File name: Pandora283s1_LaPaz_20250405_L2Fit_fout2c4d20241004p1-8.txt File generation date: 20250624T083654.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 283 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora283_OF_v3d20231025.txt Instrument calibration file used: Pandora283s1_CF_v4d20241004.txt Level 1 file used: Pandora283s1_LaPaz_20250405_L1_smca1c4d20241004p1-8.txt Full location name: Laboratory for Atmospheric Physics, UMSA, La Paz Short location name: LaPaz Country of location: Bolivia Location latitude [deg]: -16.5389 Location longitude [deg]: -68.0661 Location altitude [m]: 3420 Local noon date: 20250405 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 203 345 Nominal wavelengths inside fitting window [nm]: 305.0638 305.2044 305.3451 305.4858 305.6264 305.7671 305.9077 306.0483 306.1889 306.3295 306.4701 306.6107 306.7513 306.8918 307.0324 307.1729 307.3134 307.4539 307.5944 307.7349 307.8754 308.0158 308.1563 308.2967 308.4371 308.5776 308.7180 308.8584 308.9988 309.1391 309.2795 309.4198 309.5602 309.7005 309.8408 309.9811 310.1214 310.2617 310.4020 310.5422 310.6825 310.8227 310.9630 311.1032 311.2434 311.3836 311.5237 311.6639 311.8041 311.9442 312.0844 312.2245 312.3646 312.5047 312.6448 312.7849 312.9249 313.0650 313.2050 313.3451 313.4851 313.6251 313.7651 313.9051 314.0451 314.1851 314.3250 314.4650 314.6049 314.7448 314.8847 315.0246 315.1645 315.3044 315.4442 315.5841 315.7239 315.8638 316.0036 316.1434 316.2832 316.4230 316.5627 316.7025 316.8423 316.9820 317.1217 317.2614 317.4011 317.5408 317.6805 317.8202 317.9598 318.0995 318.2391 318.3787 318.5184 318.6580 318.7976 318.9371 319.0767 319.2163 319.3558 319.4953 319.6348 319.7744 319.9139 320.0533 320.1928 320.3323 320.4717 320.6112 320.7506 320.8900 321.0294 321.1688 321.3082 321.4476 321.5869 321.7263 321.8656 322.0049 322.1442 322.2835 322.4228 322.5621 322.7014 322.8406 322.9799 323.1191 323.2583 323.3975 323.5367 323.6759 323.8151 323.9543 324.0934 324.2325 324.3717 324.5108 324.6499 324.7890 324.9281 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250405T132026.2Z 9226.555859 114 1 54.40 2 53.22 68.60 149.37 66.01 0.00 1 0.00 1 0 17 8.522e-03 6.788e-03 3.938e-04 2.982e-04 1.762112e-01 1.494615e-04 1.871293e-03 -6.000000e+00 4.725878e-03 225.25 -2.00 3.03 -2.00 314.40 0.00e+00 3.877857e-04 1.127549e-05 1.313500e-05 -6.000000e+00 2.037700e-04 274.98 -2.00 20.00 -2.00 313.97 0.00e+00 1.666 0.000 302.00 328.00 3 2.7993e+00 3.7963e-04 1.3494e-02 -6.0000e+00 1.1714e-02 1.7979e-02 4.2216e-04 7.6957e-03 -6.0000e+00 1.2761e-02 2.2715e-03 2.4235e-04 3.8049e-03 -6.0000e+00 7.5780e-03 -4.4045e-03 1.0663e-04 1.1017e-03 -6.0000e+00 3.2438e-03 8.8502e-03 3.2838e-04 7.9000e-06 1.3623e-05 -6.0000e+00 2.1591e-04 