File name: Pandora63s1_LaPorteTX_20220915_L2Fit_fout2c14d20220908p1-8.txt File generation date: 20250514T182740.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 63 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora63_OF_v2d20210219.txt Instrument calibration file used: Pandora63s1_CF_v14d20220908.txt Level 1 file used: Pandora63s1_LaPorteTX_20220915_L1_smca1c14d20220908p1-8.txt Full location name: University Of Houston Trailer Short location name: LaPorteTX Country of location: United States Location latitude [deg]: 29.6721 Location longitude [deg]: -95.0647 Location altitude [m]: 22 Local noon date: 20220915 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 141 283 Nominal wavelengths inside fitting window [nm]: 305.0311 305.1725 305.3138 305.4552 305.5965 305.7378 305.8791 306.0204 306.1617 306.3029 306.4442 306.5854 306.7266 306.8679 307.0091 307.1503 307.2914 307.4326 307.5738 307.7149 307.8561 307.9972 308.1383 308.2794 308.4205 308.5616 308.7027 308.8437 308.9848 309.1258 309.2668 309.4079 309.5489 309.6899 309.8308 309.9718 310.1128 310.2537 310.3946 310.5356 310.6765 310.8174 310.9583 311.0992 311.2400 311.3809 311.5217 311.6626 311.8034 311.9442 312.0850 312.2258 312.3666 312.5073 312.6481 312.7888 312.9296 313.0703 313.2110 313.3517 313.4924 313.6331 313.7737 313.9144 314.0550 314.1957 314.3363 314.4769 314.6175 314.7581 314.8987 315.0392 315.1798 315.3203 315.4608 315.6014 315.7419 315.8824 316.0229 316.1633 316.3038 316.4442 316.5847 316.7251 316.8655 317.0059 317.1463 317.2867 317.4271 317.5674 317.7078 317.8481 317.9885 318.1288 318.2691 318.4094 318.5497 318.6899 318.8302 318.9704 319.1107 319.2509 319.3911 319.5313 319.6715 319.8117 319.9519 320.0920 320.2322 320.3723 320.5124 320.6525 320.7927 320.9327 321.0728 321.2129 321.3529 321.4930 321.6330 321.7730 321.9131 322.0531 322.1931 322.3330 322.4730 322.6130 322.7529 322.8928 323.0327 323.1727 323.3126 323.4524 323.5923 323.7322 323.8720 324.0119 324.1517 324.2915 324.4313 324.5711 324.7109 324.8507 324.9905 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220915T124710.0Z 8293.532754 223 1 48.55 2 81.68 91.39 35.75 263.43 0.00 1 0.00 1 0 33 3.462e-01 2.865e-02 2.117e-01 1.144e-02 5.877587e-01 5.963189e-03 7.425352e-03 -6.000000e+00 1.957144e-01 228.50 -2.00 3.24 -2.00 321.84 0.00e+00 2.965315e-03 3.214584e-03 1.415872e-02 -6.000000e+00 9.117926e-03 293.55 -2.00 20.00 -2.00 321.16 0.00e+00 6.485 0.003 302.00 328.00 3 1.6363e+00 2.3699e-02 1.0935e-01 -6.0000e+00 4.8526e-01 4.0777e-01 3.0042e-02 1.1428e-01 -6.0000e+00 5.2699e-01 -8.4289e-01 2.0448e-02 3.0024e-02 -6.0000e+00 3.1587e-01 3.6469e-01 9.8795e-03 1.0650e-02 -6.0000e+00 1.3419e-01 1.0721e-04 5.6755e-04 3.3715e-04 1.2141e-04 -6.0000e+00 9.1431e-03 1.0052e-03 -7.0975e-05 12 8 8 10 0 0 -14.43 17.28 0.19 0.00101 0.00527 40 9 1 5 0 1213.690 20.56 14.98 17.28 29.85 12.9 981.51 -83885 -29839 -92731 7656 -114090 22498 -56303 -92377 30647 -36522 191734 -119336 9913 -79761 112053 -10757 18379 23017 8819 -22924 -4525 50846 -13937 17695 -31111 54192 -25132 21953 -44714 1943 23367 21094 41079 -6109 29980 -34580 25764 -4172 98379 15011 38925 25181 37683 40532 30143 48343 561 47916 4570 29436 17400 30470 35461 19397 33353 21932 21767 5648 31309 1426 29368 4619 19980 16707 27421 13376 15045 12044 3317 17456 502 8807 5238 3042 -5672 6085 -11568 -7293 -1882 -6519 -2046 -1515 5357 -5633 4204 -1351 3005 -2167 4333 -190 -2365 -2578 -9793 -4561 -7330 -3473 -4601 -415 -2862 -3470 -3476 -6264 -6615 -3842 -764 -2296 1667 -58 2777 3629 3079 2458 -12 -1070 -3567 -1753 -2918 -480 1024 2817 2476 4647 2954 1505 928 -654 -1141 -857 -611 -1978 185 -1059 -507 -392 804 687 1950 1937 135 -249 -270 -1479 -2848 -3711 -898 -4901 159 -5941 326 -1651 -3970 473 -1051 2139 -7276 226 -4725 1449 -455 648 812 363 -1260 -208 1424 -680 681 -1893 1608 -1445 801 -2792 82 918 966 1757 -399 1387 -2686 1258 -303 3413 1227 2802 2145 2960 3104 2546 3474 61 3486 503 2698 1919 3250 3888 2605 4137 3084 3112 933 4007 231 3855 821 3433 3278 5096 2698 2928 2476 815 4274 156 2659 1609 899 -1666 1451 -3068 -1887 -521 -2199 -770 -642 2307 -2876 2084 -759 1710 -1334 2485 -110 -1330 -1355 -5325 -2467 -4621 -2451 -3798 -374 -2803 -3457 -3202 -5332 -5452 -3222 -677 -2199 1627 -62 3196 4568 4284 3592 -18 -1564 -5054 -2371 -4103 -702 1583 4453 3896 6906 4425 2227 1337 -919 -1574 -1267 -1028 -3719 369 -2240 -1124 -930 2022 1810 5186 5228 369 -652 -664 -3554 -6917 SS 20220915T130055.8Z 8293.542313 228 1 48.86 2 78.70 93.12 38.65 265.52 0.00 1 0.00 1 0 25 2.891e-01 1.715e-02 5.865e-02 2.845e-03 4.921642e-01 1.476377e-03 6.886300e-03 -6.000000e+00 1.634680e-01 228.50 -2.00 3.24 -2.00 321.24 0.00e+00 3.885142e-03 7.298449e-04 9.467793e-03 -6.000000e+00 7.614919e-03 293.55 -2.00 20.00 -2.00 320.49 0.00e+00 4.924 0.001 302.00 328.00 3 1.1603e+00 5.3509e-03 7.4031e-02 -6.0000e+00 4.0531e-01 -3.1537e-02 7.0474e-03 7.1820e-02 -6.0000e+00 4.4013e-01 -1.3695e-01 5.9021e-03 2.2612e-02 -6.0000e+00 2.6381e-01 5.9915e-02 2.8303e-03 5.0324e-03 -6.0000e+00 1.1209e-01 8.3187e-04 7.2928e-04 8.4534e-05 9.6295e-05 -6.0000e+00 7.6349e-03 4.9413e-04 -3.9648e-05 12 8 8 10 0 0 -22.03 17.28 0.11 0.00049 0.00597 144 32 1 5 0 339.220 20.56 15.01 17.28 30.57 12.8 985.14 -107657 -82493 -63579 -77132 -92676 -102961 -111379 -88781 -97374 -86435 -93544 -90117 -64828 -34732 -36927 -29153 4481 -20583 -5607 -16616 -17635 -7427 7162 -18590 -27 -4840 -9223 -15521 -15704 -16531 -5592 12555 