File name: Pandora63s1_LaPorteTX_20220306_L2Fit_fout2c2d20210924p1-8.txt File generation date: 20250514T170051.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 63 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora63_OF_v2d20210219.txt Instrument calibration file used: Pandora63s1_CF_v2d20210924.txt Level 1 file used: Pandora63s1_LaPorteTX_20220306_L1_smca1c2d20210924p1-8.txt Full location name: University Of Houston Trailer Short location name: LaPorteTX Country of location: United States Location latitude [deg]: 29.6721 Location longitude [deg]: -95.0647 Location altitude [m]: 22 Local noon date: 20220306 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 141 283 Nominal wavelengths inside fitting window [nm]: 305.0348 305.1762 305.3175 305.4588 305.6002 305.7415 305.8828 306.0240 306.1653 306.3066 306.4478 306.5891 306.7303 306.8715 307.0127 307.1539 307.2951 307.4362 307.5774 307.7185 307.8597 308.0008 308.1419 308.2830 308.4241 308.5652 308.7063 308.8473 308.9884 309.1294 309.2704 309.4114 309.5524 309.6934 309.8344 309.9753 310.1163 310.2572 310.3982 310.5391 310.6800 310.8209 310.9618 311.1027 311.2435 311.3844 311.5252 311.6661 311.8069 311.9477 312.0885 312.2293 312.3700 312.5108 312.6515 312.7923 312.9330 313.0737 313.2144 313.3551 313.4958 313.6365 313.7771 313.9178 314.0584 314.1991 314.3397 314.4803 314.6209 314.7615 314.9020 315.0426 315.1831 315.3237 315.4642 315.6047 315.7452 315.8857 316.0262 316.1667 316.3071 316.4476 316.5880 316.7284 316.8688 317.0092 317.1496 317.2900 317.4304 317.5707 317.7111 317.8514 317.9917 318.1321 318.2724 318.4126 318.5529 318.6932 318.8334 318.9737 319.1139 319.2541 319.3944 319.5346 319.6747 319.8149 319.9551 320.0952 320.2354 320.3755 320.5156 320.6557 320.7958 320.9359 321.0760 321.2161 321.3561 321.4962 321.6362 321.7762 321.9162 322.0562 322.1962 322.3362 322.4761 322.6161 322.7560 322.8959 323.0359 323.1758 323.3157 323.4555 323.5954 323.7353 323.8751 324.0150 324.1548 324.2946 324.4344 324.5742 324.7140 324.8538 324.9935 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220306T153525.2Z 8100.649597 127 1 5.20 2 54.94 122.32 84.75 80.65 0.00 1 0.00 1 0 25 1.785e-02 1.456e-02 8.272e-03 4.124e-03 1.904871e-01 2.039369e-03 2.070264e-03 -6.000000e+00 1.003107e-02 226.49 -2.00 3.24 -2.00 316.26 0.00e+00 1.169502e-03 2.342635e-04 3.108992e-04 -6.000000e+00 4.548185e-04 285.61 -2.00 20.00 -2.00 315.50 0.00e+00 1.736 0.000 302.00 328.00 3 4.1122e+00 5.2914e-03 1.9273e-02 -6.0000e+00 2.4824e-02 1.9702e-02 5.9450e-03 8.6332e-03 -6.0000e+00 2.7020e-02 -2.7768e-03 3.4270e-03 4.1846e-03 -6.0000e+00 1.6144e-02 -9.6944e-03 1.5884e-03 1.2280e-03 -6.0000e+00 6.8424e-03 1.2744e-03 6.3674e-04 1.1459e-04 1.1971e-05 -6.0000e+00 4.7098e-04 -7.9087e-03 1.6925e-04 12 9 9 12 1 1 99.33 18.36 0.11 -0.00791 -0.00312 3 9 1 5 0 1255.010 21.98 14.98 18.36 27.33 9.1 979.82 -2473 988 -357 -2276 -3645 -1902 -3312 -2476 -3450 -2773 -2952 -4368 -2066 511 1302 2397 524 3249 1698 2877 1889 2097 1257 1077 995 1012 -861 -519 -978 -771 -1277 -410 -493 -2383 -3773 -4401 -4283 -3038 -1368 -664 521 1280 753 1036 806 876 -392 1290 -664 -315 -770 90 707 1836 884 1137 994 -702 391 213 1921 2191 2991 3223 1583 -1195 -1053 -1978 -685 1161 392 1501 794 714 -275 -2395 -3100 -4105 -3518 -2719 -2120 -1561 -2454 -1172 72 581 1214 1486 1763 1088 874 -1196 -1993 -2040 -1715 -629 -2 1127 358 20 -269 -1888 -1959 -1384 -700 -868 -195 487 744 1777 2173 1785 1760 -38 -933 -1514 -1532 -1028 685 1568 1602 1710 2168 145 86 -1456 -1653 -1320 -1545 -1163 -239 -1277 -1109 -395 238 1317 1331 1633 1224 207 -7 -1418 -1827 -491 209 -78 -487 -718 -343 -615 -506 -788 -655 -693 -1039 -515 140 394 773 178 1106 602 1034 702 775 468 416 402 421 -362 -209 -376 -286 -485 -165 -210 -1053 -1623 -1841 -1874 -1484 -761 -409 340 861 519 718 559 608 -271 863 -440 -208 -525 64 520 1383 682 891 788 -564 307 168 1531 1823 2624 2926 1450 -1056 -872 -1610 -576 1050 379 1479 788 695 -258 -2132 -2584 -3314 -2905 -2413 -2028 -1574 -2588 -1265 81 679 1464 1825 2163 1317 1010 -1318 -2074 -2084 -1811 -704 -2 1404 465 26 -332 -2230 -2274 -1651 -879 -1126 -260 662 1037 2550 3202 2637 2531 -53 -1232 -1939 -1973 -1364 942 2230 2316 2454 3051 202 117 -1927 -2123 -1711 -2085 -1629 -341 -1848 -1622 -591 367 2082 2135 2643 1997 335 -11 -2227 -2870 SS 20220306T155202.9Z 8100.661145 137 1 1.02 2 51.94 125.88 81.25 82.52 0.00 1 0.00 1 0 17 1.787e-02 1.460e-02 4.411e-03 2.636e-03 1.818690e-01 1.311239e-03 1.990826e-03 -6.000000e+00 1.002755e-02 226.49 -2.00 3.24 -2.00 315.63 0.00e+00 1.093717e-03 1.314289e-04 1.978662e-04 -6.000000e+00 4.549227e-04 285.61 -2.00 20.00 -2.00 314.92 0.00e+00 1.618 0.000 302.00 328.00 3 1.8035e+00 3.3741e-03 1.8092e-02 -6.0000e+00 2.4815e-02 1.8304e-02 3.7779e-03 8.3295e-03 -6.0000e+00 2.7019e-02 -9.1014e-03 2.1643e-03 4.0225e-03 -6.0000e+00 1.6143e-02 -6.7113e-03 9.7571e-04 1.1703e-03 -6.0000e+00 6.8354e-03 1.4645e-02 -4.0151e-04 7.2645e-05 1.2620e-05 -6.0000e+00 4.7134e-04 -4.3829e-03 2.7510e-05 12 9 9 12 1 1 95.83 18.37 0.08 -0.00438 -0.00740 5 77 1 5 0 141.230 21.98 15.01 18.37 28.00 9.2 983.97 1731 224 2106 -2731 -2523 -4780 -3161 -3149 -76 -1428 -3613 -3582 -1901 321 633 2217 1210 3659 1179 2848 681 1658 1366 1463 303 261 1070 -1944 -1089 -2522 36 -405 -433 -2349 -5358 -4543 -4218 -1604 -772 493 299 972 622 986 1716 511 -14 -176 -907 18 760 480 1621 1748 718 946 1423 -91 -167 440 1155 2035 2963 3045 620 -650 -978 -2072 -204 565 545 