File name: Pandora63s1_LaPorteTX_20220330_L2Fit_fout2c2d20210924p1-8.txt File generation date: 20250514T171232.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 63 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora63_OF_v2d20210219.txt Instrument calibration file used: Pandora63s1_CF_v2d20210924.txt Level 1 file used: Pandora63s1_LaPorteTX_20220330_L1_smca1c2d20210924p1-8.txt Full location name: University Of Houston Trailer Short location name: LaPorteTX Country of location: United States Location latitude [deg]: 29.6721 Location longitude [deg]: -95.0647 Location altitude [m]: 22 Local noon date: 20220330 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 141 283 Nominal wavelengths inside fitting window [nm]: 305.0348 305.1762 305.3175 305.4588 305.6002 305.7415 305.8828 306.0240 306.1653 306.3066 306.4478 306.5891 306.7303 306.8715 307.0127 307.1539 307.2951 307.4362 307.5774 307.7185 307.8597 308.0008 308.1419 308.2830 308.4241 308.5652 308.7063 308.8473 308.9884 309.1294 309.2704 309.4114 309.5524 309.6934 309.8344 309.9753 310.1163 310.2572 310.3982 310.5391 310.6800 310.8209 310.9618 311.1027 311.2435 311.3844 311.5252 311.6661 311.8069 311.9477 312.0885 312.2293 312.3700 312.5108 312.6515 312.7923 312.9330 313.0737 313.2144 313.3551 313.4958 313.6365 313.7771 313.9178 314.0584 314.1991 314.3397 314.4803 314.6209 314.7615 314.9020 315.0426 315.1831 315.3237 315.4642 315.6047 315.7452 315.8857 316.0262 316.1667 316.3071 316.4476 316.5880 316.7284 316.8688 317.0092 317.1496 317.2900 317.4304 317.5707 317.7111 317.8514 317.9917 318.1321 318.2724 318.4126 318.5529 318.6932 318.8334 318.9737 319.1139 319.2541 319.3944 319.5346 319.6747 319.8149 319.9551 320.0952 320.2354 320.3755 320.5156 320.6557 320.7958 320.9359 321.0760 321.2161 321.3561 321.4962 321.6362 321.7762 321.9162 322.0562 322.1962 322.3362 322.4761 322.6161 322.7560 322.8959 323.0359 323.1758 323.3157 323.4555 323.5954 323.7353 323.8751 324.0150 324.1548 324.2946 324.4344 324.5742 324.7140 324.8538 324.9935 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220330T165306.6Z 8124.703549 180 1 2.64 2 33.63 135.51 38.76 168.77 0.00 1 0.00 1 0 25 1.874e-02 1.608e-02 4.111e-03 2.727e-03 1.552356e-01 1.366480e-03 1.658812e-03 -6.000000e+00 1.058096e-02 228.23 -2.00 3.24 -2.00 315.18 0.00e+00 1.161252e-03 1.254644e-04 1.697957e-04 -6.000000e+00 4.797356e-04 286.94 -2.00 20.00 -2.00 314.48 0.00e+00 1.200 0.000 302.00 328.00 3 3.3349e+00 3.5131e-03 1.3857e-02 -6.0000e+00 2.6279e-02 -8.6705e-04 3.9216e-03 7.0097e-03 -6.0000e+00 2.8573e-02 -1.2719e-02 2.2411e-03 3.3249e-03 -6.0000e+00 1.7062e-02 -7.0695e-03 9.8770e-04 9.8785e-04 -6.0000e+00 7.2036e-03 5.0469e-03 7.9750e-04 7.5221e-05 1.0535e-05 -6.0000e+00 4.9448e-04 2.4700e-03 1.9744e-04 12 9 9 12 1 1 98.12 18.31 0.13 0.00247 0.00846 4 22 1 5 0 494.370 21.98 15.00 18.31 21.41 9.4 949.75 2090 1060 1603 -340 -3438 -3507 -4401 160 -1920 -14 -4448 -2847 -1639 -177 709 594 1523 1313 2339 1963 3458 1951 2303 -72 607 1375 -822 -1303 -2334 -1766 -1912 -382 -1245 -2261 -5705 -4230 -4553 -1948 -98 969 645 237 1637 883 1518 969 381 -330 -935 -1018 -66 626 1228 2127 921 1725 682 636 404 1021 1377 2046 2828 2800 1142 -666 -1901 -2913 -97 488 1538 584 883 414 -749 -2295 -3222 -4761 -3310 -3205 -2248 -1808 -2238 -1343 43 482 1553 2110 2106 1156 133 -871 -2594 -2511 -1968 -1239 212 1017 1277 482 -215 -1781 -2344 -815 -813 -834 -58 -77 1396 1850 2420 2227 2155 530 -1151 -2102 -1753 -942 645 1453 1715 2350 1694 591 205 -1419 -2451 -1765 -1292 -946 -1162 -1372 -962 -405 490 813 1338 1378 1169 597 212 -1462 -1607 646 353 540 -111 -1051 -1007 -1297 50 -659 -5 -1573 -994 -597 -70 303 267 698 612 1107 952 1684 953 1125 -36 319 732 -443 -677 -1159 -848 -936 -193 -663 -1221 -3031 -2167 -2458 -1144 -64 689 485 183 1272 695 1190 759 296 -252 -698 -754 -50 490 992 1744 770 1454 584 545 343 863 1190 1840 2644 2698 1098 -616 -1666 -2505 -86 464 1522 597 901 415 -729 -2124 -2800 -4045 -2849 -2956 -2201 -1856 -2383 -1459 49 563 1863 2574 2570 1389 153 -955 -2711 -2584 -2080 -1380 247 1243 1607 602 -257 -2065 -2690 -955 -1000 -1063 -75 -102 1883 2572 3418 3138 2952 698 -1460 -2600 -2182 -1204 854 1990 2379 3225 2300 787 267 -1803 -3049 -2212 -1676 -1267 -1585 -1880 -1327 -573 714 1212 2018 2100 1792 908 318 -2172 -2381 SS 20220330T171148.1Z 8124.716529 195 1 2.97 2 30.96 142.68 38.16 176.01 0.00 1 0.00 1 0 17 1.692e-02 1.476e-02 6.463e-03 4.333e-03 1.577710e-01 2.178547e-03 1.712440e-03 -6.000000e+00 9.554679e-03 228.23 -2.00 3.24 -2.00 315.09 0.00e+00 9.510488e-04 1.961713e-04 1.587920e-04 -6.000000e+00 4.331374e-04 286.94 -2.00 20.00 -2.00 314.41 0.00e+00 1.166 0.000 302.00 328.00 3 4.1653e+00 5.5942e-03 1.3676e-02 -6.0000e+00 2.3730e-02 5.3572e-02 6.2382e-03 7.1806e-03 -6.0000e+00 2.5800e-02 -1.7029e-02 3.5669e-03 3.4515e-03 -6.0000e+00 1.5405e-02 -5.1474e-03 1.5741e-03 9.7551e-04 -6.0000e+00 6.5080e-03 2.2200e-03 -8.3175e-04 1.1887e-04 1.1585e-05 -6.0000e+00 4.4650e-04 -6.0637e-03 -5.6345e-05 12 9 9 12 1 1 999.00 18.30 0.18 -0.00606 -0.01231 2 12 1 5 0 933.180 21.98 15.00 18.30 24.46 9.3 966.72 2523 614 1123 -1054 -756 -1350 -1028 -2604 271 -1959 -2153 -3061 -1700 -119 561 641 -386 2811 781 3584 1321 1176 604 1896 138 1023 -875 -1752 -1087 -3395 -1151 -340 -109 -1246 -4959 -5132 -3923 -2286 -861 1309 261 151 1420 515 1016 1109 -360 295 -631 -1893 720 125 687 2323 1040 1467 1553 387 866 404 1761 2327 1680 2992 700 -347 -1645 -2296 7 1257 449 