File name: Pandora63s1_LaPorteTX_20211126_L2Fit_fout2c2d20210924p1-8.txt File generation date: 20250514T162511.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 63 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora63_OF_v2d20210219.txt Instrument calibration file used: Pandora63s1_CF_v2d20210924.txt Level 1 file used: Pandora63s1_LaPorteTX_20211126_L1_smca1c2d20210924p1-8.txt Full location name: University Of Houston Trailer Short location name: LaPorteTX Country of location: United States Location latitude [deg]: 29.6721 Location longitude [deg]: -95.0647 Location altitude [m]: 22 Local noon date: 20211126 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 141 283 Nominal wavelengths inside fitting window [nm]: 305.0348 305.1762 305.3175 305.4588 305.6002 305.7415 305.8828 306.0240 306.1653 306.3066 306.4478 306.5891 306.7303 306.8715 307.0127 307.1539 307.2951 307.4362 307.5774 307.7185 307.8597 308.0008 308.1419 308.2830 308.4241 308.5652 308.7063 308.8473 308.9884 309.1294 309.2704 309.4114 309.5524 309.6934 309.8344 309.9753 310.1163 310.2572 310.3982 310.5391 310.6800 310.8209 310.9618 311.1027 311.2435 311.3844 311.5252 311.6661 311.8069 311.9477 312.0885 312.2293 312.3700 312.5108 312.6515 312.7923 312.9330 313.0737 313.2144 313.3551 313.4958 313.6365 313.7771 313.9178 314.0584 314.1991 314.3397 314.4803 314.6209 314.7615 314.9020 315.0426 315.1831 315.3237 315.4642 315.6047 315.7452 315.8857 316.0262 316.1667 316.3071 316.4476 316.5880 316.7284 316.8688 317.0092 317.1496 317.2900 317.4304 317.5707 317.7111 317.8514 317.9917 318.1321 318.2724 318.4126 318.5529 318.6932 318.8334 318.9737 319.1139 319.2541 319.3944 319.5346 319.6747 319.8149 319.9551 320.0952 320.2354 320.3755 320.5156 320.6557 320.7958 320.9359 321.0760 321.2161 321.3561 321.4962 321.6362 321.7762 321.9162 322.0562 322.1962 322.3362 322.4761 322.6161 322.7560 322.8959 323.0359 323.1758 323.3157 323.4555 323.5954 323.7353 323.8751 324.0150 324.1548 324.2946 324.4344 324.5742 324.7140 324.8538 324.9935 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211126T133736.1Z 8000.567779 257 1 48.48 2 82.40 119.54 27.74 252.54 0.00 1 0.00 1 0 25 3.176e-01 2.622e-02 2.412e-01 1.340e-02 6.179537e-01 6.996307e-03 9.295495e-03 -6.000000e+00 1.770014e-01 224.77 -2.00 3.24 -2.00 321.96 0.00e+00 1.483007e-02 3.895428e-03 1.366433e-02 -6.000000e+00 8.159913e-03 287.77 -2.00 20.00 -2.00 321.37 0.00e+00 7.014 0.004 302.00 328.00 3 1.5259e+00 2.7577e-02 9.9563e-02 -6.0000e+00 4.3596e-01 5.3402e-01 3.4807e-02 8.1726e-02 -6.0000e+00 4.7528e-01 -9.1855e-01 2.5763e-02 3.2772e-02 -6.0000e+00 2.8470e-01 3.8903e-01 1.2380e-02 6.3865e-03 -6.0000e+00 1.2111e-01 6.4906e-05 1.4179e-04 3.8710e-04 2.8798e-04 -6.0000e+00 8.3799e-03 1.8838e-03 -1.5666e-05 12 9 8 11 8 0 82.52 17.47 0.13 0.00188 0.00295 30 7 1 5 0 1615.660 21.38 14.98 17.47 14.16 7.8 878.59 -81815 18329 2295 -19495 -150817 -54735 -17814 -70531 -38233 -88262 -70211 -79748 -82532 24609 493 5570 -22367 54617 -7210 45004 -24283 159233 -32813 31114 -23420 121 -44897 -9544 10968 2349 -10165 -36906 75034 5964 28216 10334 26514 10528 6375 33997 13071 47195 32484 25386 11041 73056 28784 52151 26381 17135 26124 29038 35452 15062 48316 20408 24777 11986 17112 6277 3956 17691 12233 32155 20898 10842 2777 16719 3642 11371 6074 7491 7892 -2556 -461 -7274 4075 -11918 1151 -6908 2277 -5218 1407 -1908 -1190 1058 2087 1553 1641 3850 -5328 1491 -8866 -8897 -8061 -3276 -3462 -154 -1203 -2350 -3549 -5176 -2244 -1735 -1620 -3732 -720 1402 1871 2390 3100 702 -498 -461 -4325 -3512 -1107 394 1047 2905 2997 2150 4179 723 2662 -1410 -2352 -464 2 -787 166 -1011 -623 -511 -83 1066 1574 1573 814 282 -1009 -1188 -2701 -3208 340 50 -490 -10284 -1467 -327 -2051 -855 -2999 -1977 -2580 -3315 500 15 185 -1027 1370 -323 1304 -1239 2081 -1632 890 -1064 4 -2406 -364 349 87 -477 -2577 2270 334 1213 501 1171 593 427 2005 1004 2784 2250 1933 961 3871 2238 3462 2215 1657 2510 2979 3672 1969 4768 2628 3049 1635 2144 868 586 2549 2075 5115 3792 2105 564 3097 834 2757 1688 2112 2161 -727 -119 -1806 870 -3005 292 -2221 782 -2189 600 -890 -588 546 1127 867 910 2060 -2921 712 -4531 -4793 -4929 -2244 -2772 -134 -1143 -2243 -3241 -4288 -1694 -1354 -1374 -3441 -685 1409 2090 3004 4273 1037 -739 -655 -6051 -4869 -1543 578 1635 4618 4701 3272 6047 1056 3692 -1955 -3313 -676 3 -1496 339 -2201 -1427 -1252 -210 2804 4206 4264 2207 754 -2556 -2840 -6528 SS 20211126T135618.3Z 8000.580767 262 1 49.12 2 78.91 122.20 31.61 256.56 0.00 1 0.00 1 0 33 2.959e-01 1.728e-02 4.610e-02 2.093e-03 5.009124e-01 1.062165e-03 7.014365e-03 -6.000000e+00 1.648702e-01 224.77 -2.00 3.24 -2.00 321.19 0.00e+00 4.929304e-03 5.151281e-04 8.519463e-03 -6.000000e+00 7.601855e-03 287.76 -2.00 20.00 -2.00 320.52 0.00e+00 5.014 0.001 302.00 328.00 3 6.4036e-01 3.7107e-03 6.9077e-02 -6.0000e+00 4.0608e-01 -1.2127e-03 4.8506e-03 5.9539e-02 -6.0000e+00 4.4273e-01 -1.2325e-01 4.2610e-03 2.3313e-02 -6.0000e+00 2.6520e-01 5.0642e-02 2.0558e-03 3.5749e-03 -6.0000e+00 1.1281e-01 1.2332e-03 5.1814e-04 6.0689e-05 1.3215e-04 -6.0000e+00 7.8069e-03 1.6510e-03 -5.5622e-05 12 8 8 10 0 0 74.33 17.45 0.07 0.00165 0.00554 261 58 1 5 0 188.180 21.38 15.00 17.45 14.32 7.8 879.56 -139700 -46551 -123642 -40458 -121872 -83207 -104039 -90025 -60553 -101577 -53134 -103109 -23039 -67676 -4163 -38826 6697 -19905 -13701 4568 -15194 -465 -16931 13857 -21389 14902 -25595 9987 -26444 -5762 -10627 -4182 4233 -11085 3275 -18044 