1138 663 627 -343 -2150 -3000 -4692 -3337 -2911 -1757 -1851 -2469 -1094 -393 441 777 1622 2122 1326 254 -643 -2176 -2059 -1673 -1287 208 1448 1053 -47 -312 -1926 -1692 -1037 -532 -820 246 142 681 1936 2387 2304 1881 938 -744 -2039 -1393 -1153 572 910 1319 1350 1884 157 144 -972 -1728 -1191 -1459 -1099 -505 -1399 -1067 -605 123 956 1516 1477 1195 346 -295 -1265 -1241 441 63 590 -765 -645 -1166 -776 -841 -22 -426 -1094 -1075 -599 109 237 873 495 1492 503 1223 303 729 605 665 144 127 520 -926 -493 -1115 16 -189 -213 -1185 -2666 -2193 -2116 -875 -473 330 212 707 462 735 1275 383 -10 -129 -651 12 550 362 1257 1391 583 780 1184 -76 -139 363 970 1770 2695 2850 589 -590 -840 -1756 -177 526 535 1143 669 623 -329 -1967 -2587 -3940 -2849 -2650 -1707 -1899 -2624 -1186 -442 516 934 1982 2586 1596 294 -706 -2280 -2120 -1779 -1439 244 1779 1342 -60 -380 -2267 -1951 -1229 -658 -1053 320 190 928 2721 3413 3306 2638 1263 -962 -2577 -1757 -1497 769 1271 1864 1890 2595 213 190 -1259 -2184 -1513 -1925 -1501 -704 -1967 -1511 -879 184 1456 2336 2312 1874 540 -455 -1914 -1872 SS 20220306T160349.9Z 8100.669328 146 1 39.44 2 49.90 128.60 78.75 83.84 0.00 1 0.00 1 0 17 1.643e-02 1.381e-02 3.457e-03 1.303e-03 1.718541e-01 6.371625e-04 1.934790e-03 -6.000000e+00 9.226861e-03 226.49 -2.00 3.24 -2.00 317.29 0.00e+00 1.109220e-03 9.155465e-05 5.453850e-04 -6.000000e+00 4.184446e-04 285.61 -2.00 20.00 -2.00 316.46 0.00e+00 1.549 0.000 302.00 328.00 3 3.2274e+00 1.6829e-03 1.7286e-02 -6.0000e+00 2.2834e-02 1.5243e-02 1.9036e-03 7.9171e-03 -6.0000e+00 2.4857e-02 7.5651e-03 1.1161e-03 3.8351e-03 -6.0000e+00 1.4851e-02 -1.6119e-02 5.3736e-04 1.0849e-03 -6.0000e+00 6.2921e-03 3.8338e-03 3.5825e-04 3.7233e-05 1.0141e-05 -6.0000e+00 4.3338e-04 -6.5646e-03 1.1310e-04 12 9 9 12 1 1 100.00 18.39 0.10 -0.00656 -0.00387 412 115 1 5 0 95.080 21.98 15.00 18.39 29.36 9.2 992.20 1030 94 422 -1708 -2687 -2142 -1555 -2159 963 -2340 -2867 -3458 -1563 -1851 576 497 261 2496 945 1995 1318 1733 1682 1113 -9 324 -1044 -2149 -1609 -1861 -659 -556 167 -2237 -4894 -4088 -3830 -2185 -276 120 163 724 555 916 442 739 -566 -203 -1104 -778 467 555 925 1347 922 995 845 74 -47 63 1379 2326 2747 2954 910 -734 -1100 -1789 164 1069 868 1344 896 685 -489 -2067 -3147 -4462 -3620 -2850 -2158 -1822 -2018 -1280 -262 276 1214 1760 1950 1376 192 -597 -2539 -2406 -1978 -1212 -52 1018 881 -49 -399 -2006 -2074 -1181 -929 -1126 174 109 1053 1894 2204 2092 1484 222 -1211 -1834 -1518 -920 499 900 1214 1412 1551 363 246 -1209 -2177 -1605 -1307 -1325 -768 -1284 -1064 -533 416 676 1352 1705 1016 533 -41 -1121 -1322 145 15 67 -263 -383 -278 -204 -318 154 -403 -488 -587 -280 -376 129 121 66 628 249 550 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