File name: Pandora63s1_LaPorteTX_20240127_L2Fit_fwvt1c9d20230718p1-8.txt File generation date: 20250505T115918.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c9p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 63 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora63_OF_v2d20210219.txt Instrument calibration file used: Pandora63s1_CF_v9d20230718.txt Level 1 file used: Pandora63s1_LaPorteTX_20240127_L1_smca1c9d20230718p1-8.txt Full location name: University Of Houston Trailer Short location name: LaPorteTX Country of location: United States Location latitude [deg]: 29.6721 Location longitude [deg]: -95.0647 Location altitude [m]: 22 Local noon date: 20240127 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1555 1703 Nominal wavelengths inside fitting window [nm]: 492.0951 492.2170 492.3389 492.4607 492.5826 492.7045 492.8263 492.9481 493.0699 493.1917 493.3135 493.4352 493.5569 493.6787 493.8004 493.9220 494.0437 494.1654 494.2870 494.4086 494.5302 494.6518 494.7734 494.8949 495.0165 495.1380 495.2595 495.3810 495.5024 495.6239 495.7453 495.8667 495.9881 496.1095 496.2309 496.3522 496.4736 496.5949 496.7162 496.8375 496.9587 497.0800 497.2012 497.3225 497.4437 497.5648 497.6860 497.8072 497.9283 498.0494 498.1705 498.2916 498.4127 498.5337 498.6548 498.7758 498.8968 499.0178 499.1387 499.2597 499.3806 499.5015 499.6224 499.7433 499.8642 499.9850 500.1059 500.2267 500.3475 500.4683 500.5890 500.7098 500.8305 500.9512 501.0719 501.1926 501.3133 501.4339 501.5546 501.6752 501.7958 501.9164 502.0369 502.1575 502.2780 502.3985 502.5190 502.6395 502.7600 502.8804 503.0009 503.1213 503.2417 503.3620 503.4824 503.6028 503.7231 503.8434 503.9637 504.0840 504.2042 504.3245 504.4447 504.5649 504.6851 504.8053 504.9255 505.0456 505.1657 505.2858 505.4059 505.5260 505.6461 505.7661 505.8861 506.0061 506.1261 506.2461 506.3661 506.4860 506.6059 506.7258 506.8457 506.9656 507.0854 507.2053 507.3251 507.4449 507.5647 507.6845 507.8042 507.9239 508.0437 508.1634 508.2831 508.4027 508.5224 508.6420 508.7616 508.8812 509.0008 509.1204 509.2399 509.3595 509.4790 509.5985 509.7179 509.8374 509.9568 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-249: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 250-398: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240127T132923.1Z 8792.562073 255 1 21.54 2 87.49 112.98 76.91 280.79 0.00 1 0.00 1 0 22 6.940e-03 6.883e-03 2.644e-04 2.636e-04 1.346070e+04 1.879831e+01 8.919353e+02 -6.000000e+00 3.999405e+02 284.92 -2.00 20.00 -2.00 505.41 0.00e+00 4.407447e-03 7.484405e-06 2.413274e-04 -6.000000e+00 1.987727e-04 284.92 -2.00 20.00 -2.00 501.03 0.00e+00 1.061684e+00 5.146706e-03 9.518763e-02 -6.000000e+00 1.386097e-01 224.67 -2.00 3.24 -2.00 502.53 0.00e+00 14.699 0.038 489.00 513.00 1 2.4778e+00 3.9496e-04 2.3894e-02 -6.0000e+00 1.0662e-02 -4.3406e-02 9.8188e-05 2.5111e-03 -6.0000e+00 2.7324e-03 1.7233e-02 7.8837e-04 2.4785e-05 1.2123e-04 -6.0000e+00 7.0947e-04 7.4987e-04 -2.7745e-06 12 9 9 12 1 1 99.22 21.88 1.28 0.00075 0.00622 156 80 1 4 0 137.130 21.88 15.00 18.01 19.19 24.2 990.73 -1500 -1006 -321 43 231 862 1026 933 841 92 6 -282 -503 -527 -941 -650 -271 373 524 224 411 588 768 1142 868 576 541 159 -466 -1176 -884 -924 12 501 91 -151 -106 -93 -242 -26 60 310 560 789 805 791 485 117 -177 -775 -1249 -1495 -1413 -682 -154 13 233 283 540 616 989 801 788 617 198 -12 -209 -201 -317 -678 -592 -556 -133 79 -481 -954 -1074 -846 -832 -824 -733 -742 -612 -345 -365 -358 -55 -20 299 430 788 1129 1141 764 455 174 -220 -341 -1274 -1595 -1458 -976 -190 -316 -719 -745 -843 -607 -123 18 227 505 836 1056 1283 1507 1309 924 499 282 192 544 841 722 412 405 81 163 399 -18 -520 -620 -973 -812 -403 -252 -204 193 410 444 519 456 427 490 