File name: Pandora283s1_LaPaz_20250521_L2Fit_fout2c4d20241004p1-8.txt File generation date: 20250624T084030.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 283 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora283_OF_v3d20231025.txt Instrument calibration file used: Pandora283s1_CF_v4d20241004.txt Level 1 file used: Pandora283s1_LaPaz_20250521_L1_smca1c4d20241004p1-8.txt Full location name: Laboratory for Atmospheric Physics, UMSA, La Paz Short location name: LaPaz Country of location: Bolivia Location latitude [deg]: -16.5389 Location longitude [deg]: -68.0661 Location altitude [m]: 3420 Local noon date: 20250521 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 203 345 Nominal wavelengths inside fitting window [nm]: 305.0638 305.2044 305.3451 305.4858 305.6264 305.7671 305.9077 306.0483 306.1889 306.3295 306.4701 306.6107 306.7513 306.8918 307.0324 307.1729 307.3134 307.4539 307.5944 307.7349 307.8754 308.0158 308.1563 308.2967 308.4371 308.5776 308.7180 308.8584 308.9988 309.1391 309.2795 309.4198 309.5602 309.7005 309.8408 309.9811 310.1214 310.2617 310.4020 310.5422 310.6825 310.8227 310.9630 311.1032 311.2434 311.3836 311.5237 311.6639 311.8041 311.9442 312.0844 312.2245 312.3646 312.5047 312.6448 312.7849 312.9249 313.0650 313.2050 313.3451 313.4851 313.6251 313.7651 313.9051 314.0451 314.1851 314.3250 314.4650 314.6049 314.7448 314.8847 315.0246 315.1645 315.3044 315.4442 315.5841 315.7239 315.8638 316.0036 316.1434 316.2832 316.4230 316.5627 316.7025 316.8423 316.9820 317.1217 317.2614 317.4011 317.5408 317.6805 317.8202 317.9598 318.0995 318.2391 318.3787 318.5184 318.6580 318.7976 318.9371 319.0767 319.2163 319.3558 319.4953 319.6348 319.7744 319.9139 320.0533 320.1928 320.3323 320.4717 320.6112 320.7506 320.8900 321.0294 321.1688 321.3082 321.4476 321.5869 321.7263 321.8656 322.0049 322.1442 322.2835 322.4228 322.5621 322.7014 322.8406 322.9799 323.1191 323.2583 323.3975 323.5367 323.6759 323.8151 323.9543 324.0934 324.2325 324.3717 324.5108 324.6499 324.7890 324.9281 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250521T120454.0Z 9272.503403 244 1 10.37 2 74.52 62.76 11.83 320.40 0.00 1 0.00 1 0 17 4.930e-02 9.455e-03 2.331e-02 4.317e-03 3.880823e-01 2.127523e-03 3.991851e-03 -6.000000e+00 2.733801e-02 225.19 -2.00 3.03 -2.00 318.04 0.00e+00 1.733966e-03 3.708844e-04 2.408208e-04 -6.000000e+00 1.174032e-03 273.99 -2.00 20.00 -2.00 317.48 0.00e+00 3.684 0.000 302.00 328.00 3 4.4321e+00 5.6599e-03 2.9804e-02 -6.0000e+00 6.7776e-02 1.6317e-02 6.3999e-03 1.7006e-02 -6.0000e+00 7.3845e-02 -2.3164e-02 4.2577e-03 8.5708e-03 -6.0000e+00 4.3829e-02 5.3333e-03 2.2449e-03 2.9347e-03 -6.0000e+00 1.8753e-02 3.2945e-04 3.5088e-04 1.1529e-04 2.7090e-05 -6.0000e+00 1.2489e-03 -1.1407e-03 0.0000e+00 12 9 9 12 33 1 96.44 24.11 0.23 -0.00114 0.00150 4 3 1 5 0 2072.510 33.25 19.72 24.11 18.18 3.4 874.78 13469 -21359 19589 -1722 -21165 -15708 -3576 -12910 -7633 -5616 -11832 -20971 -12592 -2765 5992 6344 -3764 -531 -4135 1909 10078 -4077 6888 2950 6018 -352 2617 -6180 3295 -4010 -1636 -2339 1932 568 -2247 -5347 -2345 -1585 -2243 -260 -2253 -1358 -225 3208 841 492 1409 70 2151 689 812 596 -593 975 602 324 1862 -322 1804 -101 -58 3122 1182 2853 1018 -1106 461 -732 -234 1046 138 947 189 588 473 -1227 -1174 -2902 -2101 -1615 -2454 -932 -697 -2621 -767 -247 469 631 531 1337 788 664 -560 74 -57 -166 525 238 168 -8 -556 -1608 -1787 -1432 -684 -559 -1306 -211 -494 1524 841 914 894 264 -448 149 -506 544 -305 344 268 744 124 655 -37 -526 137 648 614 123 -34 128 -359 23 621 -204 69 -295 443 31 -160 -647 -821 612 -1547 981 -101 -1337 -899 -194 -881 -556 -423 -947 -1943 -1267 -305 722 787 -553 -80 -685 311 1551 -713 1105 527 1117 -73 527 -1289 593 -784 -346 -565 501 156 -594 -1412 -655 -477 -830 -103 -1003 -633 -108 1505 405 240 678 34 1024 340 430 322 -347 599 386 200 1158 -204 1165 -66 -36 2047 876 2132 793 -824 337 -533 -172 871 121 855 171 508 403 -950 -878 -2124 -1626 -1345 -2221 -878 -707 -2689 -825 -283 537 745 628 1516 878 715 -562 72 -60 -187 628 305 223 -11 -724 -2009 -2066 -1683 -869 -717 -1764 -283 -706 2219 1274 1430 1368 399 -657 204 -692 768 -444 530 420 1135 184 976 -52 -723 185 874 862 183 -55 203 -583 39 1065 -358 123 -543 815 55 -287 -1107 -1360 SS 20250521T121412.4Z 9272.509866 247 1 54.44 2 72.55 61.79 13.38 312.75 0.00 1 0.00 1 0 17 1.611e-02 6.714e-03 6.619e-04 2.318e-04 3.457007e-01 1.143383e-04 3.575262e-03 -6.000000e+00 8.927410e-03 225.19 -2.00 3.03 -2.00 317.06 0.00e+00 7.233907e-04 1.513241e-05 1.025874e-04 -6.000000e+00 3.835599e-04 273.99 -2.00 20.00 -2.00 316.50 0.00e+00 3.291 0.000 302.00 328.00 3 9.4339e-01 2.9882e-04 2.6545e-02 -6.0000e+00 2.2132e-02 -2.3432e-02 3.3583e-04 1.5017e-02 -6.0000e+00 2.4118e-02 -9.3820e-04 2.0159e-04 7.4550e-03 -6.0000e+00 1.4315e-02 -1.7621e-03 1.0003e-04 2.2131e-03 -6.0000e+00 6.1213e-03 1.5019e-02 3.8086e-04 6.1728e-06 2.2704e-05 -6.0000e+00 4.0811e-04 2.2284e-03 0.0000e+00 11 8 0 10 0 0 51.91 24.13 0.32 0.00223 0.00509 1158 119 1 5 0 47.000 33.25 20.25 24.13 18.94 3.5 883.04 -3020 -2173 -1937 -4644 -7209 -7031 -5044 -3720 -2168 -3580 -5112 -4720 -2548 -721 818 692 540 1112 1330 1835 1267 743 1215 1219 984 720 416 -584 -960 -194 821 1382 1316 -377 -2803 -3401 -2606 -1525 -482 -55 -370 -243 -30 48 321 331 88 -161 -472 32 753 975 1038 1160 882 924 734 427 105 100 691 1272 1931 1930 819 -111 -693 -728 170 676 571 422 363 337 -59 -501 -1104 -1620 -1344 -1119 -1251 -1383 -1914 -1848 -1083 -517 -104 344 766 774 689 249 -174 -213 0 -29 321 741 509 -138 -562 -957 -1146 -675 -714 -861 -824 -445 -47 483 680 651 440 234 -183 -5 -14 288 264 273 28 247 426 573 427 319 215 482 519 358 103 -1 -294 -162 -33 2 46 253 145 -185 -460 -493 -666 -355 -282 -259 -598 -844 -789 -598 -500 -296 -523 -753 -726 -446 -136 179 170 131 282 355 508 361 210 351 352 306 235 136 -182 -282 -61 259 486 482 -146 -1036 -1228 -1020 -660 -225 -29 -202 -140 -18 29 192 200 53 -95 -279 19 457 644 701 795 630 677 530 308 77 73 513 977 1563 1633 711 -91 -548 -565 141 596 535 400 343 316 -54 -423 -879 -1291 -1089 -1001 -1188 -1372 -1987 -2008 -1210 -599 -123 408 906 909 773 272 -181 -216 0 -33 386 941 679 -184 -722 -1149 -1358 -794 -892 -1112 -1082 -595 -64 696 1024 985 666 341 -251 -7 -19 393 376 406 42 367 613 814 592 435 285 636 705 519 152 -2 -448 -257 -53 4 79 430 249 -312 -759 -793 -1064 SS 20250521T122106.3Z 9272.514656 251 1 54.41 2 71.10 61.04 14.64 308.13 0.00 1 0.00 1 0 17 1.279e-02 6.647e-03 5.100e-04 2.074e-04 3.224223e-01 1.024402e-04 3.343105e-03 -6.000000e+00 7.089706e-03 225.19 -2.00 3.03 -2.00 316.72 0.00e+00 6.770696e-04 1.238334e-05 7.120855e-05 -6.000000e+00 3.046178e-04 273.99 -2.00 20.00 -2.00 316.16 0.00e+00 3.053 0.000 302.00 328.00 3 9.0891e-01 2.6610e-04 2.4663e-02 -6.0000e+00 1.7576e-02 -2.1152e-02 2.9869e-04 1.3994e-02 -6.0000e+00 1.9154e-02 7.7962e-04 1.7665e-04 6.9431e-03 -6.0000e+00 1.1368e-02 -2.8057e-03 8.5753e-05 2.0542e-03 -6.0000e+00 4.8611e-03 1.8723e-02 3.1362e-04 5.5234e-06 2.1565e-05 -6.0000e+00 3.2413e-04 2.5774e-03 0.0000e+00 11 8 0 10 0 0 90.69 24.13 0.32 0.00258 0.00493 1284 132 1 5 0 42.370 33.00 19.93 24.13 19.95 3.5 890.96 -1803 -1445 -1131 -3755 -5580 -4950 -3527 -1852 -941 -2129 -3768 -3457 -1802 -628 537 659 595 842 1203 1634 1429 815 1345 1245 915 628 274 -466 -887 -198 831 1332 1319 -347 -2863 -3385 -2480 -1291 -495 -100 -420 -295 -231 -28 182 270 -84 -248 -537 -39 681 863 909 1037 834 867 733 424 245 126 779 1294 1851 1832 760 -128 -680 -737 105 608 581 453 329 420 7 -488 -1123 -1583 -1378 -1087 -1199 -1341 -1858 -1845 -1056 -459 -92 432 779 834 654 250 -107 -183 16 -32 339 755 534 -96 -555 -956 -1119 -670 -704 -852 -803 -478 -61 464 640 681 409 223 -178 -36 -41 228 273 285 26 181 429 561 434 283 207 495 520 335 75 -14 -294 -138 -6 28 102 231 188 -153 -442 -499 -704 -254 -224 -180 -574 -769 -649 -489 -290 -164 -395 -703 -669 -365 -149 136 187 166 246 367 518 464 263 441 410 323 232 102 -164 -293 -65 292 487 533 -140 -1163 -1339 -1062 -579 -255 -57 -253 -179 -144 -18 115 170 -53 -153 -329 -24 446 587 633 763 612 652 565 327 184 94 593 1021 1541 1593 676 -111 -565 -598 88 542 551 435 316 399 7 -416 -934 -1259 -1155 -968 -1136 -1372 -1931 -2004 -1182 -534 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