File name: Pandora63s1_LaPorteTX_20220409_L2Fit_fout2c2d20210924p1-8.txt File generation date: 20250514T172107.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 63 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora63_OF_v2d20210219.txt Instrument calibration file used: Pandora63s1_CF_v2d20210924.txt Level 1 file used: Pandora63s1_LaPorteTX_20220409_L1_smca1c2d20210924p1-8.txt Full location name: University Of Houston Trailer Short location name: LaPorteTX Country of location: United States Location latitude [deg]: 29.6721 Location longitude [deg]: -95.0647 Location altitude [m]: 22 Local noon date: 20220409 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 141 283 Nominal wavelengths inside fitting window [nm]: 305.0348 305.1762 305.3175 305.4588 305.6002 305.7415 305.8828 306.0240 306.1653 306.3066 306.4478 306.5891 306.7303 306.8715 307.0127 307.1539 307.2951 307.4362 307.5774 307.7185 307.8597 308.0008 308.1419 308.2830 308.4241 308.5652 308.7063 308.8473 308.9884 309.1294 309.2704 309.4114 309.5524 309.6934 309.8344 309.9753 310.1163 310.2572 310.3982 310.5391 310.6800 310.8209 310.9618 311.1027 311.2435 311.3844 311.5252 311.6661 311.8069 311.9477 312.0885 312.2293 312.3700 312.5108 312.6515 312.7923 312.9330 313.0737 313.2144 313.3551 313.4958 313.6365 313.7771 313.9178 314.0584 314.1991 314.3397 314.4803 314.6209 314.7615 314.9020 315.0426 315.1831 315.3237 315.4642 315.6047 315.7452 315.8857 316.0262 316.1667 316.3071 316.4476 316.5880 316.7284 316.8688 317.0092 317.1496 317.2900 317.4304 317.5707 317.7111 317.8514 317.9917 318.1321 318.2724 318.4126 318.5529 318.6932 318.8334 318.9737 319.1139 319.2541 319.3944 319.5346 319.6747 319.8149 319.9551 320.0952 320.2354 320.3755 320.5156 320.6557 320.7958 320.9359 321.0760 321.2161 321.3561 321.4962 321.6362 321.7762 321.9162 322.0562 322.1962 322.3362 322.4761 322.6161 322.7560 322.8959 323.0359 323.1758 323.3157 323.4555 323.5954 323.7353 323.8751 324.0150 324.1548 324.2946 324.4344 324.5742 324.7140 324.8538 324.9935 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220409T134053.4Z 8134.570063 124 1 47.66 2 69.06 93.03 123.88 13.42 0.00 1 0.00 1 0 25 4.896e-02 1.490e-02 4.239e-02 4.131e-03 3.423243e-01 2.059752e-03 3.947712e-03 -6.000000e+00 2.773688e-02 228.97 -2.00 3.24 -2.00 319.49 0.00e+00 1.935523e-03 5.641880e-04 2.003349e-03 -6.000000e+00 1.257124e-03 287.58 -2.00 20.00 -2.00 318.67 0.00e+00 2.770 0.000 302.00 328.00 3 4.5611e+00 5.8946e-03 3.2959e-02 -6.0000e+00 6.8996e-02 8.9791e-04 6.9291e-03 1.9341e-02 -6.0000e+00 7.4958e-02 3.7398e-03 5.0675e-03 9.0165e-03 -6.0000e+00 4.4749e-02 -9.2549e-03 2.6445e-03 2.2672e-03 -6.0000e+00 1.8890e-02 2.3160e-04 -4.6954e-04 1.1934e-04 3.0375e-05 -6.0000e+00 1.2925e-03 -6.8982e-03 -3.4898e-05 12 8 8 10 0 0 36.98 17.52 0.11 -0.00690 -0.01043 12 3 1 5 0 3971.370 21.38 15.00 17.52 25.33 9.4 973.02 17545 -9577 7441 -22688 4940 -21263 -23154 -4735 -11892 -2960 -10684 3585 -8143 4244 -8466 2305 4755 1199 -6432 -2277 -2816 -7355 11369 666 2211 -4486 1481 -4912 -4775 -5466 -2741 -6302 -418 -1867 -5080 -6211 -5187 -1703 -3179 1700 462 2402 2009 123 1850 3531 -178 558 712 -1719 2303 960 -526 1314 692 472 680 1232 -1257 -470 2126 2455 3431 3114 1071 -229 267 -1314 795 562 390 721 952 584 -753 -2677 -4118 -4611 -3450 -3427 -2592 -931 -2381 -802 -255 1403 2011 1737 2883 1350 468 -608 -2636 -3382 -1505 -1529 67 508 652 -235 288 -2282 -2826 -940 -797 -914 323 105 1321 2052 2396 1909 1413 -634 -1622 -2676 -1642 -774 550 896 1496 1384 1697 585 363 -1565 -2536 -1695 -1508 -1399 -578 -1197 -968 -35 917 493 1303 1616 1355 -157 305 -1566 -1175 394 -312 219 -858 134 -691 -792 -154 -464 -113 -445 136 -387 213 -566 157 342 95 -576 -206 -265 -724 950 65 230 -520 163 -557 -517 -594 -313 -836 -58 -276 -747 -896 -791 -296 -680 405 124 669 585 37 556 1055 -55 171 217 -547 752 345 -206 534 294 207 305 550 -564 -208 953 1189 1808 1771 631 -129 140 -693 444 356 270 520 685 407 -498 -1640 -2342 -2555 -2019 -2277 -1929 -750 -2077 -721 -243 1405 2111 1882 3089 1421 467 -567 -2333 -3002 -1410 -1587 76 628 855 -307 352 -2627 -3141 -1070 -975 -1175 428 145 1910 3157 3874 3135 2270 -980 -2366 -3797 -2325 -1140 853 1450 2435 2211 2638 892 535 -2253 -3550 -2408 -2308 -2298 -984 -2092 -1727 -65 1773 989 2659 3329 2799 -320 602 -3024 -2249 SS 20220409T134629.2Z 8134.573949 127 1 47.62 2 67.84 93.75 123.61 14.83 0.00 1 0.00 1 0 17 4.967e-02 1.489e-02 3.299e-02 3.788e-03 3.286894e-01 1.885559e-03 3.839205e-03 -6.000000e+00 2.813750e-02 228.97 -2.00 3.24 -2.00 319.32 0.00e+00 2.401489e-03 4.892486e-04 1.933350e-03 -6.000000e+00 1.275382e-03 287.58 -2.00 20.00 -2.00 318.49 0.00e+00 2.629 0.000 302.00 328.00 3 4.5461e+00 5.3363e-03 3.1289e-02 -6.0000e+00 6.9992e-02 1.3284e-02 6.2369e-03 1.8195e-02 -6.0000e+00 7.6043e-02 6.5836e-03 4.4454e-03 8.7532e-03 -6.0000e+00 4.5396e-02 -1.4678e-02 2.3192e-03 2.3152e-03 -6.0000e+00 1.9163e-02 2.7246e-04 -5.4627e-04 1.0922e-04 2.9536e-05 -6.0000e+00 1.3114e-03 -7.6667e-03 -8.8750e-05 12 8 8 10 0 0 54.42 17.56 0.17 -0.00767 -0.01177 13 3 1 5 0 3662.260 21.48 15.00 17.56 25.81 9.4 975.66 -16323 -13565 11994 -18167 -1720 -20850 -11267 -19040 634 -12006 -9638 -10697 -16241 -7465 -4071 -2212 -555 6152 -5417 6301 -2757 6401 -803 5226 -2448 628 4427 -6757 1352 -8555 1237 -6079 980 -239 -7509 -6010 -5824 -466 -2087 1769 -1608 2300 433 3138 -1185 1443 1216 696 587 -1609 1545 226 1640 -474 2467 1617 1837 -114 -865 1333 1878 3672 3801 