File name: Pandora63s1_LaPorteTX_20240324_L2Fit_fout2c7d20230718p1-8.txt File generation date: 20240325T062907.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 63 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora63_OF_v2d20210219.txt Instrument calibration file used: Pandora63s1_CF_v7d20230718.txt Level 1 file used: Pandora63s1_LaPorteTX_20240324_L1_smca1c7d20230718p1-8.txt Full location name: University Of Houston Trailer Short location name: LaPorteTX Country of location: United States Location latitude [deg]: 29.6721 Location longitude [deg]: -95.0647 Location altitude [m]: 22 Local noon date: 20240324 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Redoing OoB session using Lorentzian slit function due to bad straylight First and last pixel inside fitting window: 142 283 Nominal wavelengths inside fitting window [nm]: 305.1336 305.2750 305.4165 305.5579 305.6993 305.8407 305.9821 306.1235 306.2648 306.4062 306.5475 306.6888 306.8302 306.9715 307.1128 307.2541 307.3953 307.5366 307.6778 307.8191 307.9603 308.1015 308.2427 308.3839 308.5251 308.6663 308.8075 308.9486 309.0898 309.2309 309.3720 309.5131 309.6542 309.7953 309.9364 310.0774 310.2185 310.3595 310.5005 310.6415 310.7825 310.9235 311.0645 311.2055 311.3465 311.4874 311.6283 311.7693 311.9102 312.0511 312.1920 312.3328 312.4737 312.6146 312.7554 312.8963 313.0371 313.1779 313.3187 313.4595 313.6003 313.7410 313.8818 314.0225 314.1632 314.3040 314.4447 314.5854 314.7261 314.8667 315.0074 315.1481 315.2887 315.4293 315.5699 315.7105 315.8511 315.9917 316.1323 316.2729 316.4134 316.5539 316.6945 316.8350 316.9755 317.1160 317.2565 317.3969 317.5374 317.6778 317.8183 317.9587 318.0991 318.2395 318.3799 318.5203 318.6606 318.8010 318.9413 319.0816 319.2220 319.3623 319.5026 319.6429 319.7831 319.9234 320.0636 320.2039 320.3441 320.4843 320.6245 320.7647 320.9049 321.0451 321.1852 321.3254 321.4655 321.6056 321.7457 321.8858 322.0259 322.1660 322.3061 322.4461 322.5861 322.7262 322.8662 323.0062 323.1462 323.2862 323.4262 323.5661 323.7061 323.8460 323.9859 324.1258 324.2657 324.4056 324.5455 324.6854 324.8252 324.9651 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240324T142313.5Z 8849.599462 278 1 8.18 2 63.95 103.83 119.41 291.98 0.00 1 0.00 1 0 25 2.763e-02 1.299e-02 1.957e-02 5.650e-03 2.630443e-01 2.878912e-03 2.873359e-03 -6.000000e+00 1.611509e-02 227.84 -2.00 3.24 -2.00 317.55 0.00e+00 1.155488e-03 4.593500e-04 6.134435e-04 -6.000000e+00 7.365705e-04 286.60 -2.00 20.00 -2.00 316.72 0.00e+00 2.264 0.000 302.00 328.00 3 4.9184e+00 7.6530e-03 2.5655e-02 -6.0000e+00 4.0001e-02 -2.0432e-02 8.6494e-03 1.2329e-02 -6.0000e+00 4.3413e-02 1.6724e-02 5.2464e-03 6.0344e-03 -6.0000e+00 2.5909e-02 -1.8199e-02 2.5948e-03 1.7443e-03 -6.0000e+00 1.0969e-02 3.0375e-04 1.0921e-03 1.6377e-04 1.5613e-05 -6.0000e+00 7.6186e-04 -1.0406e-02 0.0000e+00 12 9 9 12 1 1 999.00 21.88 0.95 -0.01041 -0.00220 2 4 1 5 0 2726.290 21.88 15.00 18.03 25.20 25.6 1019.53 14337 4652 7837 -4150 -5281 2954 -11810 -7135 -2417 -1496 785 -388 -4754 2957 5415 1218 4716 2838 -1902 5336 4788 -989 5529 692 -831 -762 -2852 -1456 -3972 -1931 -1769 -645 -2095 -3011 -6482 -4872 -3399 -2253 1148 -1007 1186 -576 1246 1236 1456 -780 766 645 -1492 -733 251 2213 -709 681 328 931 -661 -845 1023 1191 2251 2049 2886 -192 -115 -319 236 745 1569 220 589 487 972 -338 -2113 -2952 -2229 -2051 -3316 -2717 -1893 -2923 -1892 -701 624 2723 1877 2162 1601 1040 92 -1845 -942 -1350 833 -777 604 354 -147 -694 -1427 -1198 -923 -57 -1995 -26 -311 610 1750 2977 1697 1006 189 -587 -501 -800 476 212 829 335 -184 906 483 371 -659 -1933 -1856 -826 -1612 -1474 -809 -1157 0 492 1023 324 640 1132 550 410 -458 -745 1247 467 759 -415 -492 252 -1292 -848 -295 -184 94 -51 -756 471 945 238 920 594 -431 1180 1066 -232 1261 177 -227 -209 -772 -369 -998 -484 -485 -190 -669 -937 -1992 -1535 -1217 -900 520 -517 598 -306 664 659 782 -424 427 354 -833 -421 145 1337 -464 455 225 652 -472 -595 701 832 1657 1553 2319 -164 -93 -236 176 578 1304 192 537 447 862 -304 -1752 -2358 -1663 -1567 -2727 -2499 -1810 -3042 -1936 -756 713 3091 2225 2547 1853 1190 98 -1902 -927 -1413 894 -933 749 453 -189 -882 -1747 -1390 -1104 -70 -2647 -35 -422 861 2508 4444 2610 1505 279 -800 -674 -1076 660 301 1251 498 -284 1337 693 533 -919 -2561 -2470 -1172 -2384 -2285 -1270 -1775 -1 827 1731 565 1134 2013 967 696 -785 -1261 SS 20240324T142807.2Z 8849.602861 281 1 19.35 2 62.92 104.56 120.38 292.77 0.00 1 0.00 1 0 25 1.897e-02 1.184e-02 1.791e-03 6.690e-04 2.517100e-01 3.411760e-04 2.753157e-03 -6.000000e+00 1.105669e-02 227.84 -2.00 3.24 -2.00 317.10 0.00e+00 1.468542e-03 4.811857e-05 4.891380e-04 -6.000000e+00 5.055321e-04 286.60 -2.00 20.00 -2.00 316.28 0.00e+00 2.185 0.000 302.00 328.00 3 2.1064e+00 8.9717e-04 2.4660e-02 -6.0000e+00 2.7445e-02 -2.1745e-02 1.0110e-03 1.1649e-02 -6.0000e+00 2.9790e-02 -6.6729e-03 5.9501e-04 5.6956e-03 -6.0000e+00 1.7778e-02 -6.1668e-03 2.8589e-04 1.7112e-03 -6.0000e+00 7.5251e-03 5.6032e-03 9.2629e-04 1.9300e-05 1.5077e-05 -6.0000e+00 5.2299e-04 -8.2671e-03 0.0000e+00 12 9 9 12 1 1 99.21 21.88 0.14 -0.00827 -0.00131 126 72 1 5 0 152.300 21.88 15.00 18.05 25.38 25.5 1020.18 -369 -970 -1415 -3450 -4128 -6234 -4226 -4573 -3113 -4743 -5124 -3270 -1693 197 657 1668 1993 3086 1773 3792 1916 1999 1592 455 -92 -977 -1989 -2140 -2231 -2348 -1420 -2254 -1951 -5079 -4742 -4258 -2049 -267 -228 -35 255 1348 1317 1297 1768 861 867 280 244 605 1258 1084 1530 943 1110 947 681 227 1053 1695 2334 2506 2037 1412 -359 -217 -719 368 1259 