File name: Pandora283s1_LaPaz_20250505_L2Fit_fwvt1c2d20240531p1-8.txt File generation date: 20250506T043608.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 283 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora283_OF_v3d20231025.txt Instrument calibration file used: Pandora283s1_CF_v2d20240531.txt Level 1 file used: Pandora283s1_LaPaz_20250505_L1_smca1c2d20240531p1-8.txt Full location name: Laboratory for Atmospheric Physics, UMSA, La Paz Short location name: LaPaz Country of location: Bolivia Location latitude [deg]: -16.5389 Location longitude [deg]: -68.0661 Location altitude [m]: 3420 Local noon date: 20250505 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 1626 1775 Nominal wavelengths inside fitting window [nm]: 492.1135 492.2344 492.3554 492.4763 492.5971 492.7180 492.8389 492.9597 493.0805 493.2013 493.3221 493.4429 493.5636 493.6844 493.8051 493.9258 494.0465 494.1672 494.2878 494.4085 494.5291 494.6497 494.7703 494.8908 495.0114 495.1319 495.2524 495.3730 495.4934 495.6139 495.7344 495.8548 495.9752 496.0956 496.2160 496.3364 496.4567 496.5771 496.6974 496.8177 496.9380 497.0582 497.1785 497.2987 497.4190 497.5392 497.6593 497.7795 497.8997 498.0198 498.1399 498.2600 498.3801 498.5002 498.6202 498.7403 498.8603 498.9803 499.1003 499.2202 499.3402 499.4601 499.5800 499.6999 499.8198 499.9397 500.0595 500.1794 500.2992 500.4190 500.5388 500.6585 500.7783 500.8980 501.0177 501.1374 501.2571 501.3768 501.4964 501.6160 501.7357 501.8552 501.9748 502.0944 502.2139 502.3335 502.4530 502.5725 502.6919 502.8114 502.9309 503.0503 503.1697 503.2891 503.4085 503.5278 503.6472 503.7665 503.8858 504.0051 504.1244 504.2436 504.3629 504.4821 504.6013 504.7205 504.8397 504.9588 505.0780 505.1971 505.3162 505.4353 505.5543 505.6734 505.7924 505.9114 506.0304 506.1494 506.2684 506.3874 506.5063 506.6252 506.7441 506.8630 506.9819 507.1007 507.2195 507.3384 507.4572 507.5759 507.6947 507.8134 507.9322 508.0509 508.1696 508.2883 508.4069 508.5256 508.6442 508.7628 508.8814 509.0000 509.1185 509.2371 509.3556 509.4741 509.5926 509.7111 509.8295 509.9480 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250505T124259.6Z 9256.529856 103 1 28.55 2 64.71 62.20 164.08 92.72 0.00 1 0.00 1 0 22 3.375e-03 3.342e-03 1.309e-04 1.307e-04 2.059291e+03 7.094228e+00 1.666552e+02 -6.000000e+00 1.718030e+02 274.35 -2.00 20.00 -2.00 505.27 0.00e+00 5.672037e-04 3.444224e-06 3.158994e-05 -6.000000e+00 9.085492e-05 274.35 -2.00 20.00 -2.00 500.50 0.00e+00 9.661618e-02 2.510982e-03 1.412717e-02 -6.000000e+00 6.519743e-02 225.28 -2.00 3.03 -2.00 502.09 0.00e+00 2.328 0.000 489.00 513.00 1 3.2438e+00 1.9139e-04 2.6488e-03 -6.0000e+00 4.9707e-03 1.8220e-03 5.0368e-05 3.8224e-04 -6.0000e+00 1.3127e-03 6.0252e-02 8.7865e-04 1.0560e-05 2.5493e-05 -6.0000e+00 2.7967e-04 3.8548e-02 -1.2757e-04 10 0 0 10 0 0 99.64 24.30 0.83 0.03855 0.04464 502 51 1 4 0 56.860 33.25 19.95 24.30 20.73 3.4 894.45 -749 -334 -164 6 341 443 492 463 319 367 198 -113 -220 -328 -379 -263 59 143 31 214 178 79 327 294 336 494 459 -166 -328 -423 -599 -461 194 163 150 212 40 -136 -220 -127 -178 3 149 296 316 297 307 263 -109 -355 -607 -886 -761 -425 -221 -49 79 23 63 156 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-579 -514 SQ 20250505T124328.2Z 9256.530187 103 2 28.55 2 64.61 62.14 163.97 92.68 0.00 1 0.00 1 0 15 3.425e-03 3.388e-03 2.021e-04 2.018e-04 2.072240e+03 1.098562e+01 1.672514e+02 -6.000000e+00 1.743153e+02 274.35 -2.00 20.00 -2.00 505.27 0.00e+00 5.716182e-04 5.318097e-06 3.221669e-05 -6.000000e+00 9.218357e-05 274.35 -2.00 20.00 -2.00 500.49 0.00e+00 8.203017e-02 3.878759e-03 1.429168e-02 -6.000000e+00 6.615189e-02 225.28 -2.00 3.03 -2.00 502.08 0.00e+00 2.319 0.000 489.00 513.00 1 4.1054e+00 2.9559e-04 2.6518e-03 -6.0000e+00 5.0435e-03 4.0278e-03 7.7863e-05 3.8446e-04 -6.0000e+00 1.3319e-03 2.5501e-02 8.8645e-04 1.6302e-05 2.5455e-05 -6.0000e+00 2.8377e-04 3.8647e-02 -1.2935e-04 10 0 0 10 0 0 99.84 24.30 0.82 0.03865 0.04480 502 51 1 4 0 56.860 33.25 19.95 24.30 20.73 3.4 895.06 -727 -321 -125 -22 357 465 530 490 353 361 183 -148 -223 -347 -358 -268 72 171 48 234 186 87 289 303 358 502 465 -148 -363 -416 -598 -446 184 114 104 230 40 -148 -236 -131 -177 22 139 265 298 296 342 291 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-327 -508 -251 -95 -78 128 216 124 158 293 324 419 358 65 -309 -537 -586 -539 SQ 20250505T124732.8Z 9256.533018 106 1 28.53 2 63.75 61.63 163.03 92.31 0.00 1 0.00 1 0 15 3.363e-03 3.330e-03 1.446e-04 1.444e-04 1.998063e+03 7.833576e+00 1.616263e+02 -6.000000e+00 1.711547e+02 274.35 -2.00 20.00 -2.00 505.27 0.00e+00 6.251173e-04 3.804456e-06 3.461992e-05 -6.000000e+00 9.051194e-05 274.35 -2.00 20.00 -2.00 500.50 0.00e+00 8.414436e-02 2.773122e-03 1.394068e-02 -6.000000e+00 6.494733e-02 225.28 -2.00 3.03 -2.00 502.08 0.00e+00 2.249 0.000 489.00 513.00 1 3.4485e+00 2.1135e-04 2.5987e-03 -6.0000e+00 4.9517e-03 3.4344e-03 5.5655e-05 3.7169e-04 -6.0000e+00 1.3076e-03 4.9478e-02 7.8770e-04 1.1679e-05 2.4918e-05 -6.0000e+00 2.7860e-04 3.8214e-02 -1.2105e-04 10 0 0 10 0 0 95.11 24.31 0.83 0.03821 0.04368 569 58 1 4 0 50.120 33.25 19.91 24.31 20.85 3.4 894.91 -746 -328 -192 17 359 432 493 500 302 381 186 -134 -215 -324 -376 -277 60 146 56 223 171 106 286 297 355 497 463 -168 -325 -431 -572 -441 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