File name: Pandora63s1_LaPorteTX_20211020_L2Fit_fout2c2d20210924p1-8.txt File generation date: 20250514T160940.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 63 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora63_OF_v2d20210219.txt Instrument calibration file used: Pandora63s1_CF_v2d20210924.txt Level 1 file used: Pandora63s1_LaPorteTX_20211020_L1_smca1c2d20210924p1-8.txt Full location name: University Of Houston Trailer Short location name: LaPorteTX Country of location: United States Location latitude [deg]: 29.6721 Location longitude [deg]: -95.0647 Location altitude [m]: 22 Local noon date: 20211020 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 141 283 Nominal wavelengths inside fitting window [nm]: 305.0348 305.1762 305.3175 305.4588 305.6002 305.7415 305.8828 306.0240 306.1653 306.3066 306.4478 306.5891 306.7303 306.8715 307.0127 307.1539 307.2951 307.4362 307.5774 307.7185 307.8597 308.0008 308.1419 308.2830 308.4241 308.5652 308.7063 308.8473 308.9884 309.1294 309.2704 309.4114 309.5524 309.6934 309.8344 309.9753 310.1163 310.2572 310.3982 310.5391 310.6800 310.8209 310.9618 311.1027 311.2435 311.3844 311.5252 311.6661 311.8069 311.9477 312.0885 312.2293 312.3700 312.5108 312.6515 312.7923 312.9330 313.0737 313.2144 313.3551 313.4958 313.6365 313.7771 313.9178 314.0584 314.1991 314.3397 314.4803 314.6209 314.7615 314.9020 315.0426 315.1831 315.3237 315.4642 315.6047 315.7452 315.8857 316.0262 316.1667 316.3071 316.4476 316.5880 316.7284 316.8688 317.0092 317.1496 317.2900 317.4304 317.5707 317.7111 317.8514 317.9917 318.1321 318.2724 318.4126 318.5529 318.6932 318.8334 318.9737 319.1139 319.2541 319.3944 319.5346 319.6747 319.8149 319.9551 320.0952 320.2354 320.3755 320.5156 320.6557 320.7958 320.9359 321.0760 321.2161 321.3561 321.4962 321.6362 321.7762 321.9162 322.0562 322.1962 322.3362 322.4761 322.6161 322.7560 322.8959 323.0359 323.1758 323.3157 323.4555 323.5954 323.7353 323.8751 324.0150 324.1548 324.2946 324.4344 324.5742 324.7140 324.8538 324.9935 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211020T132310.8Z 7963.557764 254 1 49.15 2 78.75 109.15 103.49 286.30 0.00 1 0.00 1 0 25 2.607e-01 1.662e-02 6.387e-02 3.104e-03 4.842049e-01 1.578316e-03 6.494525e-03 -6.000000e+00 1.462939e-01 226.66 -2.00 3.24 -2.00 321.12 0.00e+00 2.264493e-03 7.521886e-04 7.928303e-03 -6.000000e+00 6.788010e-03 290.90 -2.00 20.00 -2.00 320.39 0.00e+00 4.947 0.001 302.00 328.00 3 1.5162e+00 5.5077e-03 6.8182e-02 -6.0000e+00 3.6149e-01 -1.8706e-02 7.2002e-03 6.0461e-02 -6.0000e+00 3.9337e-01 -1.0839e-01 6.1216e-03 2.0021e-02 -6.0000e+00 2.3574e-01 4.4188e-02 2.9579e-03 4.2325e-03 -6.0000e+00 1.0019e-01 5.6715e-04 5.4945e-04 9.0083e-05 9.8167e-05 -6.0000e+00 6.8821e-03 3.0224e-03 -2.7663e-05 12 8 8 10 0 0 98.35 18.16 0.07 0.00302 0.00715 107 24 1 5 0 459.290 21.79 15.00 18.16 29.02 7.6 948.06 -75860 -92240 -64673 -98630 -44557 -118721 -65978 -97148 -89017 -67165 -73247 -61904 -67829 -33672 -38410 -15209 -35699 107 -23478 411 -1741 -15340 -1007 -14546 -6759 -7615 280 -26093 -12271 -18539 -9401 -3691 -5088 -1538 -9615 -7617 -8044 8097 -980 10925 7051 6015 4020 15453 8749 8378 7216 2249 2087 1342 5681 7306 5630 6509 5216 4560 2309 1897 939 3789 3259 5346 5917 7292 1663 2608 -411 -104 371 2655 1788 2201 2263 -151 -1431 -4032 -4981 -6777 -4438 -3974 -2547 -1790 -1867 -1279 -257 1062 1278 2711 1750 1640 188 -2097 -3812 -3525 -2371 -1852 486 670 181 -1298 -1577 -3781 -2762 -1232 -962 -687 304 733 1830 2888 2720 2132 1051 -601 -2165 -2470 -1413 -771 810 1013 1870 1944 2040 163 54 -1784 -2517 -1553 -989 -1156 -714 -965 -1176 -253 342 886 1586 1685 958 151 -274 -1302 -1160 -1060 -1761 -994 -1919 -539 -2464 -999 -2126 -2031 -1314 -1569 -1283 -1657 -784 -1063 -388 -1235 3 -833 12 -54 -544 -32 -566 -264 -316 11 -1264 -504 -838 -439 -191 -303 -93 -605 -461 -534 550 -83 974 730 674 479 1681 1031 1008 887 295 280 191 845 1185 1011 1241 1058 969 515 423 207 806 726 1287 1594 2131 528 784 -122 -31 124 997 742 947 962 -62 -591 -1537 -1778 -2476 -1765 -1847 -1349 -1057 -1194 -862 -171 751 956 2052 1424 1284 139 -1467 -2575 -2448 -1818 -1620 475 735 214 -1528 -1715 -3790 -2614 -1205 -1021 -770 356 908 2451 4233 4316 3263 1702 -933 -3193 -3526 -2041 -1174 1303 1697 3097 3115 3166 249 79 -2557 -3531 -2289 -1629 -2112 -1387 -1952 -2492 -528 760 2045 3721 4015 2287 351 -648 -2955 -2631 SS 20211020T132917.2Z 7963.562005 257 1 49.25 2 77.50 110.00 104.71 287.14 0.00 1 0.00 1 0 33 1.964e-01 1.531e-02 5.384e-02 2.753e-03 4.470107e-01 1.404217e-03 5.917607e-03 -6.000000e+00 1.102118e-01 226.66 -2.00 3.24 -2.00 320.89 0.00e+00 3.240605e-03 6.162096e-04 6.331776e-03 -6.000000e+00 5.113122e-03 290.90 -2.00 20.00 -2.00 320.12 0.00e+00 4.489 0.001 302.00 328.00 3 1.7962e+00 4.7107e-03 5.8392e-02 -6.0000e+00 2.7233e-01 -4.4721e-02 6.0277e-03 4.6995e-02 -6.0000e+00 2.9634e-01 -4.2087e-02 5.0600e-03 1.6957e-02 -6.0000e+00 1.7759e-01 1.4051e-02 2.4916e-03 3.1605e-03 -6.0000e+00 7.5483e-02 6.7824e-04 3.3836e-04 8.1714e-05 7.7789e-05 -6.0000e+00 5.1839e-03 2.4922e-03 -1.7268e-05 12 8 8 10 0 0 95.97 18.17 0.07 0.00249 0.00503 114 25 1 5 0 431.950 21.88 14.97 18.17 29.28 7.6 949.60 -64050 -63642 -30943 -85305 -55466 -87760 -73913 -69313 -31525 -68345 -34241 -47695 -41673 -32864 -22913 -16965 -15406 -14704 -13249 -4944 4397 -1041 4364 -9714 -314 -14558 -2821 -12399 -4598 -11585 -7186 -6914 -2452 -4182 -8048 -3359 -4948 482 3301 7128 2772 5139 5304 4730 2445 