136 168 -214 -193 -495 -1736 -2605 -3681 -3465 -2509 -2787 -2211 -2151 -1837 -358 321 1113 1004 1025 1238 594 75 -1360 -1564 -955 -541 -275 26 427 -253 -585 -1384 -1239 -478 -369 -949 -89 300 1042 1885 2115 1759 1278 494 -316 -687 -349 -314 230 887 827 830 884 595 83 -387 -2118 -1337 -1034 -777 -978 -1210 -1036 -131 396 833 812 1026 988 352 -57 -912 -1058 -50 -138 -201 -456 -506 -772 -564 -694 -499 -781 -840 -573 -335 41 151 404 496 798 478 1049 540 559 461 142 -30 -325 -644 -658 -662 -709 -464 -802 -739 -1911 -1694 -1576 -788 -121 -112 -19 147 797 795 783 1070 521 513 164 141 362 805 690 1018 652 782 686 496 163 746 1220 1777 1940 1692 1212 -295 -174 -555 293 1065 127 155 -199 -175 -452 -1455 -2119 -2844 -2738 -2208 -2591 -2126 -2225 -1980 -383 367 1273 1190 1210 1426 681 84 -1397 -1550 -995 -618 -326 32 563 -336 -733 -1678 -1428 -566 -450 -1233 -120 399 1441 2772 3112 2638 1859 710 -442 -911 -460 -432 320 1313 1256 1245 1283 837 118 -532 -2776 -1747 -1449 -1117 -1477 -1865 -1622 -204 649 1368 1365 1755 1706 601 -94 -1530 -1751 SS 20240324T143246.8Z 8849.606097 284 1 14.71 2 61.94 105.27 121.29 293.54 0.00 1 0.00 1 0 25 1.823e-02 1.178e-02 1.855e-03 7.233e-04 2.438805e-01 3.687191e-04 2.658851e-03 -6.000000e+00 1.062587e-02 227.84 -2.00 3.24 -2.00 316.97 0.00e+00 1.318127e-03 5.035069e-05 4.555459e-04 -6.000000e+00 4.858288e-04 286.60 -2.00 20.00 -2.00 316.15 0.00e+00 2.115 0.000 302.00 328.00 3 2.0399e+00 9.6762e-04 2.3866e-02 -6.0000e+00 2.6376e-02 -2.3471e-02 1.0887e-03 1.1255e-02 -6.0000e+00 2.8629e-02 -4.4493e-03 6.3927e-04 5.4914e-03 -6.0000e+00 1.7085e-02 -6.8644e-03 3.0586e-04 1.6224e-03 -6.0000e+00 7.2319e-03 6.4899e-03 9.5355e-04 2.0832e-05 1.4698e-05 -6.0000e+00 5.0261e-04 -8.3410e-03 0.0000e+00 12 9 9 12 1 1 99.85 21.88 0.14 -0.00834 -0.00118 112 85 1 5 0 127.840 21.88 15.00 18.06 25.57 25.6 1021.31 -349 -932 -835 -4353 -2990 -6018 -3544 -3277 -3786 -5002 -4681 -2745 -1713 547 615 1320 1725 2797 1657 3573 1854 2319 1555 452 62 -1159 -1381 -1913 -2066 -2320 -1384 -2272 -1599 -4846 -4732 -4032 -2610 -590 -361 73 396 1219 1414 1426 1495 814 919 238 428 543 1419 858 1577 1237 897 880 546 372 923 1626 2466 2300 1935 1280 -330 -348 -770 208 1285 -45 187 -354 -199 -581 -1803 -2445 -3389 -3437 -2371 -2770 -2116 -2105 -1788 -345 312 1082 1010 1153 1173 654 110 -1381 -1443 -822 -628 -544 121 568 -190 -721 -1494 -1229 -465 -288 -935 -129 246 1001 1789 2147 1760 1281 479 -248 -692 -309 -269 219 843 853 1010 935 655 41 -355 -2068 -1363 -1067 -749 -947 -1266 -977 -151 475 838 835 985 956 374 -101 -926 -1018 -47 -131 -127 -624 -388 -797 -504 -526 -655 -884 -817 -510 -331 119 149 338 454 764 471 1042 549 679 473 148 21 -406 -466 -614 -640 -730 -470 -839 -577 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