File name: Pandora283s1_LaPaz_20250710_L2Fit_fout2c4d20241004p1-8.txt File generation date: 20250711T044754.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 283 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora283_OF_v3d20231025.txt Instrument calibration file used: Pandora283s1_CF_v4d20241004.txt Level 1 file used: Pandora283s1_LaPaz_20250710_L1_smca1c4d20241004p1-8.txt Full location name: Laboratory for Atmospheric Physics, UMSA, La Paz Short location name: LaPaz Country of location: Bolivia Location latitude [deg]: -16.5389 Location longitude [deg]: -68.0661 Location altitude [m]: 3420 Local noon date: 20250710 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 203 345 Nominal wavelengths inside fitting window [nm]: 305.0638 305.2044 305.3451 305.4858 305.6264 305.7671 305.9077 306.0483 306.1889 306.3295 306.4701 306.6107 306.7513 306.8918 307.0324 307.1729 307.3134 307.4539 307.5944 307.7349 307.8754 308.0158 308.1563 308.2967 308.4371 308.5776 308.7180 308.8584 308.9988 309.1391 309.2795 309.4198 309.5602 309.7005 309.8408 309.9811 310.1214 310.2617 310.4020 310.5422 310.6825 310.8227 310.9630 311.1032 311.2434 311.3836 311.5237 311.6639 311.8041 311.9442 312.0844 312.2245 312.3646 312.5047 312.6448 312.7849 312.9249 313.0650 313.2050 313.3451 313.4851 313.6251 313.7651 313.9051 314.0451 314.1851 314.3250 314.4650 314.6049 314.7448 314.8847 315.0246 315.1645 315.3044 315.4442 315.5841 315.7239 315.8638 316.0036 316.1434 316.2832 316.4230 316.5627 316.7025 316.8423 316.9820 317.1217 317.2614 317.4011 317.5408 317.6805 317.8202 317.9598 318.0995 318.2391 318.3787 318.5184 318.6580 318.7976 318.9371 319.0767 319.2163 319.3558 319.4953 319.6348 319.7744 319.9139 320.0533 320.1928 320.3323 320.4717 320.6112 320.7506 320.8900 321.0294 321.1688 321.3082 321.4476 321.5869 321.7263 321.8656 322.0049 322.1442 322.2835 322.4228 322.5621 322.7014 322.8406 322.9799 323.1191 323.2583 323.3975 323.5367 323.6759 323.8151 323.9543 324.0934 324.2325 324.3717 324.5108 324.6499 324.7890 324.9281 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250710T121723.9Z 9322.512082 278 1 54.37 2 74.54 60.64 107.17 234.25 0.00 1 0.00 1 0 17 2.799e-02 6.912e-03 9.064e-04 2.188e-04 4.071987e-01 1.078350e-04 4.184556e-03 -6.000000e+00 1.549683e-02 224.99 -2.00 3.03 -2.00 317.66 0.00e+00 9.390849e-04 1.672050e-05 1.527902e-04 -6.000000e+00 6.645737e-04 273.28 -2.00 20.00 -2.00 317.10 0.00e+00 3.688 0.000 302.00 328.00 3 4.6407e-01 2.8431e-04 3.0259e-02 -6.0000e+00 3.8410e-02 -1.1491e-02 3.2077e-04 1.7689e-02 -6.0000e+00 4.1871e-02 -6.9321e-03 2.0305e-04 8.8446e-03 -6.0000e+00 2.4845e-02 1.2302e-03 1.0484e-04 2.6995e-03 -6.0000e+00 1.0620e-02 1.7085e-02 3.2319e-04 5.7724e-06 2.6042e-05 -6.0000e+00 7.0921e-04 