2078 650 -1251 -9880 -10552 -1900 5487 10531 10545 9499 8897 7000 11492 4437 8416 1901 2166 5409 7575 6084 7573 6508 5198 6544 4116 3367 796 1759 4676 4706 6820 8843 4259 330 339 -1127 990 1588 3734 1986 1219 250 -2131 -3984 -5937 -6106 -4852 -3944 -2786 -1700 -3133 -1827 -206 565 1902 2041 2525 2036 453 -2709 -3655 -4251 -2933 -2382 -570 910 -181 -1312 -2244 -3264 -2829 -1488 -1221 -273 401 1286 2218 2700 2951 2242 1267 -439 -1820 -2304 -1387 -650 661 1004 1682 2007 2226 463 -312 -2191 -2803 -1404 -1293 -1215 -1034 -1296 -929 -530 435 613 1477 1816 937 2 -313 -1316 -1082 -1942 -1351 -917 -1241 -1594 -1857 -2287 -1651 -2014 -1871 -2232 -2046 -1511 -752 -913 -780 104 -607 -153 -532 -587 -223 209 -680 -1 -175 -349 -607 -602 -663 -229 504 105 35 -67 -561 -655 -129 425 914 1021 914 901 741 1290 500 1006 226 263 729 1000 905 1208 1124 954 1232 814 669 159 377 1016 1129 1656 2321 1207 102 100 -343 328 603 1522 858 525 104 -832 -1425 -2008 -2079 -1817 -1722 -1394 -947 -1917 -1171 -139 407 1435 1582 1938 1512 319 -1819 -2350 -2832 -2154 -1999 -537 955 -206 -1490 -2376 -3148 -2582 -1404 -1249 -294 452 1529 2859 3835 4530 3570 1995 -664 -2612 -3206 -1954 -966 1041 1647 2734 3150 3380 693 -453 -3096 -3866 -2024 -2094 -2181 -1982 -2590 -1934 -1172 1021 1501 3671 4574 2373 5 -731 -2954 -2420 SS 20220915T130724.5Z 8293.546811 231 1 49.01 2 77.29 93.94 40.02 266.44 0.00 1 0.00 1 0 25 2.089e-01 1.653e-02 3.571e-02 1.881e-03 4.543244e-01 9.581480e-04 6.035276e-03 -6.000000e+00 1.181015e-01 228.50 -2.00 3.24 -2.00 320.90 0.00e+00 1.432875e-03 4.233436e-04 7.089800e-03 -6.000000e+00 5.501544e-03 293.55 -2.00 20.00 -2.00 320.10 0.00e+00 4.420 0.001 302.00 328.00 3 1.0012e+00 3.2627e-03 6.1638e-02 -6.0000e+00 2.9282e-01 -6.4233e-02 4.1835e-03 5.5648e-02 -6.0000e+00 3.1798e-01 -6.9877e-02 3.4400e-03 1.6463e-02 -6.0000e+00 1.9060e-01 2.9470e-02 1.6942e-03 5.4418e-03 -6.0000e+00 8.0986e-02 1.6324e-03 7.1058e-04 5.5619e-05 6.0972e-05 -6.0000e+00 5.5160e-03 3.2295e-04 -4.2605e-05 12 8 8 10 0 0 -11.27 17.28 0.08 0.00032 0.00566 216 48 1 5 0 226.850 20.56 15.00 17.28 30.86 12.8 986.68 -40131 -65700 -45603 -89427 -64160 -88702 -74436 -67729 -64979 -56641 -67582 -41163 -57410 -21611 -28355 -4174 -30302 4928 -11353 1641 -5531 -9767 625 -8167 640 -5914 -2017 -11222 -9838 -13525 -3282 -2728 -4200 1925 -10652 -7689 -11194 11 1681 7242 6201 6729 8295 5850 6191 6086 5601 3095 2929 -521 4738 3597 4460 4076 3644 4831 2090 1704 -516 1381 1911 4748 4538 6331 2706 -135 -1233 -1698 1003 1310 2084 1426 678 -816 -1163 -4251 -4977 -6501 -4761 -3003 -2968 -1373 -3059 -1447 -567 1247 1557 2351 2040 1615 324 -1608 -3268 -3748 -2138 -2082 43 849 430 -1201 -1759 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