File name: Pandora63s1_LaPorteTX_20220916_L2Fit_fout2c14d20220908p1-8.txt File generation date: 20250514T182604.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 63 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora63_OF_v2d20210219.txt Instrument calibration file used: Pandora63s1_CF_v14d20220908.txt Level 1 file used: Pandora63s1_LaPorteTX_20220916_L1_smca1c14d20220908p1-8.txt Full location name: University Of Houston Trailer Short location name: LaPorteTX Country of location: United States Location latitude [deg]: 29.6721 Location longitude [deg]: -95.0647 Location altitude [m]: 22 Local noon date: 20220916 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 141 283 Nominal wavelengths inside fitting window [nm]: 305.0311 305.1725 305.3138 305.4552 305.5965 305.7378 305.8791 306.0204 306.1617 306.3029 306.4442 306.5854 306.7266 306.8679 307.0091 307.1503 307.2914 307.4326 307.5738 307.7149 307.8561 307.9972 308.1383 308.2794 308.4205 308.5616 308.7027 308.8437 308.9848 309.1258 309.2668 309.4079 309.5489 309.6899 309.8308 309.9718 310.1128 310.2537 310.3946 310.5356 310.6765 310.8174 310.9583 311.0992 311.2400 311.3809 311.5217 311.6626 311.8034 311.9442 312.0850 312.2258 312.3666 312.5073 312.6481 312.7888 312.9296 313.0703 313.2110 313.3517 313.4924 313.6331 313.7737 313.9144 314.0550 314.1957 314.3363 314.4769 314.6175 314.7581 314.8987 315.0392 315.1798 315.3203 315.4608 315.6014 315.7419 315.8824 316.0229 316.1633 316.3038 316.4442 316.5847 316.7251 316.8655 317.0059 317.1463 317.2867 317.4271 317.5674 317.7078 317.8481 317.9885 318.1288 318.2691 318.4094 318.5497 318.6899 318.8302 318.9704 319.1107 319.2509 319.3911 319.5313 319.6715 319.8117 319.9519 320.0920 320.2322 320.3723 320.5124 320.6525 320.7927 320.9327 321.0728 321.2129 321.3529 321.4930 321.6330 321.7730 321.9131 322.0531 322.1931 322.3330 322.4730 322.6130 322.7529 322.8928 323.0327 323.1727 323.3126 323.4524 323.5923 323.7322 323.8720 324.0119 324.1517 324.2915 324.4313 324.5711 324.7109 324.8507 324.9905 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220916T131418.9Z 8294.551607 246 1 48.91 2 75.91 95.22 29.92 266.41 0.00 1 0.00 1 0 25 1.376e-01 1.555e-02 3.447e-02 1.973e-03 4.124775e-01 9.976572e-04 5.444400e-03 -6.000000e+00 7.782789e-02 228.45 -2.00 3.24 -2.00 320.58 0.00e+00 2.241519e-03 3.965487e-04 5.465468e-03 -6.000000e+00 3.623688e-03 293.48 -2.00 20.00 -2.00 319.74 0.00e+00 4.016 0.001 302.00 328.00 3 1.3808e+00 3.2284e-03 5.1964e-02 -6.0000e+00 1.9295e-01 -6.1648e-02 4.0501e-03 4.1881e-02 -6.0000e+00 2.0950e-01 -7.9382e-03 3.2469e-03 1.4110e-02 -6.0000e+00 1.2558e-01 -5.2818e-04 1.6313e-03 3.4475e-03 -6.0000e+00 5.3390e-02 1.6683e-03 1.0637e-03 5.8446e-05 5.2937e-05 -6.0000e+00 3.6326e-03 -1.3609e-03 5.3414e-05 12 8 8 10 0 0 99.78 17.32 0.06 -0.00136 0.00663 246 55 1 5 0 198.800 20.56 15.02 17.32 32.05 12.9 993.84 -64269 -27268 -63426 -2755 -64077 -3683 -55139 -23924 -43164 -36226 -30419 -44120 -13674 -33576 8234 -10413 14095 -6142 127 159 3979 -927 -10396 3711 -7215 4465 -7896 4725 -14272 -1152 -8750 -1995 -948 -5320 -2214 -11882 -2942 -4857 4085 -101 5288 3695 4300 1486 2928 4811 678 4539 -1298 3072 845 4231 1305 4982 1251 3358 1136 -236 1003 408 3030 2972 5474 4134 2348 -948 -1007 -2408 -621 1304 244 1167 410 892 -2343 -2704 -5590 -5438 -4584 -3166 -2195 -2210 -2227 -1957 828 504 2040 1598 2752 1265 660 -992 -3082 -2837 -2735 -874 -73 1550 -73 -795 -1822 -2459 -2355 -1027 -777 -971 614 697 2226 2498 2955 2022 1338 -422 -1706 -1758 -1744 -506 332 967 1257 1959 1495 375 -536 -1936 -2653 -1736 -1583 -1591 -817 -1435 -731 -496 454 635 1579 1762 933 342 -296 -903 -1095 -1326 -468 -1569 -41 -1454 -49 -1163 -440 -1031 -879 -714 -1217 -339 -1176 238 -396 477 -263 5 7 180 -44 -547 185 -419 247 -489 258 -895 -66 -584 -141 -75 -460 -179 -1033 -254 -502 473 -14 781 593 715 260 512 837 123 812 -249 585 178 948 326 1279 348 950 337 -71 292 121 909 978 1928 1610 951 -382 -383 -932 -261 617 128 632 222 460 -1174 -1222 -2430 -2330 -2131 -1656 -1306 -1471 -1597 -1479 653 429 1810 1465 2482 1115 554 -776 -2306 -2146 -2274 -810 -75 1748 -89 -964 -2100 -2580 -2399 -1083 -873 -1157 758 908 3085 3711 4684 3302 2136 -641 -2486 -2458 -2482 -754 526 1603 2086 3138 2374 581 -804 -2803 -3799 -2578 -2557 -2774 -1500 -2734 -1435 -1013 982 1434 3557 4032 2148 780 -646 -1924 -2331 SS 20220916T132459.3Z 8294.559019 249 1 2.36 2 73.61 96.61 32.18 267.91 0.00 1 0.00 1 0 25 8.898e-02 1.711e-02 6.222e-02 7.702e-03 3.563634e-01 3.815756e-03 4.284139e-03 -6.000000e+00 5.030297e-02 228.45 -2.00 3.24 -2.00 319.07 0.00e+00 2.173573e-03 9.488142e-04 2.314073e-03 -6.000000e+00 2.342828e-03 293.48 -2.00 20.00 -2.00 318.13 0.00e+00 3.485 0.000 302.00 328.00 3 2.2857e+00 1.0731e-02 3.9401e-02 -6.0000e+00 1.2471e-01 -4.7988e-02 1.2533e-02 2.0857e-02 -6.0000e+00 1.3543e-01 -5.7722e-03 8.6265e-03 9.1131e-03 -6.0000e+00 8.1175e-02 5.5557e-04 4.5224e-03 2.1934e-03 -6.0000e+00 3.4498e-02 1.1828e-03 2.8399e-04 2.1729e-04 2.6791e-05 -6.0000e+00 2.3496e-03 -9.0111e-04 -5.7817e-05 12 9 9 12 1 1 999.00 17.33 0.13 -0.00090 0.00123 2 15 1 5 0 727.850 20.56 15.00 17.33 32.50 12.8 995.74 -44905 30034 -20543 -21138 -46543 11835 -36587 -6340 -24931 -23086 -11243 -21683 -15614 -13720 6579 -1650 6784 508 -3417 1383 -4886 553 -137 1474 6656 7385 -10135 1018 -2045 -1103 -7571 -1552 -6750 -4055 -518 -10654 -252 -4306 8480 -2417 4531 -153 3075 3165 3063 3152 2086 -1004 -288 4876 -1923 2357 750 