4.0968e-03 0.0000e+00 11 8 0 10 0 0 16.12 24.09 0.30 0.00410 0.00653 1508 155 1 5 0 36.050 33.00 19.66 24.09 12.30 3.5 830.13 -7683 -6058 -5631 -8674 -12021 -12556 -10885 -7979 -6613 -6988 -8661 -8288 -5116 -2748 -679 196 299 747 1397 1882 1471 747 1181 1295 1019 635 195 -834 -1481 -504 692 1400 1470 -97 -2860 -3618 -2699 -1290 -364 11 -219 -162 8 257 551 652 387 105 -245 190 848 1147 1113 1317 1059 998 834 431 207 114 777 1371 2001 2031 957 43 -603 -717 100 625 666 451 313 316 -27 -557 -1149 -1682 -1398 -1141 -1269 -1432 -1973 -1964 -1185 -574 -127 344 787 830 595 178 -209 -324 -126 -102 295 667 503 -133 -600 -986 -1090 -679 -745 -909 -841 -455 -46 518 688 691 449 265 -166 -4 -11 288 236 258 34 225 510 608 469 301 265 544 527 365 95 59 -264 -153 -61 -21 80 232 157 -178 -451 -540 -701 -531 -463 -447 -669 -941 -955 -882 -659 -609 -685 -866 -881 -625 -398 -105 34 56 149 271 380 306 155 251 297 253 166 51 -210 -357 -122 185 392 462 -30 -919 -1141 -864 -455 -147 5 -109 -81 4 134 287 343 203 55 -130 103 469 695 691 830 697 678 557 287 141 77 533 974 1505 1605 782 33 -458 -541 78 538 607 415 286 287 -24 -454 -893 -1271 -1085 -984 -1166 -1425 -2059 -2080 -1288 -645 -146 405 923 966 665 189 -213 -325 -132 -116 359 857 680 -180 -782 -1197 -1300 -800 -930 -1172 -1102 -608 -64 756 1031 1070 682 389 -237 -6 -16 400 342 389 52 334 750 884 668 411 351 725 748 542 148 93 -420 -248 -103 -37 140 411 280 -310 -784 -912 -1147 SS 20250710T122734.1Z 9322.519145 281 1 54.38 2 72.42 59.55 109.06 233.13 0.00 1 0.00 1 0 17 1.762e-02 6.628e-03 5.399e-04 1.788e-04 3.634359e-01 8.809324e-05 3.749329e-03 -6.000000e+00 9.757427e-03 224.99 -2.00 3.03 -2.00 317.15 0.00e+00 7.636389e-04 1.192913e-05 1.016509e-04 -6.000000e+00 4.184410e-04 273.28 -2.00 20.00 -2.00 316.60 0.00e+00 3.269 0.000 302.00 328.00 3 3.9620e-01 2.3035e-04 2.6872e-02 -6.0000e+00 2.4184e-02 -1.1840e-02 2.5892e-04 1.5745e-02 -6.0000e+00 2.6364e-02 -2.0587e-03 1.5690e-04 7.8338e-03 -6.0000e+00 1.5644e-02 -1.1984e-03 7.8430e-05 2.3398e-03 -6.0000e+00 6.6867e-03 2.5396e-02 3.9211e-04 4.7531e-06 2.3790e-05 -6.0000e+00 4.4655e-04 4.0699e-03 0.0000e+00 11 8 0 10 0 0 10.25 24.01 0.31 0.00407 0.00702 1903 195 1 5 0 28.570 33.25 20.44 24.01 14.14 3.6 847.86 -3831 -2608 -3022 -5506 -7829 -7693 -5898 -3889 -2887 -4054 -5468 -5362 -2762 -1493 583 687 724 990 1535 1637 1398 890 1221 1129 993 809 252 -646 -1192 -165 846 1392 1563 -437 -2675 -3335 -2568 -1368 -294 48 -351 -204 37 186 415 393 113 -167 -366 43 756 976 1028 1119 963 952 683 403 116 57 621 1273 1874 1931 833 -22 -623 -636 169 654 570 376 257 308 -20 -482 -1069 -1520 -1313 -1083 -1224 -1351 -1869 -1891 -1119 -502 -160 334 758 798 626 253 -107 -223 27 -69 307 700 500 -117 -611 -922 -1099 -644 -689 -867 -775 -426 -49 495 663 674 410 229 -159 -27 -13 258 221 297 18 214 467 596 432 326 248 488 510 365 69 25 -302 -123 -22 -17 80 237 161 -177 -450 -507 -690 -414 -310 -373 -654 -845 -799 -649 -483 -400 -549 -748 -772 -454 -290 121 160 166 240 390 434 380 240 337 313 296 253 79 -193 -338 -50 260 479 560 -166 -970 -1183 -990 -583 -135 25 -190 -116 22 110 246 235 67 -99 -216 26 460 620 698 773 691 675 497 293 82 40 445 946 1475 1593 705 -18 -500 -503 138 570 528 352 248 284 -18 -412 -865 -1187 -1089 -959 -1155 -1335 -1936 -2051 -1249 -581 -189 396 894 933 698 275 -111 -225 29 -76 373 898 657 -153 -792 -1113 -1306 -760 -864 -1123 -1021 -573 -67 721 988 1033 614 330 -222 -36 -17 358 313 436 27 314 677 851 603 446 330 649 700 524 104 38 -469 -195 -36 -29 136 403 276 -302 -753 -825 -1116 SS 20250710T123429.2Z 9322.523949 285 1 54.36 2 71.00 58.78 110.33 232.34 0.00 1 0.00 1 0 17 1.417e-02 6.611e-03 4.162e-04 1.600e-04 3.394607e-01 7.901943e-05 3.523687e-03 -6.000000e+00 7.844450e-03 224.99 -2.00 3.03 -2.00 316.84 0.00e+00 6.900091e-04 9.840077e-06 7.362414e-05 -6.000000e+00 3.364124e-04 273.28 -2.00 20.00 -2.00 316.29 0.00e+00 3.038 0.000 302.00 328.00 3 3.5923e-01 2.0565e-04 2.5029e-02 -6.0000e+00 1.9443e-02 -1.0684e-02 2.3108e-04 1.4720e-02 -6.0000e+00 2.1195e-02 -4.4668e-04 1.3732e-04 7.3251e-03 -6.0000e+00 1.2577e-02 -1.9694e-03 6.7228e-05 2.1766e-03 -6.0000e+00 5.3757e-03 3.1632e-02 3.7615e-04 4.2608e-06 2.2475e-05 -6.0000e+00 3.5901e-04 4.2747e-03 0.0000e+00 11 8 0 10 0 0 5.23 23.96 0.31 0.00427 0.00710 2134 219 1 5 0 25.470 33.00 19.73 23.96 16.01 3.7 863.77 -2119 -1821 -2062 -4181 -6357 -5881 -4160 -2600 -1810 -2782 -4399 -3987 -1856 -509 656 596 734 967 1308 1618 1414 837 1315 1117 896 798 435 -501 -799 -68 854 1420 1369 -362 -2823 -3319 -2472 -1350 -472 -76 -410 -238 -163 -27 219 308 4 -204 -466 3 601 926 1009 1057 873 914 688 464 202 167 710 1239 1848 1853 772 -144 -644 -669 124 580 536 357 309 297 -14 -499 -1062 -1479 -1317 -1131 -1195 -1331 -1852 -1882 -1094 -532 -129 367 775 795 651 206 -85 -180 45 -9 365 728 510 -104 -548 -953 -1063 -647 -693 -856 -814 -458 -40 470 654 667 404 230 -151 -25 -10 262 234 226 -9 199 434 556 436 292 252 495 533 381 76 41 -268 -131 -45 -3 73 247 140 -162 -432 -513 -695 -272 -259 -303 -586 -807 -778 -534 -377 -293 -479 -763 -720 -352 -113 157 160 194 268 380 488 437 257 411 352 303 282 154 -169 -253 -21 291 505 540 -142 -1119 -1285 -980 -595 -239 -43 -244 -142 -100 -17 135 192 3 -124 -283 2 376 629 701 749 642 690 513 345 152 124 541 980 1544 1566 668 -120 -522 -531 102 526 501 349 301 277 -12 -429 -860 -1193 -1084 -995 -1158 -1351 -1969 -2034 -1219 -616 -153 447 940 931 747 222 -89 -185 48 -10 436 920 678 -138 -697 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