File name: Pandora283s1_LaPaz_20250803_L2Fit_fout2c4d20241004p1-8.txt File generation date: 20250804T045217.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 283 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora283_OF_v3d20231025.txt Instrument calibration file used: Pandora283s1_CF_v4d20241004.txt Level 1 file used: Pandora283s1_LaPaz_20250803_L1_smca1c4d20241004p1-8.txt Full location name: Laboratory for Atmospheric Physics, UMSA, La Paz Short location name: LaPaz Country of location: Bolivia Location latitude [deg]: -16.5389 Location longitude [deg]: -68.0661 Location altitude [m]: 3420 Local noon date: 20250803 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 203 345 Nominal wavelengths inside fitting window [nm]: 305.0638 305.2044 305.3451 305.4858 305.6264 305.7671 305.9077 306.0483 306.1889 306.3295 306.4701 306.6107 306.7513 306.8918 307.0324 307.1729 307.3134 307.4539 307.5944 307.7349 307.8754 308.0158 308.1563 308.2967 308.4371 308.5776 308.7180 308.8584 308.9988 309.1391 309.2795 309.4198 309.5602 309.7005 309.8408 309.9811 310.1214 310.2617 310.4020 310.5422 310.6825 310.8227 310.9630 311.1032 311.2434 311.3836 311.5237 311.6639 311.8041 311.9442 312.0844 312.2245 312.3646 312.5047 312.6448 312.7849 312.9249 313.0650 313.2050 313.3451 313.4851 313.6251 313.7651 313.9051 314.0451 314.1851 314.3250 314.4650 314.6049 314.7448 314.8847 315.0246 315.1645 315.3044 315.4442 315.5841 315.7239 315.8638 316.0036 316.1434 316.2832 316.4230 316.5627 316.7025 316.8423 316.9820 317.1217 317.2614 317.4011 317.5408 317.6805 317.8202 317.9598 318.0995 318.2391 318.3787 318.5184 318.6580 318.7976 318.9371 319.0767 319.2163 319.3558 319.4953 319.6348 319.7744 319.9139 320.0533 320.1928 320.3323 320.4717 320.6112 320.7506 320.8900 321.0294 321.1688 321.3082 321.4476 321.5869 321.7263 321.8656 322.0049 322.1442 322.2835 322.4228 322.5621 322.7014 322.8406 322.9799 323.1191 323.2583 323.3975 323.5367 323.6759 323.8151 323.9543 324.0934 324.2325 324.3717 324.5108 324.6499 324.7890 324.9281 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250803T115221.8Z 9346.494697 101 1 6.57 2 78.17 67.66 138.38 176.59 0.00 1 0.00 1 0 17 1.008e-01 9.558e-03 3.408e-02 3.114e-03 5.120978e-01 1.536616e-03 5.185808e-03 -6.000000e+00 5.582093e-02 225.17 -2.00 3.03 -2.00 318.88 0.00e+00 1.584130e-03 3.456536e-04 6.679856e-04 -6.000000e+00 2.392598e-03 273.28 -2.00 20.00 -2.00 318.35 0.00e+00 4.740 0.000 302.00 328.00 3 2.7014e+00 4.1852e-03 3.8671e-02 -6.0000e+00 1.3841e-01 1.0860e-02 4.8079e-03 2.2390e-02 -6.0000e+00 1.5087e-01 -3.5347e-02 3.6791e-03 1.1495e-02 -6.0000e+00 8.9513e-02 1.4236e-02 1.9849e-03 3.8041e-03 -6.0000e+00 3.8240e-02 8.1275e-04 3.0180e-04 8.0847e-05 3.6925e-05 -6.0000e+00 2.5537e-03 