5569e-02 -2.7350e-03 3.7579e-04 1.8305e-02 -6.0000e+00 4.9648e-02 -1.3587e-02 2.4287e-04 9.1245e-03 -6.0000e+00 2.9484e-02 3.3037e-03 1.2662e-04 2.7561e-03 -6.0000e+00 1.2613e-02 1.3265e-02 -1.7449e-04 6.7053e-06 2.6990e-05 -6.0000e+00 8.4405e-04 3.8860e-02 -1.9083e-04 11 8 0 10 0 0 11.20 24.21 0.30 0.03886 0.03755 1298 133 1 5 0 41.900 33.25 20.25 24.21 20.27 3.6 894.51 -9500 -7659 -7297 -10471 -14958 -14615 -12667 -10439 -7854 -8695 -10019 -8960 -6206 -3382 -831 -177 199 418 849 1338 1446 508 1024 1096 985 601 -413 -1469 -1638 -729 560 1705 1627 -180 -2841 -3291 -2694 -1157 -103 119 -197 -70 92 192 458 643 249 -35 -277 346 910 1186 1169 1410 1103 1082 791 453 150 195 794 1481 2108 2140 835 59 -496 -560 353 783 607 428 269 319 -33 -599 -1121 -1697 -1475 -1160 -1185 -1362 -1941 -1929 -1173 -595 -156 341 694 732 644 207 -243 -351 -166 -171 273 699 438 -130 -553 -1034 -1085 -670 -805 -896 -808 -491 -52 461 579 700 438 207 -121 70 36 357 286 324 122 346 506 635 524 327 224 493 435 293 68 -1 -342 -184 -87 -63 85 227 121 -103 -377 -496 -705 -601 -537 -532 -745 -997 -939 -864 -803 -666 -718 -845 -800 -641 -413 -119 -26 32 71 153 251 277 98 202 233 209 135 -94 -320 -369 -166 130 446 445 -53 -800 -906 -808 -380 -41 53 -91 -34 44 93 223 315 122 -17 -138 176 499 675 681 875 717 692 520 298 97 124 513 1036 1557 1657 644 45 -375 -419 272 638 525 387 243 275 -27 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