1359 615 556 460 -2194 -3078 -5173 -2323 -3893 -2243 -1913 -2028 -1724 82 184 1514 2370 1696 932 194 -393 -2094 -2197 -2465 -1382 247 922 878 528 337 -2003 -1592 -1006 -110 -975 -556 -759 1039 2270 2079 1962 1794 263 -969 -1567 -1271 -846 889 841 1556 1331 1566 521 699 -698 -1787 -1254 -1151 -1222 -912 -1102 -1239 -87 225 580 1267 1297 838 693 -362 -1130 -1233 786 209 387 -353 -232 -387 -298 -832 92 -705 -766 -1085 -627 -48 243 293 -183 1320 380 1740 663 590 302 965 74 557 -481 -931 -545 -1674 -563 -173 -58 -680 -2663 -2677 -2113 -1354 -571 939 199 119 1129 413 814 885 -286 228 -479 -1436 548 100 563 1934 883 1260 1343 337 744 348 1531 2106 1599 2920 687 -325 -1460 -1984 6 1193 452 1396 636 565 451 -2051 -2701 -4413 -1984 -3598 -2197 -1969 -2168 -1891 93 216 1830 2904 2087 1133 227 -433 -2195 -2248 -2612 -1533 288 1130 1110 661 406 -2326 -1810 -1174 -135 -1236 -722 -1009 1401 3139 2944 2777 2465 349 -1222 -1926 -1561 -1070 1165 1145 2149 1825 2112 691 900 -878 -2194 -1540 -1470 -1614 -1230 -1495 -1692 -121 323 855 1887 1955 1272 1041 -536 -1655 -1795 SS 20220330T171535.0Z 8124.719155 198 1 18.05 2 30.47 144.26 38.09 177.50 0.00 1 0.00 1 0 17 1.637e-02 1.405e-02 1.479e-03 8.703e-04 1.531227e-01 4.355839e-04 1.683123e-03 -6.000000e+00 9.254543e-03 228.23 -2.00 3.24 -2.00 315.68 0.00e+00 9.936028e-04 4.420507e-05 2.312184e-04 -6.000000e+00 4.193349e-04 286.94 -2.00 20.00 -2.00 314.93 0.00e+00 1.160 0.000 302.00 328.00 3 3.0017e+00 1.1267e-03 1.3507e-02 -6.0000e+00 2.2985e-02 3.5747e-02 1.2615e-03 6.9467e-03 -6.0000e+00 2.4983e-02 -1.2008e-02 7.2143e-04 3.3570e-03 -6.0000e+00 1.4918e-02 -6.2351e-03 3.2401e-04 9.6092e-04 -6.0000e+00 6.3064e-03 7.2552e-03 1.8719e-04 2.4173e-05 1.0934e-05 -6.0000e+00 4.3204e-04 -7.3220e-03 1.0123e-04 12 9 9 12 1 1 99.99 18.29 0.08 -0.00732 -0.00592 86 53 1 5 0 205.440 21.98 15.00 18.29 24.92 9.4 970.39 1461 1290 1219 -1537 -2415 -2460 -2360 -1564 -337 -1730 -3268 -2919 -1736 -512 866 1344 787 2086 1338 2650 1876 1210 1642 1628 760 631 -310 -1729 -1682 -2002 -868 -1176 28 -2664 -5044 -4283 -3917 -1993 -168 547 294 753 931 1005 820 664 34 -333 -1015 -504 546 333 998 1329 987 1215 913 192 94 399 1072 2073 2607 2716 914 -624 -1153 -1861 -171 884 533 1031 785 745 -367 -1809 -3193 -4397 -3485 -2905 -2347 -1838 -2229 -1357 -89 294 991 1569 1797 1352 293 -720 -2234 -2256 -2003 -1196 -32 1270 881 177 -181 -1709 -1890 -1066 -811 -1082 157 82 1128 1952 2351 2102 1597 551 -786 -1653 -1516 -979 415 876 1205 1398 1690 556 342 -1200 -1879 -1471 -1324 -1110 -556 -1132 -1035 -372 414 664 1286 1517 999 384 -31 -1140 -1590 360 348 334 -408 -631 -586 -566 -414 -98 -533 -999 -874 -546 -178 334 505 306 811 536 1077 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