File name: Pandora63s1_LaPorteTX_20211226_L2Fit_fout2c2d20210924p1-8.txt File generation date: 20250514T163451.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 63 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora63_OF_v2d20210219.txt Instrument calibration file used: Pandora63s1_CF_v2d20210924.txt Level 1 file used: Pandora63s1_LaPorteTX_20211226_L1_smca1c2d20210924p1-8.txt Full location name: University Of Houston Trailer Short location name: LaPorteTX Country of location: United States Location latitude [deg]: 29.6721 Location longitude [deg]: -95.0647 Location altitude [m]: 22 Local noon date: 20211226 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 141 283 Nominal wavelengths inside fitting window [nm]: 305.0348 305.1762 305.3175 305.4588 305.6002 305.7415 305.8828 306.0240 306.1653 306.3066 306.4478 306.5891 306.7303 306.8715 307.0127 307.1539 307.2951 307.4362 307.5774 307.7185 307.8597 308.0008 308.1419 308.2830 308.4241 308.5652 308.7063 308.8473 308.9884 309.1294 309.2704 309.4114 309.5524 309.6934 309.8344 309.9753 310.1163 310.2572 310.3982 310.5391 310.6800 310.8209 310.9618 311.1027 311.2435 311.3844 311.5252 311.6661 311.8069 311.9477 312.0885 312.2293 312.3700 312.5108 312.6515 312.7923 312.9330 313.0737 313.2144 313.3551 313.4958 313.6365 313.7771 313.9178 314.0584 314.1991 314.3397 314.4803 314.6209 314.7615 314.9020 315.0426 315.1831 315.3237 315.4642 315.6047 315.7452 315.8857 316.0262 316.1667 316.3071 316.4476 316.5880 316.7284 316.8688 317.0092 317.1496 317.2900 317.4304 317.5707 317.7111 317.8514 317.9917 318.1321 318.2724 318.4126 318.5529 318.6932 318.8334 318.9737 319.1139 319.2541 319.3944 319.5346 319.6747 319.8149 319.9551 320.0952 320.2354 320.3755 320.5156 320.6557 320.7958 320.9359 321.0760 321.2161 321.3561 321.4962 321.6362 321.7762 321.9162 322.0562 322.1962 322.3362 322.4761 322.6161 322.7560 322.8959 323.0359 323.1758 323.3157 323.4555 323.5954 323.7353 323.8751 324.0150 324.1548 324.2946 324.4344 324.5742 324.7140 324.8538 324.9935 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20211226T142731.0Z 8030.602442 287 1 36.82 2 77.16 126.69 43.06 240.98 0.00 1 0.00 1 0 33 4.453e-01 2.395e-02 2.527e-01 1.236e-02 4.116410e-01 6.292887e-03 4.860587e-03 -6.000000e+00 2.511817e-01 224.29 -2.00 3.24 -2.00 320.69 0.00e+00 9.339927e-04 2.556063e-03 3.960179e-03 -6.000000e+00 1.204033e-02 285.84 -2.00 20.00 -2.00 319.98 0.00e+00 4.380 0.001 302.00 328.00 3 4.0269e+00 2.0100e-02 5.1031e-02 -6.0000e+00 6.1822e-01 -4.5972e-02 2.5386e-02 3.2027e-02 -6.0000e+00 6.7573e-01 7.9786e-03 2.1795e-02 1.3601e-02 -6.0000e+00 4.0105e-01 -3.7679e-03 1.0848e-02 2.8282e-03 -6.0000e+00 1.7296e-01 8.2762e-05 1.2558e-03 3.7413e-04 5.7894e-05 -6.0000e+00 1.2182e-02 1.2702e-03 1.3315e-04 12 9 9 12 1 1 100.00 18.29 0.28 0.00127 0.01071 20 6 1 5 0 1744.860 21.98 14.98 18.29 28.91 8.6 971.63 900000 900000 -72911 900000 -69147 900000 -132850 900000 -74690 -23899 -94585 56903 138799 12639 208457 60446 244325 -17662 221076 -23596 32988 -1754 66972 72501 -34562 107960 -21757 40023 -42799 44229 -20558 32380 -17631 36192 -1505 -16387 10014 -16921 26447 -15271 24796 -4593 22163 -6093 9417 2543 11116 8795 -4396 -3923 -4996 17961 1606 10616 -3197 18843 -2235 9422 4868 -1256 10465 702 15481 1265 7714 -1459 4150 -6869 1639 -3376 -1224 1188 -1539 3770 -7422 692 -10094 -3002 -3974 -3470 -4126 -1693 -2313 577 216 170 5256 -2392 4408 -488 4244 -3418 -1971 -5288 -3625 -1239 -1773 2989 -563 1313 -3552 -1925 -2523 -344 -342 245 2293 853 2168 1063 3759 654 2037 -1042 -1646 -2892 -1348 -1389 -95 1762 -414 2897 278 2145 -1443 -1102 -3882 -500 -1399 439 -805 -1486 -313 -1641 1163 -61 2369 1794 1434 399 -53 -1923 -1756 900000 900000 -1865 900000 -1566 900000 -5239 900000 -2301 -511 -3764 685 1672 295 2511 1251 2943 -812 2663 -1267 1136 -82 1794 1981 -2532 2485 -1514 1603 -3366 1686 -1488 1685 -1567 2114 -118 -1442 759 -1906 2445 -2379 2984 -766 3025 -1100 1495 435 1774 1442 -824 -760 -1057 3372 380 2454 -880 4395 -652 2475 1311 -357 2780 223 4752 483 2831 -555 1425 -2646 644 -1591 -618 610 -808 1805 -3678 288 -4305 -1194 -1745 -1749 -2395 -1071 -1580 406 164 138 4309 -2166 3733 -419 3259 -2611 -1403 -3959 -2933 -1111 -1797 3231 -669 1512 -3974 -1937 -2455 -344 -372 280 2703 1074 2915 1570 5786 1058 3173 -1572 -2338 -4010 -1881 -2047 -148 2834 -683 4516 431 3173 -2132 -1549 -5440 -712 -2216 746 -1461 -2801 -605 -3388 2495 -138 5349 4142 3311 903 -115 -4079 -3733 SS 20211226T144707.5Z 8030.616059 293 1 48.27 2 73.82 129.80 46.83 245.17 0.00 1 0.00 1 0 33 8.369e-02 1.421e-02 4.597e-02 3.372e-03 3.473450e-01 1.666695e-03 4.309074e-03 -6.000000e+00 4.655692e-02 224.29 -2.00 3.24 -2.00 320.19 0.00e+00 2.530863e-03 5.661162e-04 3.254613e-03 -6.000000e+00 2.132567e-03 285.84 -2.00 20.00 -2.00 319.43 0.00e+00 3.528 0.000 302.00 328.00 3 2.5632e+00 5.0198e-03 4.0906e-02 -6.0000e+00 1.1462e-01 -8.6159e-02 6.0834e-03 2.4554e-02 -6.0000e+00 1.2504e-01 7.1471e-02 4.8147e-03 1.1355e-02 -6.0000e+00 7.4841e-02 -3.6969e-02 2.4689e-03 2.6672e-03 -6.0000e+00 3.1814e-02 8.6774e-04 7.0324e-04 1.0118e-04 4.9301e-05 -6.0000e+00 2.2074e-03 1.3459e-03 1.9285e-05 12 8 8 10 0 0 99.99 18.30 0.07 0.00135 0.00663 317 71 1 5 0 152.230 21.98 15.01 18.30 29.47 8.6 975.11 -52987 18761 -28392 5783 -20287 16912 12481 -10909 -5040 -30409 1970 -19619 22622 -26947 18785 -5966 19717 -2653 16474 8430 4365 7464 16 10021 -2940 7577 -2318 -3372 -5162 3442 -1040 3964 2005 -8270 3420 -9654 -600 -5585 2966 -427 3288 -2183 1992 814 -207 3091 -1342 2245 -4169 1512 -1461 3363 79 1827 115 1372 590 -1633 -177 -2107 2186 2091 4852 2862 2507 -1587 -1376 -2119 120 1559 -287 1257 15 967 -1621 -1281 -4031 -3688 -3365 -2500 -1485 -2230 -1403 -1800 442 117 2120 1267 2145 996 277 -614 -2498 -1746 -2387 -160 -520 1881 507 -106 -1658 -2214 -1953 -745 -451 -1031 577 249 1907 1993 2589 1805 1271 -647 -1539 -1845 -1639 -705 303 1248 992 1969 1028 200 -648 -2021 -2344 -1959 -1039 -1504 -753 -1607 -926 -591 592 538 1324 1727 1072 480 -227 -804 -1073 -1615 365 -836 128 -515 309 247 -288 -141 -1097 56 -691 646 -1342 746 -325 933 -159 893 510 283 473 1 672 -234 580 -193 -277 -419 263 -89 365 206 -968 350 -1091 -68 -771 453 -78 637 -474 434 183 -48 702 -318 514 -1020 362 -384 922 24 578 38 468 208 -588 -62 -756 783 821 2043 1329 1180 -734 -599 -927 56 823 -169 757 9 562 -899 -643 -1911 -1716 -1695 -1432 -955 -1596 -1067 -1448 373 107 2002 1240 2081 945 246 -509 -1971 -1376 -2067 -152 -557 2180 631 -130 -1927 -2362 -2009 -797 -524 -1272 736 334 2691 3048 4159 2973 2027 -989 -2206 -2554 -2303 -1039 477 2035 1642 3149 1616 307 -967 -2920 -3266 -2833 -1628 -2579 -1342 -2962 -1751 -1171 1239 1171 2929 3874 2418 1060 -486 -1665 -2226 SS 20211226T163527.8Z 8030.691294 361 1 48.87 2 58.77 151.49 69.16 262.10 0.00 1 0.00 1 0 17 3.021e-02 1.490e-02 2.568e-02 7.116e-03 2.033032e-01 3.448823e-03 2.305070e-03 -6.000000e+00 1.681771e-02 224.29 -2.00 3.24 -2.00 318.11 0.00e+00 1.223994e-03 6.139627e-04 7.887393e-04 -6.000000e+00 7.700286e-04 285.84 -2.00 20.00 -2.00 317.26 0.00e+00 1.921 0.000 302.00 328.00 3 5.2842e+00 9.2486e-03 2.1287e-02 -6.0000e+00 4.1407e-02 5.9792e-03 1.0565e-02 9.6952e-03 -6.0000e+00 4.5157e-02 4.4518e-02 6.4460e-03 4.7085e-03 -6.0000e+00 2.7030e-02 -3.1506e-02 3.2314e-03 1.3335e-03 -6.0000e+00 1.1498e-02 3.1941e-04 8.2710e-04 2.0730e-04 1.2613e-05 -6.0000e+00 7.9666e-04 -4.5093e-04 1.3926e-04 12 8 8 10 0 0 99.96 18.36 0.17 -0.00045 0.00576 144 32 1 5 0 339.240 21.98 15.01 18.36 31.19 8.7 984.98 3210 -5707 3676 3115 960 -14860 4086 -1189 1878 4011 -15505 6309 -2014 9288 -6341 3124 -5050 1569 2936 994 1938 -1340 6102 -80 997 -499 4151 -5304 570 -3810 5059 -1436 299 -2528 -5479 -1362 -5635 495 -3446 600 -1758 984 -522 -684 1207 -394 684 -1300 545 -731 1528 -1270 3434 1373 2523 723 -295 -75 -147 2082 567 2395 2149 2741 -692 -656 -885 -2012 -406 1710 1952 429 1668 873 -182 -3012 -2598 -2004 -2250 -2581 -3628 -981 -3523 -822 428 788 670 2163 1648 637 936 -673 -2152 -2554 -1180 -2137 851 656 1018 -428 194 -3024 -2438 -1612 -1224 -718 -359 405 1182 1904 2081 2576 1391 -673 -1728 -2132 -1103 -1445 1118 559 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