File name: Pandora283s1_LaPaz_20250725_L2Fit_fout2c4d20241004p1-8.txt File generation date: 20250726T045052.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 283 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora283_OF_v3d20231025.txt Instrument calibration file used: Pandora283s1_CF_v4d20241004.txt Level 1 file used: Pandora283s1_LaPaz_20250725_L1_smca1c4d20241004p1-8.txt Full location name: Laboratory for Atmospheric Physics, UMSA, La Paz Short location name: LaPaz Country of location: Bolivia Location latitude [deg]: -16.5389 Location longitude [deg]: -68.0661 Location altitude [m]: 3420 Local noon date: 20250725 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 203 345 Nominal wavelengths inside fitting window [nm]: 305.0638 305.2044 305.3451 305.4858 305.6264 305.7671 305.9077 306.0483 306.1889 306.3295 306.4701 306.6107 306.7513 306.8918 307.0324 307.1729 307.3134 307.4539 307.5944 307.7349 307.8754 308.0158 308.1563 308.2967 308.4371 308.5776 308.7180 308.8584 308.9988 309.1391 309.2795 309.4198 309.5602 309.7005 309.8408 309.9811 310.1214 310.2617 310.4020 310.5422 310.6825 310.8227 310.9630 311.1032 311.2434 311.3836 311.5237 311.6639 311.8041 311.9442 312.0844 312.2245 312.3646 312.5047 312.6448 312.7849 312.9249 313.0650 313.2050 313.3451 313.4851 313.6251 313.7651 313.9051 314.0451 314.1851 314.3250 314.4650 314.6049 314.7448 314.8847 315.0246 315.1645 315.3044 315.4442 315.5841 315.7239 315.8638 316.0036 316.1434 316.2832 316.4230 316.5627 316.7025 316.8423 316.9820 317.1217 317.2614 317.4011 317.5408 317.6805 317.8202 317.9598 318.0995 318.2391 318.3787 318.5184 318.6580 318.7976 318.9371 319.0767 319.2163 319.3558 319.4953 319.6348 319.7744 319.9139 320.0533 320.1928 320.3323 320.4717 320.6112 320.7506 320.8900 321.0294 321.1688 321.3082 321.4476 321.5869 321.7263 321.8656 322.0049 322.1442 322.2835 322.4228 322.5621 322.7014 322.8406 322.9799 323.1191 323.2583 323.3975 323.5367 323.6759 323.8151 323.9543 324.0934 324.2325 324.3717 324.5108 324.6499 324.7890 324.9281 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250725T121521.0Z 9337.510660 66 1 54.41 2 74.09 63.44 84.15 66.49 0.00 1 0.00 1 0 17 1.980e-02 6.664e-03 7.240e-04 2.208e-04 3.762731e-01 1.087608e-04 3.876659e-03 -6.000000e+00 1.096794e-02 225.07 -2.00 3.03 -2.00 317.33 0.00e+00 7.646839e-04 1.537713e-05 1.129771e-04 -6.000000e+00 4.701761e-04 273.26 -2.00 20.00 -2.00 316.77 0.00e+00 3.590 0.000 302.00 328.00 3 5.9914e-01 2.8526e-04 2.8928e-02 -6.0000e+00 2.7190e-02 -4.2968e-03 3.2102e-04 1.6337e-02 -6.0000e+00 2.9639e-02 -8.5522e-03 1.9665e-04 8.1333e-03 -6.0000e+00 1.7586e-02 1.1338e-03 9.9192e-05 2.4315e-03 -6.0000e+00 7.5151e-03 1.6600e-02 2.7068e-04 5.8576e-06 2.4358e-05 -6.0000e+00 5.0183e-04 