262 -205 -872 -1093 -896 -1356 -901 -296 40 217 824 996 887 797 89 5 -267 -473 -492 -879 -611 -259 354 508 218 401 575 755 1129 864 559 538 156 -450 -1111 -830 -881 12 491 91 -151 -105 -92 -238 -26 59 311 568 789 810 797 485 116 -178 -765 -1211 -1435 -1358 -669 -151 13 237 289 550 629 1015 828 796 621 203 -13 -209 -200 -312 -664 -578 -548 -133 79 -483 -947 -1048 -841 -825 -817 -730 -724 -602 -343 -366 -359 -55 -20 296 427 791 1145 1153 757 450 167 -208 -327 -1215 -1520 -1375 -955 -189 -316 -729 -753 -847 -608 -124 18 231 517 858 1086 1329 1582 1357 960 527 293 196 554 861 746 429 422 85 170 418 -18 -536 -634 -998 -840 -414 -264 -217 207 435 476 560 494 463 530 282 -218 -917 -1172 -943 SQ 20240127T133248.8Z 8792.564454 258 1 49.04 2 86.80 113.42 77.62 281.16 0.00 1 0.00 1 0 29 6.127e-03 6.079e-03 5.018e-04 5.006e-04 1.169861e+04 3.533674e+01 7.713497e+02 -6.000000e+00 3.531241e+02 284.92 -2.00 20.00 -2.00 505.40 0.00e+00 3.628608e-03 1.417868e-05 2.003533e-04 -6.000000e+00 1.754509e-04 284.92 -2.00 20.00 -2.00 500.95 0.00e+00 1.012037e+00 9.774783e-03 8.495475e-02 -6.000000e+00 1.223443e-01 224.67 -2.00 3.24 -2.00 502.47 0.00e+00 13.073 0.027 489.00 513.00 1 4.6705e+00 7.5055e-04 2.0962e-02 -6.0000e+00 9.4104e-03 -3.1779e-02 1.8671e-04 2.2229e-03 -6.0000e+00 2.4111e-03 2.4657e-03 1.1124e-04 4.7531e-05 1.0252e-04 -6.0000e+00 6.2683e-04 -2.5326e-03 3.9224e-05 12 8 8 10 0 0 100.00 21.79 0.90 -0.00253 -0.00176 225 50 1 4 0 217.920 21.79 14.99 18.00 19.31 24.1 991.09 -1360 -809 -323 9 113 755 943 790 716 147 -5 -170 -392 -439 -768 -593 -248 207 538 153 400 572 682 1011 734 571 329 168 -523 -1006 -770 -1013 100 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-497 -129 51 316 429 759 960 1177 1338 1205 846 430 345 265 431 820 709 298 331 -8 79 377 -71 -470 -575 -767 -709 -324 -296 -166 183 336 479 494 451 444 420 273 -174 -820 -994 -847 SQ 20240127T151647.5Z 8792.636660 310 1 0.93 2 67.46 129.15 98.75 293.20 0.00 1 0.00 1 0 15 4.210e-03 4.195e-03 1.439e-03 1.437e-03 1.485123e+03 8.572329e+01 9.318337e+01 -6.000000e+00 2.426394e+02 284.92 -2.00 20.00 -2.00 505.26 0.00e+00 7.329559e-04 4.036670e-05 3.914145e-05 -6.000000e+00 1.205580e-04 284.92 -2.00 20.00 -2.00 500.54 0.00e+00 5.892282e-02 2.837730e-02 1.474534e-02 -6.000000e+00 8.419221e-02 224.67 -2.00 3.24 -2.00 502.11 0.00e+00 2.587 0.000 489.00 513.00 1 4.3203e+00 2.1823e-03 4.0076e-03 -6.0000e+00 6.4735e-03 1.1995e-02 5.5829e-04 3.5876e-04 -6.0000e+00 1.6620e-03 1.7741e-02 2.1055e-03 1.4264e-04 1.5601e-05 -6.0000e+00 4.3057e-04 -2.5340e-02 6.6094e-05 12 9 1 12 1 1 69.67 21.79 0.12 -0.02534 -0.01074 3 47 1 4 0 232.340 21.79 15.00 17.93 20.20 23.3 993.38 -600 -589 -57 89 168 368 557 767 657 44 -37 -329 -414 -224 -417 -174 -200 -52 246 -7 351 320 625 648 591 352 226 237 -126 -630 -132 -684 135 355 -257 -446 -341 -135 40 -47 -101 242 332 297 552 226 383 211 91 -111 -812 -744 -967 -400 -217 -155 -108 -272 367 270 643 402 706 346 -140 94 -185 103 276 -405 -210 -443 -162 34 -144 -976 -566 -204 -345 -336 -546 -764 -588 -254 -481 13 -165 -4 -56 -15 283 853 402 162 336 -226 -140 -206 -619 -541 -746 -629 116 -173 -779 -192 -485 -445 79 115 195 299 369 666 814 849 780 883 374 658 158 445 353 251 387 380 -48 296 293 137 -281 -351 -490 -482 -210 -473 -269 93 115 328 292 364 306 108 -140 -82 -334 -482 -505 -580 -582 -56 90 170 379 582 784 671 46 -38 -333 -414 -227 -421 -176 -201 -54 253 -7 362 330 645 671 613 364 233 241 -128 -623 -133 -679 137 363 -268 -464 -352 -137 41 -48 -102 245 340 307 572 234 392 212 92 -110 -808 -727 -945 -398 -217 -155 -110 -275 369 271 648 407 713 349 -140 94 -184 101 274 -401 -207 -430 -159 34 -142 -956 -556 -199 -335 -327 -538 -740 -573 -250 -478 13 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