File name: Pandora63s1_LaPorteTX_20220525_L2Fit_fout2c2d20210924p1-8.txt File generation date: 20250514T174055.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 63 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora63_OF_v2d20210219.txt Instrument calibration file used: Pandora63s1_CF_v2d20210924.txt Level 1 file used: Pandora63s1_LaPorteTX_20220525_L1_smca1c2d20210924p1-8.txt Full location name: University Of Houston Trailer Short location name: LaPorteTX Country of location: United States Location latitude [deg]: 29.6721 Location longitude [deg]: -95.0647 Location altitude [m]: 22 Local noon date: 20220525 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 141 283 Nominal wavelengths inside fitting window [nm]: 305.0348 305.1762 305.3175 305.4588 305.6002 305.7415 305.8828 306.0240 306.1653 306.3066 306.4478 306.5891 306.7303 306.8715 307.0127 307.1539 307.2951 307.4362 307.5774 307.7185 307.8597 308.0008 308.1419 308.2830 308.4241 308.5652 308.7063 308.8473 308.9884 309.1294 309.2704 309.4114 309.5524 309.6934 309.8344 309.9753 310.1163 310.2572 310.3982 310.5391 310.6800 310.8209 310.9618 311.1027 311.2435 311.3844 311.5252 311.6661 311.8069 311.9477 312.0885 312.2293 312.3700 312.5108 312.6515 312.7923 312.9330 313.0737 313.2144 313.3551 313.4958 313.6365 313.7771 313.9178 314.0584 314.1991 314.3397 314.4803 314.6209 314.7615 314.9020 315.0426 315.1831 315.3237 315.4642 315.6047 315.7452 315.8857 316.0262 316.1667 316.3071 316.4476 316.5880 316.7284 316.8688 317.0092 317.1496 317.2900 317.4304 317.5707 317.7111 317.8514 317.9917 318.1321 318.2724 318.4126 318.5529 318.6932 318.8334 318.9737 319.1139 319.2541 319.3944 319.5346 319.6747 319.8149 319.9551 320.0952 320.2354 320.3755 320.5156 320.6557 320.7958 320.9359 321.0760 321.2161 321.3561 321.4962 321.6362 321.7762 321.9162 322.0562 322.1962 322.3362 322.4761 322.6161 322.7560 322.8959 323.0359 323.1758 323.3157 323.4555 323.5954 323.7353 323.8751 324.0150 324.1548 324.2946 324.4344 324.5742 324.7140 324.8538 324.9935 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220525T175335.9Z 8180.745555 328 1 47.64 2 10.15 146.92 52.37 244.91 0.00 1 0.00 1 0 25 1.743e-02 1.443e-02 3.941e-03 2.189e-03 1.416829e-01 1.099197e-03 1.561906e-03 -6.000000e+00 9.945073e-03 230.98 -2.00 3.24 -2.00 315.96 0.00e+00 1.101925e-03 1.178415e-04 2.642458e-04 -6.000000e+00 4.539630e-04 290.94 -2.00 20.00 -2.00 315.12 0.00e+00 1.016 0.000 302.00 328.00 3 5.6280e+00 2.8694e-03 1.2067e-02 -6.0000e+00 2.4830e-02 3.0295e-02 3.2088e-03 6.4698e-03 -6.0000e+00 2.6922e-02 -7.1112e-03 1.8307e-03 3.0997e-03 -6.0000e+00 1.6078e-02 -1.0463e-02 8.2592e-04 8.7334e-04 -6.0000e+00 6.7788e-03 6.1872e-04 -1.3885e-04 6.1260e-05 9.6182e-06 -6.0000e+00 4.6041e-04 -2.4845e-03 3.0484e-05 12 8 8 10 0 0 95.91 18.06 0.19 -0.00248 -0.00353 12 3 1 5 0 3968.940 21.69 15.01 18.06 33.89 10.4 1019.72 3375 257 1603 -3121 -2731 -3611 -230 -2441 -951 -1977 -2889 -1671 -2186 -869 -652 1590 1126 2772 1622 2491 1405 582 2491 791 496 -36 240 -2051 -1551 -2478 -1530 -1075 291 -2512 -5243 -3960 -4781 -1411 -951 1012 514 946 759 877 1233 855 -88 -453 -1035 -1278 605 -5 1599 1469 1487 1026 816 77 -304 295 1062 2111 2714 3000 466 -854 -1191 -2008 -204 711 1204 930 929 743 -336 -1999 -3070 -4533 -3465 -3424 -1922 -1610 -2417 -1443 -132 467 1192 1868 1874 1264 396 -827 -1785 -2680 -1785 -1656 273 1087 745 -98 -182 -1621 -2178 -1231 -954 -800 -176 218 807 2115 2319 2074 1394 317 -951 -1949 -1566 -1162 560 1179 1402 1459 1580 468 300 -1354 -1808 -1465 -1334 -1025 -799 -892 -1117 -298 506 536 1244 1700 1249 271 -155 -1368 -1424 797 68 423 -815 -636 -784 -49 -590 -252 -548 -793 -447 -626 -275 -229 582 426 1045 636 995 578 240 1006 335 220 -17 109 -901 -634 -980 -605 -449 127 -1142 -2310 -1663 -2133 -702 -553 651 356 680 557 646 906 629 -64 -318 -707 -864 413 -4 1196 1132 1166 820 660 62 -245 236 868 1815 2464 2826 442 -758 -979 -1596 -169 645 1163 932 935 730 -317 -1762 -2494 -3529 -2754 -2975 -1800 -1607 -2534 -1556 -148 556 1474 2347 2360 1559 465 -903 -1808 -2666 -1837 -1828 319 1354 967 -126 -222 -1872 -2469 -1451 -1199 -1048 -236 300 1144 3079 3469 3083 2005 432 -1223 -2416 -1956 -1505 759 1673 2029 2096 2222 642 400 -1752 -2250 -1830 -1748 -1404 -1120 -1250 -1589 -433 767 841 1979 2732 2025 438 -246 -2133 -2218 SS 20220525T175910.0Z 8180.749421 331 1 50.12 2 9.55 153.66 53.43 245.98 0.00 1 0.00 1 0 25 1.713e-02 1.439e-02 3.236e-03 1.824e-03 1.398728e-01 9.172827e-04 1.548865e-03 -6.000000e+00 9.778658e-03 230.98 -2.00 3.24 -2.00 315.90 0.00e+00 9.690352e-04 9.705088e-05 2.648495e-04 -6.000000e+00 4.462656e-04 290.94 -2.00 20.00 -2.00 315.06 0.00e+00 1.014 0.000 302.00 328.00 3 5.3759e+00 2.3921e-03 1.2006e-02 -6.0000e+00 2.4415e-02 2.1594e-02 2.6730e-03 6.3860e-03 -6.0000e+00 2.6469e-02 -6.1371e-03 1.5259e-03 3.0614e-03 -6.0000e+00 1.5808e-02 -9.7112e-03 6.8740e-04 8.4378e-04 -6.0000e+00 6.6668e-03 8.0332e-04 1.8680e-04 5.0991e-05 9.8578e-06 -6.0000e+00 4.5249e-04 -3.0810e-03 9.4600e-05 12 8 8 10 0 0 97.17 18.06 0.19 -0.00308 -0.00168 16 4 1 5 0 3131.930 21.69 15.00 18.06 34.03 10.4 1020.75 859 1496 817 -1001 -3684 -2041 -2718 -1238 -1343 -1524 -3783 -1999 -974 -539 1051 452 1412 2396 1691 1040 1570 608 2690 1653 509 438 -410 -1400 -2392 -1773 -1088 -1044 -552 -2403 -6061 -4734 -4332 -1945 -67 363 450 382 1066 830 1064 536 213 61 -433 -273 346 732 675 1754 608 1431 688 440 179 512 1091 2059 2603 2735 864 -831 -1237 -1888 239 427 