4.3163e-03 0.0000e+00 11 8 0 10 0 0 95.56 24.01 0.31 0.00432 0.00635 1207 124 1 5 0 45.070 33.00 20.23 24.01 13.35 3.6 838.00 -4381 -3658 -3234 -6124 -8995 -9015 -6446 -4989 -4095 -4503 -6169 -5850 -3573 -1719 350 512 642 1158 1522 1698 1666 781 1255 1176 939 701 453 -845 -1341 -331 796 1510 1532 -266 -2777 -3232 -2442 -1340 -249 94 -184 -100 73 158 473 405 146 -85 -311 135 714 1055 984 1089 893 899 695 411 182 64 652 1328 1805 1883 854 -31 -633 -648 116 664 537 419 280 320 -23 -478 -1072 -1518 -1372 -1101 -1296 -1377 -1892 -1968 -1170 -554 -166 349 772 826 716 357 -69 -172 48 -80 291 656 473 -151 -627 -986 -1081 -654 -692 -827 -855 -453 -81 456 655 620 367 205 -175 -5 24 317 276 321 70 235 469 563 432 303 254 468 523 339 76 21 -269 -94 -13 19 87 233 154 -196 -467 -521 -726 -419 -388 -354 -648 -871 -842 -634 -557 -511 -596 -829 -828 -532 -302 66 108 145 275 354 412 413 193 318 321 276 202 131 -250 -377 -93 228 484 513 -94 -945 -1074 -883 -536 -114 48 -99 -54 40 89 265 229 82 -48 -174 77 416 670 641 722 617 639 487 288 130 45 468 988 1423 1557 700 -25 -494 -499 92 585 486 396 264 288 -20 -399 -848 -1161 -1118 -958 -1205 -1386 -1935 -2111 -1291 -633 -194 419 925 954 813 384 -70 -173 51 -92 353 842 623 -198 -814 -1193 -1285 -771 -867 -1070 -1127 -609 -113 668 982 937 554 299 -247 -6 32 445 395 478 105 348 687 813 610 409 342 615 730 494 116 33 -418 -148 -22 33 149 406 270 -337 -783 -867 -1173 SS 20250725T122527.0Z 9337.517674 69 1 54.39 2 71.94 62.38 82.00 65.70 0.00 1 0.00 1 0 17 1.421e-02 6.707e-03 4.524e-04 1.750e-04 3.369487e-01 8.642282e-05 3.491515e-03 -6.000000e+00 7.868072e-03 225.07 -2.00 3.03 -2.00 316.84 0.00e+00 6.928278e-04 1.075942e-05 7.937937e-05 -6.000000e+00 3.372688e-04 273.26 -2.00 20.00 -2.00 316.30 0.00e+00 3.186 0.000 302.00 328.00 3 4.4727e-01 2.2484e-04 2.5748e-02 -6.0000e+00 1.9505e-02 -2.6611e-03 2.5254e-04 1.4624e-02 -6.0000e+00 2.1262e-02 -5.4998e-03 1.5015e-04 7.2643e-03 -6.0000e+00 1.2615e-02 -7.4514e-04 7.3529e-05 2.1551e-03 -6.0000e+00 5.3914e-03 2.6474e-02 3.3917e-04 4.6555e-06 2.2314e-05 -6.0000e+00 3.5996e-04 3.7887e-03 0.0000e+00 11 8 0 10 0 0 8.90 24.07 0.30 0.00379 0.00634 1870 192 1 5 0 29.080 33.25 19.75 24.07 14.96 3.6 854.62 -2085 -1718 -2062 -4015 -6255 -5861 -4222 -2421 -1730 -2901 -4455 -3966 -1996 -482 671 664 605 868 1309 1795 1483 932 1252 1193 907 724 408 -526 -896 -149 985 1422 1389 -341 -2781 -3456 -2451 -1389 -424 -42 -364 -250 -191 -16 234 306 84 -216 -471 -14 666 999 1028 1099 863 895 710 467 203 183 713 1276 1888 1834 744 -176 -758 -700 140 683 556 462 361 372 -1 -537 -1089 -1580 -1422 -1130 -1249 -1366 -1862 -1881 -1114 -503 -116 411 786 816 660 224 -102 -205 -47 -41 372 754 542 -100 -537 -973 -1074 -677 -675 -816 -809 -441 -68 469 651 