5.3172e-03 0.0000e+00 12 9 9 12 1 1 -0.94 23.92 0.22 0.00532 0.00759 11 10 1 5 0 547.030 33.00 19.90 23.92 14.23 3.5 843.41 -14025 -51248 5176 -52183 -44483 -42833 -20756 -19430 -38541 6452 -26674 -25419 -6893 -10359 -8221 1892 1433 -3743 -2113 -5906 840 -7904 -7060 -1259 450 -5537 -962 -3028 -2192 -2033 -4686 296 -522 3056 -5991 -7251 -4408 160 -102 -84 -1004 926 -668 1182 116 3297 876 -316 -165 1092 1874 168 2154 2000 2728 881 1698 181 10 -1184 1545 2363 2878 3635 1814 686 -244 -1050 325 679 622 785 516 1319 440 -827 -1590 -3387 -2798 -1696 -1528 -1624 -1705 -2124 -1366 -371 274 586 1447 893 -175 -743 -625 -1548 -418 -350 600 636 632 569 -658 -1157 -1878 -986 -793 -972 -898 -176 171 818 982 1332 966 271 -403 -445 -270 17 98 -92 252 580 954 595 217 138 172 411 -48 448 392 -383 -775 -361 -156 11 -21 851 656 -175 -563 -551 -701 -302 -1836 112 -1901 -1351 -1249 -529 -566 -1545 176 -1037 -1073 -297 -579 -552 134 112 -334 -199 -553 83 -768 -707 -130 50 -683 -114 -351 -243 -235 -643 45 -92 549 -1110 -1331 -866 36 -26 -26 -317 305 -234 414 41 1158 318 -118 -63 430 746 75 1030 963 1369 467 919 99 5 -626 819 1363 1743 2429 1205 439 -160 -698 221 502 506 631 412 1046 323 -582 -1099 -2351 -1990 -1323 -1306 -1493 -1622 -2135 -1388 -399 296 650 1589 993 -183 -754 -623 -1488 -438 -382 709 817 848 763 -865 -1429 -2236 -1182 -989 -1234 -1194 -236 237 1202 1519 2147 1543 415 -597 -648 -391 25 153 -145 399 886 1448 876 318 193 239 579 -73 701 642 -640 -1346 -636 -285 21 -39 1634 1266 -330 -1036 -986 -1251 SS 20250803T115723.3Z 9346.498186 104 1 54.42 2 77.06 67.20 138.29 174.97 0.00 1 0.00 1 0 17 5.996e-02 7.162e-03 2.241e-03 3.187e-04 4.785056e-01 1.571456e-04 4.866766e-03 -6.000000e+00 3.321199e-02 225.17 -2.00 3.03 -2.00 318.40 0.00e+00 1.293932e-03 3.032172e-05 3.153880e-04 -6.000000e+00 1.423621e-03 273.28 -2.00 20.00 -2.00 317.85 0.00e+00 4.359 0.000 302.00 328.00 3 6.8368e-01 4.2124e-04 3.5727e-02 -6.0000e+00 8.2350e-02 2.2005e-03 4.7866e-04 2.0840e-02 -6.0000e+00 8.9769e-02 -2.1826e-02 3.3430e-04 1.0508e-02 -6.0000e+00 5.3259e-02 6.8111e-03 1.7860e-04 3.3368e-03 -6.0000e+00 2.2750e-02 8.1188e-03 2.1444e-04 8.3001e-06 3.1519e-05 -6.0000e+00 1.5196e-03 5.9319e-03 0.0000e+00 11 8 0 10 0 0 96.92 23.92 0.30 0.00593 0.00754 990 102 1 5 0 54.960 33.00 20.43 23.92 14.55 3.5 846.69 -21044 -16101 -13872 -19470 -24939 -27351 -23847 -19810 -14913 -14729 -16906 -15745 -11087 -6851 -2908 -2018 -927 -520 265 406 721 -977 -235 -127 -242 -1059 -1289 -2616 -3041 -2256 -119 1110 1319 -117 -3167 -3437 -2740 -870 -105 218 60 313 302 554 1031 1059 845 350 68 661 1231 1329 1413 1575 1279 1088 1058 371 266 89 815 1549 2156 2379 1253 196 -482 -605 230 751 653 481 346 302 -40 -617 -1344 -1883 -1595 -1311 -1265 -1461 -1904 -1999 -1176 -544 -142 323 804 852 711 315 -160 -317 -150 -207 211 592 473 -144 -681 -1044 -1199 -815 -854 -987 -883 -404 -43 530 673 665 475 264 -145 -11 44 337 255 303 110 328 576 637 484 254 214 480 466 339 63 8 -316 -133 -83 -43 91 246 161 -170 -470 -473 -624 -827 -686 -608 -857 -1042 -1140 -1046 -966 -786 -827 -985 -988 -807 -592 -267 -213 -105 -64 34 55 100 -137 -34 -20 -41 -176 -216 -462 -518 -395 -21 228 307 -29 -764 -813 -654 -244 -33 77 23 130 123 228 425 443 356 149 30 298 603 677 779 878 750 627 627 220 162 53 500 979 1442 1672 920 137 -340 -428 168 603 553 408 292 253 -32 -468 -987 -1363 -1194 -1092 -1114 -1394 -1903 -2023 -1261 -598 -159 370 915 968 751 319 -158 -312 -155 -236 253 751 632 -193 -882 -1299 -1422 -981 -1047 -1283 -1162 -542 -60 784 1024 1053 742 403 -212 -16 62 482 379 462 169 503 874 931 697 362 290 657 684 524 103 14 -526 -227 -148 -79 169 455 299 -315 -847 -826 -1081 SS 20250803T120304.8Z 9346.502139 107 1 54.38 2 75.81 66.67 138.14 173.14 0.00 1 0.00 1 0 17 3.943e-02 6.930e-03 1.877e-03 3.604e-04 4.411781e-01 1.776296e-04 4.502979e-03 -6.000000e+00 2.183865e-02 225.17 -2.00 3.03 -2.00 318.02 0.00e+00 1.098775e-03 3.042043e-05 2.035847e-04 -6.000000e+00 9.360568e-04 273.28 -2.00 20.00 -2.00 317.46 0.00e+00 3.997 0.000 302.00 328.00 3 1.2125e+00 4.7249e-04 3.2802e-02 -6.0000e+00 5.4150e-02 2.1225e-03 5.3402e-04 1.9176e-02 -6.0000e+00 5.9026e-02 -1.5311e-02 3.5248e-04 9.6048e-03 -6.0000e+00 3.5020e-02 3.8080e-03 1.8555e-04 2.9852e-03 -6.0000e+00 1.4960e-02 6.3054e-03 3.0860e-04 9.4883e-06 2.9171e-05 -6.0000e+00 9.9909e-04 5.4022e-03 0.0000e+00 11 8 0 10 0 0 87.48 23.92 0.29 0.00540 0.00772 621 64 1 5 0 87.560 33.00 20.34 23.92 15.12 3.5 853.32 -12114 -9399 -8082 -12611 -17961 -17423 -15780 -12242 -10003 -9995 -11789 -10487 -6786 -4270 -1616 -620 -326 615 684 1402 1960 46 1040 443 799 402 43 -1491 -1716 -1036 832 1406 1766 -72 -2719 -3740 -2826 -1377 -347 113 -310 -89 143 361 794 633 598 137 -66 347 1032 1252 1284 1488 1254 978 916 384 182 176 805 1459 2085 2214 968 156 -450 -654 70 691 572 405 349 324 -100 -557 -1144 -1730 -1510 -1158 -1281 -1377 -2025 -2016 -1283 -639 -123 309 717 789 655 399 -93 -112 -58 -159 280 631 461 -108 -685 -1030 -1073 -702 -756 -906 -879 -450 -27 458 611 652 406 228 -143 33 24 366 251 290 132 293 516 554 440 311 244 523 497 376 47 -1 -279 -90 -31 -35 67 228 131 -199 -470 -510 -642 -663 -566 -503 -776 -1044 -978 -947 -819 -741 -787 -954 -903 -614 -462 -205 -89 -51 93 110 235 334 8 183 85 166 88 9 -317 -349 -214 191 339 480 -21 -759 -1030 -787 -451 -129 47 -134 -41 68 173 380 307 290 67 -33 177 536 678 749 881 777 628 604 253 117 111 521 975 1476 1645 748 114 -328 -476 52 572 500 357 305 281 -83 -435 -857 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