File name: Pandora63s1_LaPorteTX_20220129_L2Fit_fout2c2d20210924p1-8.txt File generation date: 20250514T165300.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 63 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora63_OF_v2d20210219.txt Instrument calibration file used: Pandora63s1_CF_v2d20210924.txt Level 1 file used: Pandora63s1_LaPorteTX_20220129_L1_smca1c2d20210924p1-8.txt Full location name: University Of Houston Trailer Short location name: LaPorteTX Country of location: United States Location latitude [deg]: 29.6721 Location longitude [deg]: -95.0647 Location altitude [m]: 22 Local noon date: 20220129 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 141 283 Nominal wavelengths inside fitting window [nm]: 305.0348 305.1762 305.3175 305.4588 305.6002 305.7415 305.8828 306.0240 306.1653 306.3066 306.4478 306.5891 306.7303 306.8715 307.0127 307.1539 307.2951 307.4362 307.5774 307.7185 307.8597 308.0008 308.1419 308.2830 308.4241 308.5652 308.7063 308.8473 308.9884 309.1294 309.2704 309.4114 309.5524 309.6934 309.8344 309.9753 310.1163 310.2572 310.3982 310.5391 310.6800 310.8209 310.9618 311.1027 311.2435 311.3844 311.5252 311.6661 311.8069 311.9477 312.0885 312.2293 312.3700 312.5108 312.6515 312.7923 312.9330 313.0737 313.2144 313.3551 313.4958 313.6365 313.7771 313.9178 314.0584 314.1991 314.3397 314.4803 314.6209 314.7615 314.9020 315.0426 315.1831 315.3237 315.4642 315.6047 315.7452 315.8857 316.0262 316.1667 316.3071 316.4476 316.5880 316.7284 316.8688 317.0092 317.1496 317.2900 317.4304 317.5707 317.7111 317.8514 317.9917 318.1321 318.2724 318.4126 318.5529 318.6932 318.8334 318.9737 319.1139 319.2541 319.3944 319.5346 319.6747 319.8149 319.9551 320.0952 320.2354 320.3755 320.5156 320.6557 320.7958 320.9359 321.0760 321.2161 321.3561 321.4962 321.6362 321.7762 321.9162 322.0562 322.1962 322.3362 322.4761 322.6161 322.7560 322.8959 323.0359 323.1758 323.3157 323.4555 323.5954 323.7353 323.8751 324.0150 324.1548 324.2946 324.4344 324.5742 324.7140 324.8538 324.9935 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220129T134207.5Z 8064.570921 105 1 49.08 2 84.68 114.02 65.58 146.37 0.00 1 0.00 1 0 33 3.124e-01 5.532e-02 2.805e-01 4.846e-02 7.189397e-01 2.478604e-02 6.840282e-03 -6.000000e+00 1.741329e-01 224.72 -2.00 3.24 -2.00 321.39 0.00e+00 -9.208877e-03 7.034276e-03 5.390049e-03 -6.000000e+00 7.929609e-03 284.90 -2.00 20.00 -2.00 320.53 0.00e+00 9.376 0.010 302.00 328.00 3 4.1974e-01 7.6527e-02 1.0531e-01 -6.0000e+00 4.2928e-01 1.5985e+00 9.0248e-02 6.2083e-02 -6.0000e+00 4.6811e-01 -1.7901e+00 5.0680e-02 1.7249e-02 -6.0000e+00 2.7994e-01 6.1773e-01 2.7175e-02 1.0679e-02 -6.0000e+00 1.1889e-01 1.6194e-05 3.8810e-03 1.3068e-03 9.6256e-05 -6.0000e+00 8.2397e-03 -7.1422e-03 -1.3658e-04 12 8 8 10 0 0 0.76 16.83 0.55 -0.00714 0.02202 20 4 1 5 0 2453.670 20.87 15.00 16.83 10.55 8.4 872.67 114124 75878 59446 120767 -33727 -15849 -1022 55066 -38641 91604 -2958 8775 -17007 20287 5795 62746 5594 64801 16980 31408 30184 -53527 17904 11607 115710 -30270 31512 17123 1105 -2160 13400 -2966 349 6796 -56130 79568 -2119 23324 7231 72670 5438 8335 -15875 37623 -13421 -33391 -33934 -13657 17994 -11252 -1466 40644 12557 26686 6219 54202 42662 46501 -27882 23233 -32019 12702 -9677 6997 23400 -16474 -1677 4320 100710 65 34391 28554 19154 -4597 -6810 902 -12452 -30571 -29095 -8661 -8224 12997 -1053 3454 19562 25039 7028 14979 8812 -2015 -5815 -3596 10557 -9707 -13991 7092 -1027 5702 2523 253 -2263 -17018 -12186 6513 -5266 5970 2101 7703 5649 11912 5088 -760 2218 -5996 -913 -6110 -3649 -4598 -2086 2737 8698 3798 3625 5885 -4209 -1079 -11301 -244 723 -2418 -946 -628 -1728 622 -472 477 2600 2070 2201 -548 -243 -1179 -1673 8298 8000 6699 6659 -6034 -2247 -126 4554 -7867 5412 -398 1053 -2844 2581 927 6425 935 6380 2407 3958 3566 -12454 2186 1600 6463 -6052 3351 1821 122 -238 1372 -397 48 857 -11937 4444 -282 2806 1111 7181 1028 1543 -3626 5173 -2643 -7627 -7484 -2640 2551 -2224 -283 5588 2428 4701 1389 7685 6782 6793 -7906 3693 -8804 2401 -2536 1683 4826 -4813 -411 1039 11423 21 8275 7361 5185 -1442 -1931 209 -3103 -9457 -10125 -2902 -3180 4579 -461 1529 7816 10005 3503 6951 4240 -1022 -2848 -1622 4490 -4963 -8596 4113 -746 4385 2135 214 -1789 -13892 -9005 4198 -4140 4437 1724 6487 5486 12385 6274 -1042 2945 -8321 -1149 -7954 -4798 -6499 -3065 3916 11435 5026 5156 8010 -6166 -1474 -17090 -366 1253 -4914 -1878 -1320 -3928 1494 -1234 1286 7004 5675 6532 -1584 -654 -3021 -4363 SS 20220129T135531.3Z 8064.580223 108 1 49.13 2 82.04 115.82 64.08 149.12 0.00 1 0.00 1 0 25 3.857e-01 2.351e-02 1.320e-01 6.846e-03 6.449613e-01 3.582075e-03 8.936617e-03 -6.000000e+00 2.150381e-01 224.72 -2.00 3.24 -2.00 322.01 0.00e+00 1.189785e-02 2.084644e-03 1.227532e-02 -6.000000e+00 9.790721e-03 284.90 -2.00 20.00 -2.00 321.45 0.00e+00 6.748 0.004 302.00 328.00 3 5.7606e-01 1.4203e-02 9.3757e-02 -6.0000e+00 5.3013e-01 4.0799e-01 1.8590e-02 7.7032e-02 -6.0000e+00 5.7802e-01 -7.6109e-01 1.5217e-02 3.5480e-02 -6.0000e+00 3.4567e-01 3.2422e-01 7.0774e-03 8.5886e-03 -6.0000e+00 1.4685e-01 2.1423e-04 -1.4805e-04 1.9462e-04 2.7932e-04 -6.0000e+00 1.0171e-02 -8.9270e-03 -1.2147e-04 12 8 8 10 0 0 1.20 16.82 0.12 -0.00893 -0.01004 104 23 1 5 0 472.290 20.87 15.00 16.82 12.39 8.4 884.79 -111726 -68460 -81229 -91017 -114377 -128103 -127862 -117734 -123905 -23428 -128935 -113570 -113593 -69323 -61892 -12034 -5500 -21094 23911 11869 73814 -20719 -33422 -14081 -2369 -22336 -29258 -13246 -40642 -21552 -28733 -8287 2962 98915 -4848 81 -23130 -10652 28700 28953 26211 29510 36687 18699 51931 21028 43527 17502 27650 23958 19586 32979 20832 29173 18252 30625 15219 29590 3259 17777 13084 16465 22214 19103 16737 10432 13862 1885 18007 6069 11261 6144 5620 2268 -2417 -4165 -9037 -4468 -3646 1164 -1215 1295 -2454 -2263 -787 -2088 2736 2130 2091 -621 54 -3395 -6576 -7225 -5474 -3642 -2013 -466 -1705 -1886 -3597 -3893 -5583 -1527 -2210 -980 -755 931 1211 2074 2999 1612 1513 -1846 -2546 -3821 -2044 -1230 355 1483 2948 3636 3343 1683 -5 -148 -2645 378 -916 -464 92 -718 -833 -267 603 277 1664 1468 1104 25 -561 -1624 -2174 -3046 -1409 -1989 -2329 -3245 -3706 -3557 -3079 -3585 -297 -3874 -3159 -3918 -2006 -2101 -321 -154 -681 566 324 1183 -680 -1209 -462 -70 -813 -1119 -418 -1677 -785 -1215 -346 127 2047 -224 4 -1274 -599 1411 1498 1531 1773 2143 1342 2963 1533 2591 1392 2061 1959 1831 2991 2318 3181 2128 3493 1884 3375 432 2176 1747 2363 3183 3179 3009 1950 2428 382 3450 1505 2903 1726 1556 609 -618 -971 -2075 -1007 -931 340 -428 507 -1089 -1064 -389 -1116 1476 1190 1164 -343 28 -1684 -3249 -3774 -3211 -2467 -1567 -410 -1658 -1837 -3302 -3193 -4333 -1174 -1857 -866 -707 924 1336 2574 4092 2349 2203 -2672 -3516 -5190 -2797 -1774 540 2316 4479 5708 5101 2546 -8 -212 -3798 567 -1602 -918 182 -1513 -1855 -634 1521 733 4441 3982 2988 64 -1380 -4109 -5482 SS 20220129T141013.1Z 8064.590429 113 1 48.99 2 79.19 117.88 62.58 152.25 0.00 1 0.00 1 0 25 3.269e-01 1.602e-02 5.404e-02 2.361e-03 5.301489e-01 1.218595e-03 7.243761e-03 -6.000000e+00 1.823426e-01 224.72 -2.00 3.24 -2.00 321.33 0.00e+00 6.502880e-03 6.002792e-04 8.320118e-03 -6.000000e+00 8.299566e-03 284.90 -2.00 20.00 -2.00 320.71 0.00e+00 5.135 0.002 302.00 328.00 3 6.9000e-01 4.2728e-03 6.8717e-02 -6.0000e+00 4.4953e-01 1.7782e-02 5.6550e-03 5.6043e-02 -6.0000e+00 4.9008e-01 -1.5436e-01 5.1828e-03 2.6078e-02 -6.0000e+00 2.9308e-01 6.5488e-02 2.4791e-03 5.8265e-03 -6.0000e+00 1.2455e-01 1.0047e-03 7.6508e-05 6.8870e-05 1.5638e-04 -6.0000e+00 8.6199e-03 -9.6995e-03 -4.9624e-05 12 8 8 10 0 0 70.33 16.81 0.08 -0.00970 -0.00912 225 50 1 5 0 217.710 20.87 15.00 16.81 14.19 8.3 893.24 -109973 -101215 -78217 -94826 -111515 -118087 -138574 -86036 -123849 -77240 -114513 -63030 -83030 -30442 -31897 -23184 -17672 -28630 -1033 -17767 -5217 -26779 -6158 -20325 -13557 -14669 -13288 -27751 -28731 -5250 -16507 11866 1250 -1328 -16404 -5473 -3598 -1143 5495 2863 7718 3539 9100 6502 12674 4269 9008 7826 7615 4554 5162 10430 6959 10156 5316 6593 2955 4847 1276 1396 4212 5316 7889 7240 6404 599 1217 -704 1833 1283 3002 1529 618 239 -2271 -2564 -6111 -6000 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