7742 3691 2759 964 2163 4997 1429 5125 3059 5012 3620 2452 -54 608 858 2044 4798 5084 6747 2746 525 -1775 -1981 1579 1939 1666 2068 662 -606 -1486 -3621 -5238 -6738 -4202 -3535 -1589 -1343 -1942 -2014 -482 1250 944 2409 1380 1538 -53 -1038 -3509 -3020 -2209 -1147 92 870 421 -1101 -1521 -3037 -2426 -1176 -628 -613 375 665 1744 2572 2577 2261 1009 -676 -2046 -2030 -1448 -704 562 785 1601 1844 1885 156 126 -1909 -2444 -1788 -1354 -1067 -918 -1240 -1032 -417 443 579 1365 1652 961 310 -244 -1252 -1183 -985 -1134 -423 -1794 -866 -1799 -1389 -1421 -500 -1529 -610 -1048 -1027 -846 -651 -528 -520 -533 -507 -184 153 -38 156 -428 -14 -765 -133 -621 -208 -578 -386 -432 -166 -302 -582 -227 -370 41 307 752 341 660 711 654 351 1073 537 410 148 343 839 275 1031 671 1128 858 602 -14 149 208 512 1287 1526 2182 947 191 -627 -709 605 851 804 1034 332 -294 -670 -1499 -2034 -2650 -1782 -1740 -884 -835 -1310 -1440 -364 996 799 2066 1189 1271 -42 -754 -2465 -2159 -1737 -1019 92 968 502 -1313 -1679 -3074 -2329 -1170 -675 -698 445 834 2354 3786 4082 3678 1618 -1035 -2961 -2827 -2045 -1047 886 1293 2616 2917 2887 235 182 -2689 -3348 -2567 -2161 -1873 -1712 -2401 -2077 -886 1000 1363 3264 4007 2340 733 -550 -2718 -2565 SS 20211020T133446.9Z 7963.565820 260 1 48.91 2 76.38 110.78 105.80 287.90 0.00 1 0.00 1 0 25 1.488e-01 1.514e-02 3.785e-02 2.150e-03 4.208244e-01 1.080358e-03 5.402939e-03 -6.000000e+00 8.348128e-02 226.66 -2.00 3.24 -2.00 320.62 0.00e+00 1.898136e-03 4.345956e-04 5.194255e-03 -6.000000e+00 3.872902e-03 290.90 -2.00 20.00 -2.00 319.82 0.00e+00 4.145 0.001 302.00 328.00 3 1.7361e+00 3.4848e-03 5.2330e-02 -6.0000e+00 2.0628e-01 -5.6470e-02 4.3814e-03 4.0165e-02 -6.0000e+00 2.2446e-01 -1.8314e-02 3.5987e-03 1.4324e-02 -6.0000e+00 1.3452e-01 3.6112e-03 1.8011e-03 3.1322e-03 -6.0000e+00 5.7176e-02 1.0268e-03 4.8603e-04 6.3488e-05 5.7675e-05 -6.0000e+00 3.9265e-03 2.4322e-03 -1.4223e-05 12 8 8 10 0 0 99.04 18.17 0.07 0.00243 0.00608 145 32 1 5 0 337.260 21.88 15.01 18.17 29.44 7.5 949.97 -33296 -57807 -26306 -54526 -40619 -76252 -17969 -53517 -54776 -31990 -57305 -20656 -35018 -17197 -24232 55 -4649 1698 382 -1347 861 -11027 -1489 -13117 3424 -9336 3428 -12573 -6944 -7909 -4466 856 -3452 -911 -12198 54 -9720 235 460 4871 2660 4920 2743 5272 3360 1766 4126 64 1598 -242 3791 1661 2938 2888 2986 3012 258 395 -395 1232 1404 4346 3819 5052 2050 475 -773 -1715 601 1325 1605 849 1572 -569 -658 -4088 -4702 -5622 -4774 -2747 -2653 -1950 -2775 -967 -522 1159 1509 2133 2006 1430 641 -1456 -2501 -2972 -1863 -1751 371 927 519 -1178 -1490 -2591 -2378 -723 -892 -658 140 923 1498 2796 2734 2020 1180 -475 -1837 -2208 -1261 -859 962 843 1331 1637 1659 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