3.6282e-04 0.0000e+00 11 8 0 10 0 0 99.58 24.30 0.33 0.00036 0.00283 356 37 1 5 0 152.780 33.25 20.05 24.30 25.10 3.5 932.56 221 95 -35 -1836 -2678 -1913 -370 747 972 -291 -1675 -1515 -758 -261 605 382 319 505 963 1299 1100 603 1031 995 759 649 414 -149 -427 359 998 1311 1264 -371 -2576 -2811 -2072 -1336 -538 -286 -676 -658 -614 -436 -239 -205 -375 -452 -699 -203 574 735 882 963 781 790 728 510 324 206 754 1094 1569 1640 592 -275 -802 -751 106 560 520 477 447 499 257 -205 -777 -1257 -1179 -981 -1130 -1309 -1832 -1815 -995 -530 -172 288 695 647 462 129 -153 -145 65 9 349 742 577 -8 -440 -774 -983 -578 -613 -758 -808 -473 -104 446 616 691 435 229 -136 -68 -88 161 256 358 90 180 387 497 474 311 241 513 456 294 40 7 -274 -128 54 52 59 206 160 -187 -412 -513 -796 90 39 -15 -755 -1022 -681 -137 291 421 -125 -702 -666 -344 -126 311 202 172 277 541 750 619 349 598 579 465 394 259 -87 -240 202 551 769 761 -231 -1505 -1651 -1250 -898 -398 -227 -563 -550 -524 -373 -203 -173 -319 -370 -570 -163 458 625 759 836 694 712 667 465 290 183 684 1026 1534 1646 595 -261 -733 -675 96 543 537 499 469 522 260 -192 -697 -1087 -1043 -907 -1101 -1361 -1975 -1976 -1117 -621 -208 358 862 777 543 141 -159 -147 69 10 396 900 728 -10 -532 -905 -1117 -659 -724 -928 -1031 -610 -135 597 843 953 590 302 -167 -82 -105 193 321 474 120 240 512 647 601 375 288 602 551 371 52 9 -353 -170 74 74 83 299 230 -271 -579 -711 -1104 SS 20250405T132528.2Z 9226.559354 117 1 54.33 2 52.10 67.90 148.33 66.44 0.00 1 0.00 1 0 17 8.739e-03 6.910e-03 5.846e-04 4.449e-04 1.716771e-01 2.228904e-04 1.822616e-03 -6.000000e+00 4.846210e-03 225.25 -2.00 3.03 -2.00 314.37 0.00e+00 3.960919e-04 1.673267e-05 1.198149e-05 -6.000000e+00 2.089572e-04 274.98 -2.00 20.00 -2.00 313.94 0.00e+00 1.625 0.000 302.00 328.00 3 3.6208e+00 5.6579e-04 1.3154e-02 -6.0000e+00 1.2012e-02 2.0306e-02 6.2894e-04 7.5004e-03 -6.0000e+00 1.3086e-02 2.3913e-03 3.6121e-04 3.7086e-03 -6.0000e+00 7.7709e-03 -4.4465e-03 1.5877e-04 1.0787e-03 -6.0000e+00 3.3264e-03 4.0345e-03 3.0890e-04 1.1772e-05 1.3261e-05 -6.0000e+00 2.2140e-04 3.2039e-04 0.0000e+00 11 8 0 10 0 0 83.28 24.33 0.29 0.00032 0.00264 167 17 1 5 0 325.260 33.25 19.89 24.33 25.77 3.4 933.76 376 -140 109 -1925 -2591 -2069 -502 760 841 -25 -1856 -1671 -771 -184 829 504 355 663 803 1242 1233 598 987 1178 777 772 393 -140 -413 246 879 1355 1275 -283 -2559 -3053 -2085 -1347 -631 -203 -751 -719 -539 -431 -248 -298 -403 -577 -685 -222 477 714 899 1010 789 871 648 480 406 229 680 1126 1585 1689 643 -336 -757 -764 56 632 471 456 452 517 227 -207 -756 -1377 -1260 -990 -1151 -1266 -1824 -1785 -906 -476 -173 378 732 721 524 228 -85 -272 71 20 370 783 594 -23 -434 -807 -1018 -602 -586 -873 -825 -494 -103 412 586 629 433 154 -170 -65 -90 132 182 