File name: Pandora63s1_LaPorteTX_20220426_L2Fit_fout2c2d20210924p1-8.txt File generation date: 20250514T172644.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 63 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora63_OF_v2d20210219.txt Instrument calibration file used: Pandora63s1_CF_v2d20210924.txt Level 1 file used: Pandora63s1_LaPorteTX_20220426_L1_smca1c2d20210924p1-8.txt Full location name: University Of Houston Trailer Short location name: LaPorteTX Country of location: United States Location latitude [deg]: 29.6721 Location longitude [deg]: -95.0647 Location altitude [m]: 22 Local noon date: 20220426 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 141 283 Nominal wavelengths inside fitting window [nm]: 305.0348 305.1762 305.3175 305.4588 305.6002 305.7415 305.8828 306.0240 306.1653 306.3066 306.4478 306.5891 306.7303 306.8715 307.0127 307.1539 307.2951 307.4362 307.5774 307.7185 307.8597 308.0008 308.1419 308.2830 308.4241 308.5652 308.7063 308.8473 308.9884 309.1294 309.2704 309.4114 309.5524 309.6934 309.8344 309.9753 310.1163 310.2572 310.3982 310.5391 310.6800 310.8209 310.9618 311.1027 311.2435 311.3844 311.5252 311.6661 311.8069 311.9477 312.0885 312.2293 312.3700 312.5108 312.6515 312.7923 312.9330 313.0737 313.2144 313.3551 313.4958 313.6365 313.7771 313.9178 314.0584 314.1991 314.3397 314.4803 314.6209 314.7615 314.9020 315.0426 315.1831 315.3237 315.4642 315.6047 315.7452 315.8857 316.0262 316.1667 316.3071 316.4476 316.5880 316.7284 316.8688 317.0092 317.1496 317.2900 317.4304 317.5707 317.7111 317.8514 317.9917 318.1321 318.2724 318.4126 318.5529 318.6932 318.8334 318.9737 319.1139 319.2541 319.3944 319.5346 319.6747 319.8149 319.9551 320.0952 320.2354 320.3755 320.5156 320.6557 320.7958 320.9359 321.0760 321.2161 321.3561 321.4962 321.6362 321.7762 321.9162 322.0562 322.1962 322.3362 322.4761 322.6161 322.7560 322.8959 323.0359 323.1758 323.3157 323.4555 323.5954 323.7353 323.8751 324.0150 324.1548 324.2946 324.4344 324.5742 324.7140 324.8538 324.9935 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220426T153350.3Z 8151.648499 211 1 48.27 2 41.11 103.88 40.23 185.57 0.00 1 0.00 1 0 25 1.871e-02 1.457e-02 3.865e-03 1.751e-03 1.664554e-01 8.705396e-04 1.845322e-03 -6.000000e+00 1.064205e-02 230.01 -2.00 3.24 -2.00 316.68 0.00e+00 1.212373e-03 1.088623e-04 4.061023e-04 -6.000000e+00 4.829362e-04 288.76 -2.00 20.00 -2.00 315.82 0.00e+00 1.326 0.000 302.00 328.00 3 4.7971e+00 2.2891e-03 1.5289e-02 -6.0000e+00 2.6527e-02 2.1379e-02 2.5737e-03 7.6305e-03 -6.0000e+00 2.8792e-02 -5.3735e-03 1.4840e-03 3.6818e-03 -6.0000e+00 1.7186e-02 -1.0049e-02 6.9175e-04 1.0444e-03 -6.0000e+00 7.2463e-03 9.9810e-04 3.3806e-04 4.9371e-05 1.0079e-05 -6.0000e+00 4.9412e-04 -2.8358e-03 9.4483e-05 12 8 8 10 0 0 99.94 18.14 0.16 -0.00284 -0.00030 30 7 1 5 0 1608.790 21.88 15.00 18.14 26.55 9.8 981.13 1799 2303 1635 -2058 -3520 -4953 -3515 -4024 -1330 -3062 -3009 -4759 -2715 -427 -355 1368 1037 1873 1549 2253 1957 1483 2356 1408 264 605 -16 -1634 -1951 -2229 -1101 -1291 -58 -2525 -5665 -4742 -3737 -1638 -277 996 262 1021 525 536 1134 1085 448 -141 -1000 -814 154 399 685 1488 1097 982 833 191 198 447 1311 2356 2897 2941 529 -785 -943 -2123 -249 880 602 1362 891 504 -441 -2362 -3064 -4643 -3439 -3071 -2395 -1658 -2211 -1078 130 320 1139 1782 2007 978 294 -772 -2524 -2219 -2038 -1351 -179 1159 873 35 -244 -1750 -2249 -1141 -1097 -1074 119 191 1186 2016 2486 2084 1555 261 -1496 -2048 -1685 -1131 556 1194 1581 1523 1712 387 108 -1358 -2106 -1275 -1492 -1179 -830 -918 -1134 -396 695 717 1447 1441 973 387 -119 -1274 -1429 316 441 320 -393 -620 -812 -589 -740 -265 -661 -636 -1012 -608 -106 -99 404 317 577 492 732 651 490 786 490 98 231 -6 -591 -673 -735 -366 -459 -22 -985 -2143 -1741 -1443 -707 -141 564 163 656 346 356 747 711 288 -90 -617 -495 96 264 475 1062 803 731 629 144 147 329 987 1880 2480 2584 469 -658 -729 -1592 -196 773 565 1319 866 476 -401 -2012 -2346 -3472 -2638 -2561 -2217 -1622 -2299 -1132 144 373 1394 2228 2495 1183 338 -825 -2533 -2200 -2075 -1500 -212 1446 1148 45 -301 -2053 -2571 -1361 -1390 -1405 160 267 1715 2986 3807 3184 2314 369 -1956 -2605 -2150 -1515 773 1765 2335 2271 2468 540 147 -1820 -2694 -1636 -1999 -1677 -1217 -1356 -1666 -604 1114 1176 2419 2456 1672 654 -196 -2090 -2334 SS 20220426T153826.9Z 8151.651700 214 1 4.94 2 40.14 104.74 40.32 187.29 0.00 1 0.00 1 0 17 1.995e-02 1.573e-02 8.966e-03 5.594e-03 1.667267e-01 2.821933e-03 1.771559e-03 -6.000000e+00 1.133567e-02 230.01 -2.00 3.24 -2.00 315.45 0.00e+00 8.988801e-04 2.716347e-04 1.701214e-04 -6.000000e+00 5.146119e-04 288.76 -2.00 20.00 -2.00 314.70 0.00e+00 1.307 0.000 302.00 328.00 3 4.7466e+00 7.2995e-03 1.5109e-02 -6.0000e+00 2.8256e-02 3.0915e-02 8.1427e-03 7.6051e-03 -6.0000e+00 3.0675e-02 -1.1597e-02 4.6518e-03 3.6407e-03 -6.0000e+00 1.8310e-02 -6.0095e-03 2.0682e-03 1.0139e-03 -6.0000e+00 7.7151e-03 1.0671e-03 -8.7599e-04 1.5433e-04 1.1248e-05 -6.0000e+00 5.2682e-04 -1.7179e-03 -4.3050e-05 12 9 9 12 1 1 999.00 18.14 0.14 -0.00172 -0.00830 1 5 1 5 0 2382.980 21.88 15.01 18.14 26.93 9.8 983.16 -198 1822 669 1665 -6918 -484 -6947 -2202 -1942 777 -5055 -445 -778 -1390 450 839 1169 1861 2432 1804 1634 1642 3838 3321 386 137 -1369 -1962 -946 -1073 -2027 1550 -446 -1543 -4914 -4735 -5612 -2732 1680 1226 1193 698 1422 82 991 2070 -884 -763 -1770 -894 85 129 1288 1722 707 1353 126 -1300 -343 741 1758 1929 3347 2465 694 -376 -1869 -2427 810 926 602 