642 381 201 -172 -36 -29 270 282 330 62 237 472 568 415 277 218 467 508 330 77 -34 -332 -149 -42 33 110 258 162 -139 -451 -512 -703 -268 -244 -303 -563 -794 -776 -591 -350 -280 -499 -771 -714 -377 -106 159 176 170 239 376 536 454 283 388 396 303 253 143 -175 -300 -49 330 529 539 -140 -1085 -1318 -1012 -635 -211 -23 -212 -153 -116 -10 142 187 51 -135 -293 -9 426 664 699 792 621 661 538 353 150 133 532 987 1542 1568 651 -149 -623 -563 116 604 523 440 354 350 -1 -468 -894 -1245 -1186 -1003 -1182 -1395 -1931 -2041 -1246 -583 -138 489 957 959 740 244 -106 -213 -51 -46 445 952 720 -133 -684 -1189 -1258 -811 -836 -1046 -1056 -586 -93 673 975 965 571 289 -238 -48 -38 363 397 483 90 348 686 795 567 370 282 605 694 470 114 -51 -508 -231 -69 55 184 433 274 -234 -747 -826 -1103 SS 20250725T123224.4Z 9337.522505 73 1 54.38 2 70.46 61.62 80.52 65.13 0.00 1 0.00 1 0 25 1.183e-02 6.631e-03 3.536e-04 1.564e-04 3.141920e-01 7.721772e-05 3.266904e-03 -6.000000e+00 6.552711e-03 225.07 -2.00 3.03 -2.00 316.52 0.00e+00 6.659460e-04 8.939429e-06 5.907804e-05 -6.000000e+00 2.808775e-04 273.26 -2.00 20.00 -2.00 315.99 0.00e+00 2.960 0.000 302.00 328.00 3 4.0707e-01 2.0017e-04 2.3948e-02 -6.0000e+00 1.6244e-02 -2.4565e-03 2.2446e-04 1.3633e-02 -6.0000e+00 1.7707e-02 -3.3729e-03 1.3168e-04 6.7662e-03 -6.0000e+00 1.0506e-02 -1.7114e-03 6.3303e-05 2.0010e-03 -6.0000e+00 4.4902e-03 3.2979e-02 3.3856e-04 4.1601e-06 2.0810e-05 -6.0000e+00 2.9977e-04 3.5638e-03 0.0000e+00 11 8 0 10 0 0 12.61 24.10 0.31 0.00356 0.00611 2109 216 1 5 0 25.780 33.00 20.13 24.10 16.84 3.7 870.12 -1217 -935 -974 -3233 -4737 -4624 -2884 -1263 -675 -1988 -3567 -3173 -1763 -607 631 654 558 860 1342 1717 1407 999 1285 1047 908 698 299 -608 -978 -183 816 1326 1320 -390 -2711 -3264 -2300 -1232 -319 -20 -421 -414 -259 -153 152 201 -49 -314 -522 -143 550 879 937 1042 891 907 670 450 237 172 685 1209 1766 1731 750 -220 -770 -787 86 619 586 491 411 389 53 -440 -1079 -1567 -1390 -1109 -1182 -1368 -1849 -1847 -1088 -471 -98 410 780 791 663 232 -109 -196 9 25 375 746 534 -79 -544 -942 -1096 -677 -672 -802 -814 -445 -79 474 644 674 414 206 -177 -46 -80 246 269 306 67 204 401 549 400 302 228 483 501 337 62 0 -292 -153 -41 17 78 265 173 -142 -427 -503 -703 -200 -156 -167 -574 -754 -704 -463 -228 -126 -394 -708 -651 -381 -153 171 197 166 267 434 576 483 340 445 366 339 272 117 -225 -340 -66 299 537 557 -173 -1143 -1341 -1022 -577 -171 -12 -255 -263 -169 -101 100 132 -32 -202 -332 -92 358 619 675 763 676 705 514 345 184 132 538 985 1517 1503 664 -188 -632 -653 73 564 569 483 403 378 50 -382 -911 -1265 -1182 -1003 -1138 -1380 -1952 -1981 -1204 -542 -116 498 945 949 758 256 -114 -199 9 29 450 945 694 -102 -694 -1152 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