File name: Pandora63s1_LaPorteTX_20220927_L2Fit_fout2c14d20220908p1-8.txt File generation date: 20250514T183621.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 63 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora63_OF_v2d20210219.txt Instrument calibration file used: Pandora63s1_CF_v14d20220908.txt Level 1 file used: Pandora63s1_LaPorteTX_20220927_L1_smca1c14d20220908p1-8.txt Full location name: University Of Houston Trailer Short location name: LaPorteTX Country of location: United States Location latitude [deg]: 29.6721 Location longitude [deg]: -95.0647 Location altitude [m]: 22 Local noon date: 20220927 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 141 283 Nominal wavelengths inside fitting window [nm]: 305.0311 305.1725 305.3138 305.4552 305.5965 305.7378 305.8791 306.0204 306.1617 306.3029 306.4442 306.5854 306.7266 306.8679 307.0091 307.1503 307.2914 307.4326 307.5738 307.7149 307.8561 307.9972 308.1383 308.2794 308.4205 308.5616 308.7027 308.8437 308.9848 309.1258 309.2668 309.4079 309.5489 309.6899 309.8308 309.9718 310.1128 310.2537 310.3946 310.5356 310.6765 310.8174 310.9583 311.0992 311.2400 311.3809 311.5217 311.6626 311.8034 311.9442 312.0850 312.2258 312.3666 312.5073 312.6481 312.7888 312.9296 313.0703 313.2110 313.3517 313.4924 313.6331 313.7737 313.9144 314.0550 314.1957 314.3363 314.4769 314.6175 314.7581 314.8987 315.0392 315.1798 315.3203 315.4608 315.6014 315.7419 315.8824 316.0229 316.1633 316.3038 316.4442 316.5847 316.7251 316.8655 317.0059 317.1463 317.2867 317.4271 317.5674 317.7078 317.8481 317.9885 318.1288 318.2691 318.4094 318.5497 318.6899 318.8302 318.9704 319.1107 319.2509 319.3911 319.5313 319.6715 319.8117 319.9519 320.0920 320.2322 320.3723 320.5124 320.6525 320.7927 320.9327 321.0728 321.2129 321.3529 321.4930 321.6330 321.7730 321.9131 322.0531 322.1931 322.3330 322.4730 322.6130 322.7529 322.8928 323.0327 323.1727 323.3126 323.4524 323.5923 323.7322 323.8720 324.0119 324.1517 324.2915 324.4313 324.5711 324.7109 324.8507 324.9905 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220927T124057.1Z 8305.528439 44 1 49.99 2 84.43 95.21 104.71 91.13 0.00 1 0.00 1 0 33 2.875e-01 4.426e-02 3.019e-01 4.260e-02 6.985179e-01 2.204737e-02 7.205108e-03 -6.000000e+00 1.621710e-01 227.89 -2.00 3.24 -2.00 321.66 0.00e+00 -2.249317e-03 7.936899e-03 7.754507e-03 -6.000000e+00 7.543782e-03 292.67 -2.00 20.00 -2.00 320.84 0.00e+00 9.031 0.009 302.00 328.00 3 6.3856e-01 7.5181e-02 1.0763e-01 -6.0000e+00 4.0163e-01 1.3711e+00 8.8667e-02 7.3116e-02 -6.0000e+00 4.3644e-01 -1.7490e+00 4.6140e-02 1.8239e-02 -6.0000e+00 2.6158e-01 6.5693e-01 2.5577e-02 1.1316e-02 -6.0000e+00 1.1116e-01 1.9984e-05 1.0385e-03 1.1854e-03 4.4086e-05 -6.0000e+00 7.5923e-03 1.3302e-03 -6.5295e-05 12 8 8 10 0 0 68.78 17.20 0.37 0.00133 0.00913 18 4 1 5 0 2776.660 20.46 15.00 17.20 25.23 12.8 954.39 22227 12917 48166 2844 97406 -22903 -18568 -56819 60946 -17929 77771 70457 7247 128871 69739 41715 16035 30624 45531 -2333 15360 -1408 -12893 3655 1977 88815 44748 -49852 -4951 -55557 80747 -5785 4480 6355 -2972 6602 -42628 -21754 14637 27626 10852 -29337 57968 33968 12511 -5445 23930 78578 -27955 -44994 44523 8110 -8213 9652 28672 -5508 11053 9276 50732 13360 -445 -27856 -6734 26698 -6216 15718 -29839 -165 22463 6129 31880 11210 -2613 4094 3843 884 -3993 -13684 -13877 8976 -3490 11866 -5312 -2419 14609 17606 8467 8694 839 8499 -11697 -1302 -18741 -568 -8823 1594 2799 2249 1794 -7571 -2646 -11530 -2044 -8335 2369 -5268 3002 3571 5503 6353 6581 8121 2375 -1797 -838 1957 -9036 2823 244 -187 -566 7098 -2195 1527 1040 -3785 -5245 1972 -1743 -1124 -2869 -241 -2008 -1646 -469 1060 1738 2012 988 2382 -3282 781 -924 2974 1933 4925 377 4595 -2781 -2109 -9406 3605 -2083 3684 3594 716 5354 4861 4043 1977 3295 4264 -320 1701 -169 -1633 414 234 4714 3286 -7673 -469 -8116 3806 -666 503 695 -328 623 -6442 -3054 1737 3258 1590 -6215 5619 3951 1689 -848 2798 5568 -5175 -10055 4781 1311 -1604 1683 4411 -1173 2029 1667 5958 2076 -79 -6798 -1511 4785 -1531 3083 -8588 -38 4562 1634 7210 3124 -807 1112 934 200 -883 -3421 -3875 2413 -1194 4016 -2279 -1067 5782 7181 3971 4143 426 3883 -5990 -574 -9602 -259 -4918 938 1890 1745 1511 -6936 -2124 -9031 -1395 -6316 1755 -4478 2496 3195 5431 7092 8008 10268 3188 -2473 -1090 2421 -12873 3809 362 -288 -859 9763 -3224 2116 1409 -5186 -7206 2758 -2939 -2144 -6092 -529 -4781 -4137 -1254 2919 4857 5796 2846 6448 -8766 1884 -2267 SS 20220927T125431.0Z 8305.537859 47 1 48.96 2 81.50 96.94 101.89 92.78 0.00 1 0.00 1 0 25 3.459e-01 2.122e-02 1.091e-01 5.651e-03 5.937939e-01 2.972481e-03 8.148740e-03 -6.000000e+00 1.951158e-01 227.89 -2.00 3.24 -2.00 321.88 0.00e+00 7.032629e-03 1.743805e-03 1.491704e-02 -6.000000e+00 9.075684e-03 292.67 -2.00 20.00 -2.00 321.25 0.00e+00 6.365 0.003 302.00 328.00 3 6.6430e-01 1.2304e-02 1.0888e-01 -6.0000e+00 4.8322e-01 2.5658e-01 1.6205e-02 1.1358e-01 -6.0000e+00 5.2508e-01 -5.7532e-01 1.2596e-02 3.5710e-02 -6.0000e+00 3.1471e-01 2.4955e-01 5.9048e-03 6.2117e-03 -6.0000e+00 1.3375e-01 3.1050e-04 1.9204e-04 1.6489e-04 1.8041e-04 -6.0000e+00 9.1337e-03 4.6961e-04 -7.0122e-05 12 8 8 10 0 0 37.50 17.19 0.13 0.00047 0.00191 99 22 1 5 0 494.500 20.46 15.00 17.19 26.12 12.8 959.98 -84374 -81003 -84075 -112385 -105617 -125563 -147196 -61204 -133285 -98747 -100503 -83865 -91465 -42990 -9410 -37677 -22366 -35955 -11315 -21364 13512 -38252 -6001 -51050 -28868 -12095 5427 -14061 -28144 -12768 -31610 