2099 1321 599 -929 -1408 -3050 -4348 -4240 -3181 -2187 -2163 -1836 -1463 -757 578 1269 2072 2326 1381 1409 -519 -2302 -2338 -2518 -956 66 1049 1103 551 73 -1544 -2340 -1544 -1246 28 -186 298 912 1459 1791 1548 2275 37 -994 -1909 -1730 -223 586 719 1389 2183 1383 653 409 -1974 -2031 -840 -1088 -1010 -173 -981 -1068 -193 281 178 1655 1674 822 619 539 -1961 -1694 -55 541 204 482 -1955 -122 -1867 -625 -601 245 -1642 -139 -258 -508 178 352 502 807 1072 820 757 758 1739 1552 192 70 -704 -973 -441 -486 -937 733 -225 -794 -2487 -2327 -2906 -1548 1046 843 871 526 1087 64 763 1581 -679 -572 -1305 -650 63 100 1024 1401 587 1132 107 -1118 -290 621 1497 1716 3090 2363 670 -346 -1630 -2067 705 871 599 2127 1344 603 -906 -1291 -2643 -3643 -3636 -2910 -2133 -2227 -1951 -1596 -857 679 1536 2547 2849 1667 1629 -572 -2411 -2405 -2674 -1063 77 1292 1401 695 89 -1799 -2690 -1828 -1547 36 -244 397 1244 2048 2566 2218 3155 49 -1273 -2378 -2161 -286 780 996 1946 3027 1898 877 536 -2544 -2536 -1049 -1411 -1359 -236 -1355 -1489 -275 412 269 2518 2578 1276 950 812 -2940 -2525 SS 20220426T155055.6Z 8151.660365 223 1 48.15 2 37.53 107.20 40.72 191.90 0.00 1 0.00 1 0 25 1.807e-02 1.449e-02 3.984e-03 1.929e-03 1.592150e-01 9.618221e-04 1.754879e-03 -6.000000e+00 1.027841e-02 230.01 -2.00 3.24 -2.00 316.46 0.00e+00 1.221435e-03 1.141987e-04 3.370673e-04 -6.000000e+00 4.663815e-04 288.76 -2.00 20.00 -2.00 315.61 0.00e+00 1.260 0.000 302.00 328.00 3 5.0389e+00 2.5213e-03 1.4551e-02 -6.0000e+00 2.5621e-02 3.7155e-02 2.8286e-03 7.2896e-03 -6.0000e+00 2.7807e-02 -6.3732e-03 1.6252e-03 3.5152e-03 -6.0000e+00 1.6598e-02 -1.0313e-02 7.5025e-04 1.0168e-03 -6.0000e+00 6.9996e-03 8.4388e-04 3.3483e-04 5.4267e-05 9.8125e-06 -6.0000e+00 4.7710e-04 -3.4848e-03 1.2559e-04 12 8 8 10 0 0 99.94 18.15 0.14 -0.00348 -0.00097 25 6 1 5 0 1925.470 21.88 15.00 18.15 27.75 9.7 986.70 1216 1230 1199 -1277 -4116 -1710 -4919 -819 -2209 -1391 -4523 -2079 -1418 -1076 641 1366 1171 2017 1889 1621 2304 247 2974 996 461 834 -1904 -1321 -2454 -1595 -1741 -778 -1140 -2051 -6199 -4309 -4205 -2071 -268 44 848 663 1379 552 1611 893 794 -621 -863 -721 364 641 606 1974 1119 1273 171 730 -83 218 1125 2024 2397 2685 1019 -607 -1449 -2178 336 862 819 1190 935 741 -600 -2244 -3295 -4313 -4119 -3138 -2390 -1650 -2627 -870 86 356 1307 1486 2165 1078 605 -903 -2408 -2628 -2015 -1198 40 1213 540 106 -186 -1936 -1971 -1125 -1117 -855 182 188 1160 1883 2392 2059 1725 22 -1081 -1904 -1582 -1202 554 885 1352 1594 1569 449 152 -1329 -2042 -1292 -1527 -1001 -807 -918 -1061 -469 681 691 1338 1521 1078 217 -30 -1355 -1322 237 262 259 -268 -800 -301 -904 -161 -490 -319 -1053 -469 -340 -288 189 432 382 663 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