372 179 164 418 478 445 337 224 464 464 288 146 -15 -275 -35 -34 11 92 251 150 -109 -456 -540 -780 152 -61 48 -787 -985 -735 -185 312 361 -11 -814 -727 -345 -87 437 272 195 370 461 696 702 336 555 692 482 472 238 -83 -236 134 491 803 771 -177 -1501 -1812 -1263 -904 -463 -158 -615 -611 -467 -375 -213 -255 -336 -480 -548 -181 387 593 782 881 705 788 597 441 365 204 620 1056 1545 1684 641 -328 -692 -689 51 608 482 487 483 535 228 -194 -680 -1199 -1121 -913 -1149 -1299 -1933 -1965 -1025 -561 -209 469 910 867 620 251 -90 -273 74 22 421 950 748 -28 -523 -922 -1134 -691 -693 -1068 -1050 -633 -137 560 811 878 579 201 -214 -78 -107 158 227 488 237 216 550 620 562 406 269 547 560 361 187 -19 -360 -45 -46 16 131 356 217 -154 -644 -756 -1066 SS 20250405T133051.1Z 9226.563091 120 1 54.77 2 50.91 67.12 147.20 66.86 0.00 1 0.00 1 0 17 4.516e-02 4.837e-02 2.070e-03 1.476e-03 1.836716e-01 7.361764e-04 1.992913e-03 -6.000000e+00 2.504120e-02 225.25 -2.00 3.03 -2.00 314.70 0.00e+00 2.470567e-03 5.895281e-05 1.140440e-04 -6.000000e+00 1.079888e-03 274.98 -2.00 20.00 -2.00 314.25 0.00e+00 1.583 0.000 302.00 328.00 3 5.8642e+00 1.8719e-03 1.3462e-02 -6.0000e+00 6.2068e-02 1.1830e-01 2.0849e-03 8.8948e-03 -6.0000e+00 6.7621e-02 -1.9614e-02 1.1974e-03 4.0841e-03 -6.0000e+00 4.0156e-02 -1.5986e-02 5.3123e-04 2.0575e-03 -6.0000e+00 1.7186e-02 4.1473e-04 6.0103e-04 3.9357e-05 1.6866e-05 -6.0000e+00 1.1443e-03 1.5071e-03 0.0000e+00 12 9 8 11 8 0 99.73 24.38 -0.24 0.00151 0.00602 19 2 1 5 0 2882.110 33.25 19.91 24.38 26.12 3.3 935.88 1787 315 3821 -2018 -2641 -1710 -2070 -1081 -1994 -1884 -5615 -10642 -6986 -1314 2300 2127 2294 3037 3299 4176 4668 2557 2025 1571 1043 342 -1272 -1033 17 2157 2182 4066 4814 3441 -981 -576 232 1405 1069 1542 537 58 804 1806 1410 1490 2463 1273 2169 2835 3861 3262 -46452 3958 3077 2464 3130 1519 1608 1207 2421 3197 3338 3706 2457 1388 1137 1616 2277 2952 2116 2322 1426 1582 842 -127 -256 -1489 -584 305 34 401 -248 -884 97 -86 342 821 658 935 155 -154 -1002 -786 713 639 1089 1556 1206 258 22 -984 -1557 -896 -1076 -1584 -1505 -965 -671 250 350 608 305 -414 -523 -644 -32 -17 -22 98 -220 -676 -769 -338 -384 -696 -806 248 -124 384 294 -115 207 615 993 646 545 705 549 154 -442 -490 -596 630 121 1428 -733 -839 -549 -696 -368 -754 -728 -2155 -4307 -3036 -569 1086 1088 1196 1605 1790 2147 2420 1320 1050 847 588 199 -741 -560 9 1093 1153 2256 2643 1943 -570 -320 128 894 761 1178 446 47 665 1487 1160 1223 2068 1040 1691 2164 3036 2746 -53837 3390 2704 2198 2805 1370 1415 1058 2160 3036 3231 3781 2510 1299 1018 1457 2026 2803 2212 2387 1475 1664 833 -120 -229 -1255 -502 274 34 417 -260 -967 112 -102 425 1000 803 1154 178 -168 -1045 -821 724 712 1261 1880 1555 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