930 1257 870 763 -850 -1967 -3990 -4029 -4105 -2995 -2421 -1842 -2199 -1124 52 200 1266 1927 1929 1126 394 -724 -2148 -2633 -2091 -1441 63 1115 604 160 -365 -1562 -2238 -957 -787 -768 -134 197 1078 2064 2428 2024 1804 101 -784 -1906 -1414 -1112 470 832 1152 1471 1597 559 407 -1105 -1995 -1521 -1387 -1355 -699 -1090 -857 -228 778 632 1231 1391 1122 142 28 -1233 -1475 211 398 221 -262 -886 -446 -604 -302 -365 -431 -1067 -550 -282 -172 367 170 541 919 668 424 657 254 1106 699 229 203 -191 -617 -1007 -702 -437 -444 -245 -1099 -2726 -2028 -1958 -978 -39 236 315 278 786 617 785 399 154 43 -296 -185 240 530 512 1349 482 1140 558 360 144 409 893 1764 2356 2588 817 -743 -1019 -1509 199 391 902 1265 878 756 -809 -1737 -3278 -3125 -3286 -2609 -2281 -1856 -2318 -1210 58 239 1570 2414 2435 1396 460 -792 -2190 -2623 -2149 -1590 74 1376 777 205 -444 -1808 -2561 -1129 -985 -1004 -179 272 1521 3002 3603 2990 2579 137 -1010 -2368 -1758 -1436 639 1182 1660 2110 2243 766 537 -1432 -2497 -1909 -1826 -1846 -977 -1537 -1206 -332 1169 985 1956 2228 1810 229 44 -1908 -2271 SS 20220525T180952.3Z 8180.756855 334 1 49.34 2 8.79 168.65 55.50 247.96 0.00 1 0.00 1 0 25 1.683e-02 1.444e-02 3.395e-03 1.910e-03 1.393411e-01 9.596126e-04 1.551271e-03 -6.000000e+00 9.606715e-03 230.98 -2.00 3.24 -2.00 315.91 0.00e+00 9.975568e-04 1.017592e-04 2.786537e-04 -6.000000e+00 4.384310e-04 290.94 -2.00 20.00 -2.00 315.07 0.00e+00 1.012 0.000 302.00 328.00 3 5.4250e+00 2.5031e-03 1.1968e-02 -6.0000e+00 2.3986e-02 2.5066e-02 2.7965e-03 6.3491e-03 -6.0000e+00 2.6004e-02 -6.5562e-03 1.5964e-03 3.0428e-03 -6.0000e+00 1.5530e-02 -9.7184e-03 7.1968e-04 8.3763e-04 -6.0000e+00 6.5495e-03 7.6661e-04 1.7049e-04 5.3419e-05 9.9958e-06 -6.0000e+00 4.4458e-04 -3.5334e-03 6.3247e-05 12 8 8 10 0 0 98.14 18.08 0.23 -0.00353 -0.00225 16 4 1 5 0 3083.330 21.69 15.01 18.08 34.54 10.2 1022.82 2467 1424 113 -2373 -2907 -2124 -778 -2010 -938 -1770 -3467 -1163 -769 -458 768 936 1016 2141 1141 2718 1045 1269 2055 1388 8 290 -483 -2198 -2073 -2458 -1070 -1412 -977 -3204 -4980 -4532 -3415 -1887 -523 341 797 935 1367 641 1274 1156 -187 -189 -1228 -666 246 206 784 1331 1392 1135 982 2 -338 54 1209 2432 2717 2819 684 -381 -1181 -1870 199 1018 497 1229 908 746 -702 -2335 -2996 -4328 -3416 -3383 -2292 -2244 -2156 -1226 -130 277 1201 1986 1934 1391 121 -688 -2233 -2404 -2237 -1360 95 1385 868 48 -345 -1887 -1948 -1123 -830 -1093 18 24 1193 1812 2337 2240 1598 223 -1051 -1608 -1480 -1146 293 1108 1373 1570 1692 297 225 -1357 -1852 -1491 -1323 -1290 -772 -1101 -731 -473 537 632 1173 1616 1034 445 -216 -1007 -1569 595 377 31 -626 -691 -463 -172 -493 -253 -500 -972 -316 -222 -147 268 350 389 820 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