3982 1238 -475 -622 -2125 -843 1387 725 100 576 282 -649 -3567 -2695 -5733 -3185 -3091 -1920 -1588 -2249 -1178 209 501 1004 2600 2233 1549 -100 -318 -2679 -2812 -1379 -1103 63 806 699 -808 75 -2453 -2289 -977 -863 -1106 141 765 1080 2064 2421 2210 1018 118 -1450 -2143 -1824 -1319 803 1263 1827 1213 1828 -170 45 -1364 -2748 -1595 -1681 -1298 -578 -823 -1247 -51 193 841 1349 1431 1119 536 -180 -1199 -1193 -571 -527 387 -755 -57 -770 -394 -803 25 -564 -449 -520 -941 -473 -294 -177 -47 518 -538 586 -289 616 -84 544 -293 77 524 -858 153 -1056 149 -882 147 -38 -1230 -943 -974 -87 -478 456 -473 692 137 991 -395 474 399 228 192 -546 541 87 666 -208 1090 740 856 -54 -408 614 890 1851 2093 2360 760 -280 -344 -1174 -496 904 520 75 429 204 -445 -2274 -1567 -3310 -1912 -2104 -1452 -1317 -2002 -1087 203 516 1084 2843 2450 1661 -103 -301 -2409 -2513 -1305 -1153 72 1002 920 -1063 92 -2849 -2548 -1121 -1061 -1432 187 1057 1573 3176 3896 3612 1634 180 -2105 -3008 -2573 -1937 1231 2026 2951 1934 2833 -259 67 -1947 -3822 -2252 -2553 -2111 -974 -1419 -2200 -93 369 1663 2710 2914 2287 1078 -353 -2282 -2258 SS 20220409T135226.5Z 8134.578085 130 1 50.66 2 66.55 94.53 123.28 16.31 0.00 1 0.00 1 0 17 4.556e-02 1.505e-02 2.841e-02 3.484e-03 3.129012e-01 1.731303e-03 3.581878e-03 -6.000000e+00 2.581715e-02 228.97 -2.00 3.24 -2.00 319.17 0.00e+00 1.551278e-03 4.269374e-04 1.665201e-03 -6.000000e+00 1.169855e-03 287.58 -2.00 20.00 -2.00 318.33 0.00e+00 2.494 0.000 302.00 328.00 3 4.5627e+00 4.8605e-03 2.9574e-02 -6.0000e+00 6.4221e-02 4.2566e-03 5.6558e-03 1.7036e-02 -6.0000e+00 6.9764e-02 1.2271e-02 3.9511e-03 7.9607e-03 -6.0000e+00 4.1648e-02 -1.5867e-02 2.0598e-03 2.0286e-03 -6.0000e+00 1.7586e-02 3.1385e-04 -1.3641e-04 1.0055e-04 2.2955e-05 -6.0000e+00 1.2026e-03 -8.5884e-03 -2.1280e-05 12 8 8 10 0 0 36.71 17.60 0.18 -0.00859 -0.00961 15 3 1 5 0 3377.000 21.48 15.00 17.60 26.37 9.4 978.81 556 -19780 17410 -18340 7105 -8406 -3536 -6446 -3401 -4225 -16290 13068 -18408 2819 -1478 7638 -3569 2865 -3481 3647 -149 3779 4400 -661 1471 -5404 455 -6807 -2615 -6634 -3245 -2557 -4179 -1888 -11680 -1495 -5756 -2288 -1917 2106 -87 743 1514 332 3533 -147 2789 -1685 1983 -1629 1976 1744 2430 1226 1531 1950 -300 445 -686 1392 -454 3776 2880 4098 314 -1301 -211 -2315 667 325 1850 714 1104 -353 -649 -2255 -3490 -5245 -3996 -2608 -3056 -508 -2722 -1231 -739 1043 1818 1819 2461 1427 538 -931 -1886 -2511 -1737 -1745 255 1193 743 -168 -1050 -2315 -2606 -645 -829 -519 -544 602 1219 2263 2306 1828 1533 -222 -1122 -2372 -1483 -1236 184 1044 1611 1426 1511 485 -42 -1253 -2426 -1544 -1878 -1273 -1126 -689 -1022 -372 613 894 1141 1726 1349 212 -8 -1368 -1276 19 -928 607 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