4355 468 782 71 -329 2100 -1882 3197 3083 2825 1975 1560 1303 -737 -1206 559 1890 721 1983 -1521 991 -2124 -1753 -6262 -5565 -3478 -4407 -1523 -2279 -1415 -1099 394 873 3139 1143 2709 1414 -393 -306 -2529 -3538 -2599 -1113 84 271 -164 -648 -1235 -1831 -3341 -870 40 -1830 1788 1137 2288 1439 2935 2472 1377 -93 -567 -1738 -2096 -257 955 1142 1142 1696 1455 921 -690 -2006 -2311 -1313 -1256 -1856 -1009 -810 -983 129 515 384 1538 1577 1006 683 -647 -819 -1373 -2091 827 -916 -924 -2355 344 -1681 -252 -1301 -1255 -562 -1242 -961 -984 461 -140 576 48 -356 144 -555 60 -15 172 793 916 -1478 130 -259 -139 -1094 -240 -1206 -735 -88 -1935 -45 -930 1950 -702 1362 -51 1022 1072 1049 1097 732 -361 -103 1719 -762 971 334 1969 226 389 36 -169 1044 -963 1625 1679 1677 1256 1010 804 -441 -721 355 1316 544 1530 -1202 750 -1554 -1183 -4109 -3560 -2327 -3306 -1238 -2006 -1302 -1052 392 910 3372 1269 2979 1533 -409 -300 -2410 -3393 -2631 -1211 99 342 -215 -850 -1545 -2167 -3884 -1031 50 -2396 2368 1563 3255 2170 4577 3896 2148 -140 -819 -2461 -3008 -378 1466 1811 1820 2658 2246 1396 -1028 -2920 -3303 -1909 -1930 -3029 -1692 -1378 -1714 231 957 736 2969 3073 1971 1319 -1222 -1514 -2543 SS 20220916T134317.8Z 8294.571734 259 1 48.78 2 69.67 99.06 36.07 270.26 0.00 1 0.00 1 0 25 3.370e-02 1.436e-02 9.257e-03 1.140e-03 3.063445e-01 5.616820e-04 3.708514e-03 -6.000000e+00 1.906774e-02 228.45 -2.00 3.24 -2.00 319.42 0.00e+00 1.030364e-03 1.511817e-04 2.321085e-03 -6.000000e+00 8.875955e-04 293.48 -2.00 20.00 -2.00 318.47 0.00e+00 2.848 0.000 302.00 328.00 3 1.6892e+00 1.6149e-03 3.3241e-02 -6.0000e+00 4.7274e-02 -3.5416e-02 1.9017e-03 2.0255e-02 -6.0000e+00 5.1319e-02 1.8597e-02 1.3175e-03 8.0163e-03 -6.0000e+00 3.0762e-02 -1.5768e-02 6.8844e-04 2.0560e-03 -6.0000e+00 1.3084e-02 4.1617e-03 1.1780e-03 3.3469e-05 2.0424e-05 -6.0000e+00 8.8956e-04 -2.7247e-03 1.1647e-04 12 8 8 10 0 0 99.99 17.32 0.08 -0.00272 0.00613 399 89 1 5 0 122.230 20.56 15.01 17.32 33.27 12.9 1000.82 -5176 -3455 -4772 -7649 -12826 -18117 -8580 -8724 -4195 -6484 -9530 -9435 -7737 -1585 -75 1560 -533 1230 2256 860 284 -230 1065 313 53 -1091 -1198 -2382 -3131 -4315 -3272 -2262 -1702 -4194 -7203 -5902 -5710 -2801 671 1008 628 1428 1755 1363 2103 1231 691 -194 -1155 -605 518 1100 1330 2174 1135 1577 666 139 -95 439 1307 2854 3499 3644 1322 -680 -989 -1827 174 912 870 1090 563 427 -993 -2709 -3847 -4775 -3814 -3001 -2186 -1614 -2178 -1208 105 777 1449 1835 2322 1321 211 -793 -2435 -2326 -1895 -1292 187 1344 491 -450 -1019 -2079 -2013 -1014 -861 -800 418 607 1799 2198 2627 2056 1360 -188 -1215 -1916 -1423 -854 584 863 1158 1575 1580 268 -219 -1861 -2363 -1507 -1480 -1436 -953 -1252 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