File name: Pandora63s1_LaPorteTX_20220704_L2Fit_fout2c2d20210924p1-8.txt File generation date: 20250514T175813.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 63 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora63_OF_v2d20210219.txt Instrument calibration file used: Pandora63s1_CF_v2d20210924.txt Level 1 file used: Pandora63s1_LaPorteTX_20220704_L1_smca1c2d20210924p1-8.txt Full location name: University Of Houston Trailer Short location name: LaPorteTX Country of location: United States Location latitude [deg]: 29.6721 Location longitude [deg]: -95.0647 Location altitude [m]: 22 Local noon date: 20220704 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 141 283 Nominal wavelengths inside fitting window [nm]: 305.0348 305.1762 305.3175 305.4588 305.6002 305.7415 305.8828 306.0240 306.1653 306.3066 306.4478 306.5891 306.7303 306.8715 307.0127 307.1539 307.2951 307.4362 307.5774 307.7185 307.8597 308.0008 308.1419 308.2830 308.4241 308.5652 308.7063 308.8473 308.9884 309.1294 309.2704 309.4114 309.5524 309.6934 309.8344 309.9753 310.1163 310.2572 310.3982 310.5391 310.6800 310.8209 310.9618 311.1027 311.2435 311.3844 311.5252 311.6661 311.8069 311.9477 312.0885 312.2293 312.3700 312.5108 312.6515 312.7923 312.9330 313.0737 313.2144 313.3551 313.4958 313.6365 313.7771 313.9178 314.0584 314.1991 314.3397 314.4803 314.6209 314.7615 314.9020 315.0426 315.1831 315.3237 315.4642 315.6047 315.7452 315.8857 316.0262 316.1667 316.3071 316.4476 316.5880 316.7284 316.8688 317.0092 317.1496 317.2900 317.4304 317.5707 317.7111 317.8514 317.9917 318.1321 318.2724 318.4126 318.5529 318.6932 318.8334 318.9737 319.1139 319.2541 319.3944 319.5346 319.6747 319.8149 319.9551 320.0952 320.2354 320.3755 320.5156 320.6557 320.7958 320.9359 321.0760 321.2161 321.3561 321.4962 321.6362 321.7762 321.9162 322.0562 322.1962 322.3362 322.4761 322.6161 322.7560 322.8959 323.0359 323.1758 323.3157 323.4555 323.5954 323.7353 323.8751 324.0150 324.1548 324.2946 324.4344 324.5742 324.7140 324.8538 324.9935 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220704T183041.0Z 8220.771308 276 1 49.40 2 6.98 191.27 62.50 94.50 0.00 1 0.00 1 0 17 1.571e-02 1.373e-02 2.398e-03 1.437e-03 1.326221e-01 7.202363e-04 1.486906e-03 -6.000000e+00 8.940992e-03 230.35 -2.00 3.24 -2.00 315.65 0.00e+00 7.915425e-04 7.361132e-05 2.454706e-04 -6.000000e+00 4.139160e-04 293.64 -2.00 20.00 -2.00 314.80 0.00e+00 1.007 0.000 302.00 328.00 3 4.9386e+00 1.8705e-03 1.1756e-02 -6.0000e+00 2.2267e-02 3.1824e-02 2.0901e-03 6.0618e-03 -6.0000e+00 2.4149e-02 -7.3741e-03 1.1916e-03 2.9128e-03 -6.0000e+00 1.4453e-02 -9.5087e-03 5.3381e-04 7.9089e-04 -6.0000e+00 6.1156e-03 1.2734e-03 -2.2846e-04 4.0074e-05 1.0565e-05 -6.0000e+00 4.1509e-04 2.1518e-04 -1.3152e-05 12 8 8 10 0 0 11.97 17.58 0.15 0.00022 -0.00150 25 6 1 5 0 1975.850 20.77 14.97 17.58 38.94 11.4 1040.58 1393 1115 741 -1300 -2065 -2616 -1394 -1313 -306 -2199 -2581 -2445 -684 -311 944 695 1115 1900 1210 2078 1409 1097 1354 839 566 784 -351 -1343 -2048 -1993 -718 -1408 -541 -3325 -5031 -4580 -3167 -2058 -203 136 377 889 898 888 1045 663 -33 130 -1226 -523 382 440 801 1490 975 1337 1046 236 96 -1 1224 1977 2897 2605 557 -881 -1174 -1548 79 793 207 1067 537 752 -649 -2034 -3248 -3966 -3229 -2935 -2066 -1646 -2211 -1105 88 488 1068 1547 2022 1179 164 -790 -2303 -2217 -1970 -1058 -102 1184 737 92 -221 -1606 -1881 -1211 -1112 -984 164 157 1130 1817 2418 2211 1720 134 -977 -1716 -1551 -821 159 895 1180 1308 1514 421 350 -1125 -1717 -1287 -1363 -1397 -580 -1081 -937 -364 576 582 1282 1576 1094 227 -197 -1008 -1435 378 328 220 -373 -535 -632 -337 -354 -90 -680 -789 -733 -214 -108 355 280 457 781 512 905 628 485 593 381 270 384 -171 -627 -900 -838 -305 -628 -253 -1612 -2350 -2036 -1475 -1093 -123 93 275 663 681 685 800 505 -25 94 -875 -363 271 327 620 1184 792 1097 870 196 78 -1 1031 1743 2682 2494 533 -794 -975 -1247 67 731 203 1081 546 748 -620 -1810 -2674 -3112 -2597 -2585 -1953 -1662 -2335 -1189 99 580 1321 1957 2536 1451 193 -862 -2351 -2206 -2025 -1163 -118 1467 948 116 -265 -1847 -2140 -1429 -1389 -1280 220 215 1575 2612 3572 3239 2446 181 -1245 -2106 -1913 -1047 215 1252 1695 1852 2098 570 456 -1444 -2126 -1600 -1778 -1879 -797 -1499 -1315 -523 860 898 1992 2491 1746 357 -306 -1543 -2193 SS 20220704T184308.7Z 8220.779962 285 1 49.36 2 7.99 212.06 59.89 96.18 0.00 1 0.00 1 0 17 1.679e-02 1.454e-02 3.119e-03 1.846e-03 1.320954e-01 9.256786e-04 1.473899e-03 -6.000000e+00 9.558841e-03 230.35 -2.00 3.24 -2.00 315.70 0.00e+00 7.662120e-04 9.546966e-05 2.617488e-04 -6.000000e+00 4.424928e-04 293.64 -2.00 20.00 -2.00 314.84 0.00e+00 1.010 0.000 302.00 328.00 3 5.3524e+00 2.4056e-03 1.1737e-02 -6.0000e+00 2.3806e-02 3.7857e-02 2.6898e-03 5.9861e-03 -6.0000e+00 2.5816e-02 -4.6935e-03 1.5337e-03 2.8712e-03 -6.0000e+00 1.5451e-02 -1.0415e-02 6.8728e-04 7.7976e-04 -6.0000e+00 6.5386e-03 8.3876e-04 2.7993e-04 5.1563e-05 1.0467e-05 -6.0000e+00 4.4368e-04 1.1876e-03 5.8814e-05 12 8 8 10 0 0 99.24 17.58 0.23 0.00119 0.00329 17 4 1 5 0 2902.850 20.77 15.01 17.58 39.32 11.4 1042.87 608 1043 357 -1444 -3413 -2956 -2764 -645 -809 -2352 -2484 -1655 -1033 -1546 1348 399 1335 2221 1757 2167 1687 1151 1761 887 -441 942 -616 -960 -2375 -982 -1483 -1075 -340 -3624 -5118 -4476 -3048 -2046 443 427 550 766 1059 767 865 1108 -213 238 -1263 -34 -209 974 690 1609 1318 1105 736 376 1 456 1268 2459 2714 2354 962 -740 -1236 -2036 185 413 514 1357 503 774 -1019 -2110 -3531 -4372 -3497 -3181 -2497 -2229 -2088 -1234 29 451 1109 1680 2382 962 206 -551 -2730 -2648 -1834 -1354 -72 1268 636 47 -122 -1745 -2035 -1215 -879 -967 173 68 1295 1794 2458 2229 1547 472 -1094 -1754 -1891 -878 521 1202 1112 1669 1487 470 270 -1189 -1730 -1420 -1440 -1291 -671 -867 -850 -548 778 596 1456 1526 905 252 -321 -1137 -1551 163 300 104 -404 -874 -696 -665 -170 -235 -717 -743 -486 -320 -533 498 159 537 902 733 923 735 501 765 398 -210 455 -299 -442 -1040 -405 -619 -473 -157 -1741 -2353 -1973 -1410 -1077 267 287 397 573 804 586 657 838 -160 171 -887 -23 -148 722 533 1273 1063 906 612 311 1 373 1060 2151 2519 2269 919 -667 -1028 -1645 155 382 508 1369 511 771 -973 -1870 -2899 -3443 -2798 -2776 -2365 -2248 -2195 -1343 33 538 1379 2133 2989 1186 242 -598 -2789 -2629 -1881 -1485 -84 1569 822 60 -148 -2009 -2312 -1425 -1099 -1266 231 94 1813 2606 3633 3290 2201 634 -1393 -2158 -2348 -1120 699 1699 1603 2380 2074 637 354 -1520 -2125 -1755 -1875 -1746 -921 -1196 -1187 -791 1157 921 2270 2425 1451 399 -498 -1733 -2381 SS 20220704T184753.5Z 8220.783259 288 1 49.07 2 8.59 218.43 58.89 96.84 0.00 1 0.00 1 0 17 1.603e-02 1.409e-02 2.124e-03 1.249e-03 1.329553e-01 6.266107e-04 1.507103e-03 -6.000000e+00 9.122847e-03 230.35 -2.00 3.24 -2.00 315.73 0.00e+00 8.365407e-04 6.498257e-05 2.845732e-04 -6.000000e+00 4.222963e-04 293.64 -2.00 20.00 -2.00 314.87 0.00e+00 1.011 0.000 302.00 328.00 3 4.5574e+00 1.6295e-03 1.1777e-02 -6.0000e+00 2.2720e-02 3.3466e-02 1.8212e-03 6.0356e-03 -6.0000e+00 2.4638e-02 -7.5192e-03 1.0382e-03 2.8966e-03 -6.0000e+00 1.4746e-02 -9.0917e-03 4.6610e-04 7.8693e-04 -6.0000e+00 6.2407e-03 1.8547e-03 3.2031e-04 3.4944e-05 1.0765e-05 -6.0000e+00 4.2340e-04 9.3304e-04 7.0633e-05 12 9 9 12 1 1 99.99 17.58 0.12 0.00093 0.00334 47 11 1 5 0 1022.000 20.77 15.00 17.58 39.68 11.4 1045.22 1311 425 1223 -1592 -2777 -2403 -2376 -927 -1160 -1635 -3388 -1571 -1589 -280 1006 1048 736 1612 1554 2026 1162 876 1711 1199 270 613 -321 -979 -1659 -1600 -894 -835 -656 -2638 -5040 -4035 -3636 -1757 -335 343 259 746 1024 840 1148 820 -274 -326 -1195 -627 422 548 1126 1276 972 1231 569 238 190 333 1401 1935 2645 2707 836 -843 -1215 -1954 190 893 828 968 728 704 -641 -2054 -3392 -4341 -3443 -3203 -2341 -2017 -2232 -1220 177 495 1139 1623 1964 1016 181 -860 -2243 -2291 -2028 -1304 52 1291 684 96 -280 -1581 -2093 -1054 -1169 -1116 76 259 1225 2008 2396 2097 1594 279 -957 -1650 -1532 -907 506 1088 1178 1381 1681 494 198 -1239 -1826 -1357 -1406 -1300 -960 -1143 -966 -437 524 608 1455 1322 1085 391 -146 -1050 -1460 351 121 356 -445 -696 -563 -566 -243 -338 -495 -1015 -454 -488 -95 373 415 299 655 645 859 506 378 727 528 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