2383 -3293 10022 1003 11692 6072 6781 10326 5759 9786 4212 9584 1771 8207 3888 10015 6437 7217 5969 4443 4564 207 2915 -296 6052 4095 8555 5828 5623 1172 -122 -954 538 3196 410 3065 -314 1769 -3031 -3389 -6136 -5681 -3924 -3634 -907 -2123 -1677 -2309 656 -5 1890 1720 2594 1018 -574 -1502 -4217 -3359 -3204 -1401 -665 1335 -134 -875 -2191 -3476 -2428 -1413 -517 -1301 860 483 2413 2307 3184 1718 1141 -735 -2345 -2285 -1762 -320 334 1441 1497 2493 1967 662 -78 -1911 -2315 -1562 -957 -1047 -556 -1619 -629 -437 637 507 1479 1764 942 309 -474 -1227 -1477 -3122 -552 -2890 -469 -2578 -1235 -1918 -1631 -946 -2358 -853 -2683 -364 -1906 -82 -1172 153 -612 -425 126 -509 -14 -586 395 -872 464 -1142 325 -1142 -219 -478 -205 218 -678 172 -1133 135 -228 743 93 1100 638 741 1119 666 1110 513 1145 231 1075 573 1541 1118 1331 1168 915 960 45 607 -63 1291 972 2194 1696 1692 353 -36 -291 181 1184 171 1293 -135 718 -1185 -1215 -2103 -1958 -1487 -1618 -455 -1195 -1016 -1493 441 -3 1425 1334 1982 771 -412 -1022 -2802 -2288 -2441 -1188 -641 1401 -153 -990 -2350 -3450 -2267 -1368 -538 -1448 988 583 3137 3328 4858 2738 1789 -1125 -3418 -3264 -2561 -478 533 2368 2445 3959 3043 1005 -116 -2780 -3288 -2342 -1582 -1893 -1069 -3275 -1297 -959 1456 1211 3582 4328 2318 736 -1093 -2746 -3314 SS 20211126T140223.0Z 8000.584988 265 1 49.13 2 77.80 123.10 32.88 257.72 0.00 1 0.00 1 0 25 2.255e-01 1.566e-02 3.521e-02 1.764e-03 4.686572e-01 8.912042e-04 6.504887e-03 -6.000000e+00 1.256431e-01 224.77 -2.00 3.24 -2.00 320.89 0.00e+00 3.887663e-03 3.981717e-04 7.000222e-03 -6.000000e+00 5.792296e-03 287.76 -2.00 20.00 -2.00 320.18 0.00e+00 4.592 0.001 302.00 328.00 3 8.8333e-01 2.9617e-03 6.0610e-02 -6.0000e+00 3.0946e-01 -2.7987e-02 3.8243e-03 4.9489e-02 -6.0000e+00 3.3737e-01 -5.8300e-02 3.3426e-03 1.9443e-02 -6.0000e+00 2.0209e-01 1.9707e-02 1.6348e-03 3.1958e-03 -6.0000e+00 8.5973e-02 1.4816e-03 4.0038e-04 5.1395e-05 1.0709e-04 -6.0000e+00 5.9485e-03 1.2740e-03 -3.7134e-05 12 8 8 10 0 0 97.72 17.45 0.05 0.00127 0.00428 245 55 1 5 0 200.490 21.38 14.98 17.45 14.57 7.7 880.81 -75873 -69169 -79992 -61286 -97144 -70023 -92855 -61969 -81872 -57095 -63669 -41154 -47721 -31524 -19356 -16778 -1778 -7112 851 -9032 -2331 -6806 750 -7519 -176 -1329 -15673 -10272 -14238 -9389 -9643 5212 -3773 3889 -14514 -4470 -4809 -2272 2093 4249 3349 3386 6138 3292 7981 4539 5237 2285 2856 2116 3088 5237 4192 5305 2352 4619 1195 1271 108 743 2873 3790 5605 5027 3460 649 513 -2625 1492 1449 1811 1478 948 275 -1677 -2929 -5634 -5693 -4720 -2122 -2276 -1311 -2572 -1568 18 381 1817 1709 2280 1378 338 -1960 -3266 -3285 -2606 -1279 -11 1069 234 -813 -1858 -2883 -2652 -915 -1253 -676 269 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