10236 32473 -1753 -11907 10939 4776 -128 15789 6464 18001 13167 28358 20005 33842 15248 25086 19608 13844 18165 16662 21722 11138 28138 10980 18052 17524 9765 5459 9629 10097 9203 19682 13296 14886 6243 6763 2627 7612 8171 8053 7670 3037 3278 -2319 -1488 -7614 -8527 -6398 -2293 -2906 -755 -3009 -1915 -59 1629 2796 1267 2410 -10 -215 -3979 -5055 -6042 -3271 -3310 -1348 68 -1529 -2048 -3873 -4493 -5060 -1943 -1884 -2090 87 1195 2599 2703 3384 2132 838 -796 -2150 -3373 -1406 -519 834 1196 2108 3039 3000 1428 707 -1439 -2065 -739 -1578 -560 -813 -1117 -647 -331 386 388 1781 1411 857 14 -313 -1571 -1894 -1480 -1583 -1769 -2984 -2328 -3083 -4499 -944 -4140 -2226 -2316 -1941 -2520 -1019 -197 -1114 -628 -1243 -323 -696 343 -1437 -179 -2251 -1070 -388 159 -480 -987 -443 -1394 389 1127 -82 -585 452 203 -7 854 447 1227 1003 1932 1513 2255 1245 1885 1591 1228 1629 1661 2285 1299 3228 1432 2263 2245 1336 757 1380 1497 1399 3064 2461 2830 1253 1304 542 1668 2049 2215 2198 897 911 -622 -388 -1972 -2277 -1894 -712 -1062 -307 -1361 -910 -30 857 1541 730 1366 -6 -123 -2203 -2720 -3436 -2053 -2424 -1029 58 -1444 -1933 -3755 -3928 -4188 -1623 -1711 -2024 87 1276 3034 3547 4850 3232 1276 -1177 -3043 -4691 -1967 -766 1302 1935 3349 4612 4418 2079 1002 -1998 -2818 -1067 -2625 -1037 -1637 -2369 -1437 -784 976 1026 4746 3832 2328 37 -774 -3712 -4473 SS 20220927T130729.1Z 8305.546865 52 1 48.88 2 78.71 98.61 99.20 94.36 0.00 1 0.00 1 0 25 2.778e-01 1.722e-02 3.904e-02 1.958e-03 4.997351e-01 1.005280e-03 7.140691e-03 -6.000000e+00 1.566852e-01 227.89 -2.00 3.24 -2.00 321.14 0.00e+00 3.002249e-03 4.873175e-04 9.535528e-03 -6.000000e+00 7.287670e-03 292.67 -2.00 20.00 -2.00 320.39 0.00e+00 4.931 0.001 302.00 328.00 3 4.8148e-01 3.5635e-03 7.4263e-02 -6.0000e+00 3.8804e-01 -6.9618e-03 4.6743e-03 7.2103e-02 -6.0000e+00 4.2164e-01 -1.4398e-01 3.9354e-03 2.1821e-02 -6.0000e+00 2.5272e-01 6.2476e-02 1.8942e-03 5.6746e-03 -6.0000e+00 1.0742e-01 1.5919e-03 5.4694e-04 5.6990e-05 1.0071e-04 -6.0000e+00 7.3336e-03 -1.2396e-04 -5.7378e-05 12 8 8 10 0 0 46.26 17.18 0.08 -0.00012 0.00399 249 55 1 5 0 196.290 20.46 14.98 17.18 27.14 12.8 965.21 -82533 -88403 -88378 -96881 -92695 -103411 -91180 -97100 -66149 -86707 -70388 -71681 -66740 -50328 -38216 -25961 -17569 -2360 -14587 -7751 -14198 1449 -10478 -19229 -10292 -16980 -10724 -21428 -12010 -25218 -4681 -8591 1407 -3775 -6614 -7981 -7875 1889 6289 9125 7484 11973 9641 7412 8081 10150 7902 6285 4970 2046 7613 6815 8480 8127 6902 5629 4872 2737 1334 2385 4147 5543 6739 6915 3558 1539 38 -629 742 2238 2041 1972 1232 222 -1525 -4268 -5907 -7694 -5487 -3424 -2534 -2297 -2872 -1648 121 896 1672 1859 2302 1634 -56 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