File name: Pandora63s1_LaPorteTX_20240520_L2Fit_fout2c9d20230718p1-8.txt File generation date: 20250505T120829.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 63 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora63_OF_v2d20210219.txt Instrument calibration file used: Pandora63s1_CF_v9d20230718.txt Level 1 file used: Pandora63s1_LaPorteTX_20240520_L1_smca1c9d20230718p1-8.txt Full location name: University Of Houston Trailer Short location name: LaPorteTX Country of location: United States Location latitude [deg]: 29.6721 Location longitude [deg]: -95.0647 Location altitude [m]: 22 Local noon date: 20240520 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 141 283 Nominal wavelengths inside fitting window [nm]: 305.0040 305.1453 305.2866 305.4279 305.5692 305.7105 305.8517 305.9930 306.1342 306.2754 306.4166 306.5578 306.6990 306.8402 306.9814 307.1225 307.2637 307.4048 307.5459 307.6870 307.8281 307.9692 308.1103 308.2514 308.3924 308.5335 308.6745 308.8156 308.9566 309.0976 309.2386 309.3795 309.5205 309.6615 309.8024 309.9434 310.0843 310.2252 310.3661 310.5070 310.6479 310.7888 310.9296 311.0705 311.2113 311.3521 311.4930 311.6338 311.7746 311.9154 312.0561 312.1969 312.3376 312.4784 312.6191 312.7598 312.9005 313.0412 313.1819 313.3226 313.4633 313.6039 313.7446 313.8852 314.0258 314.1664 314.3070 314.4476 314.5882 314.7287 314.8693 315.0098 315.1504 315.2909 315.4314 315.5719 315.7124 315.8529 315.9933 316.1338 316.2742 316.4147 316.5551 316.6955 316.8359 316.9763 317.1167 317.2570 317.3974 317.5377 317.6781 317.8184 317.9587 318.0990 318.2393 318.3796 318.5198 318.6601 318.8003 318.9406 319.0808 319.2210 319.3612 319.5014 319.6416 319.7817 319.9219 320.0621 320.2022 320.3423 320.4824 320.6225 320.7626 320.9027 321.0428 321.1828 321.3229 321.4629 321.6029 321.7429 321.8829 322.0229 322.1629 322.3029 322.4428 322.5828 322.7227 322.8626 323.0025 323.1424 323.2823 323.4222 323.5621 323.7019 323.8418 323.9816 324.1214 324.2613 324.4011 324.5408 324.6806 324.8204 324.9601 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240520T120646.6Z 8906.504705 160 1 48.90 2 82.27 71.18 124.16 277.33 0.00 1 0.00 1 0 25 3.324e-01 1.661e-02 2.370e-01 6.127e-03 7.058449e-01 3.809646e-03 1.211915e-02 -6.000000e+00 2.132671e-01 231.00 -2.00 3.24 -2.00 321.93 0.00e+00 1.051599e-02 2.520250e-03 2.409885e-02 -6.000000e+00 1.938988e-02 290.59 -2.00 20.00 -2.00 321.37 0.00e+00 6.911 0.004 302.00 328.00 3 1.9210e+00 1.6588e-02 1.5242e-01 -6.0000e+00 5.4948e-01 -1.8334e-01 2.7061e-02 1.7630e-01 -6.0000e+00 6.0666e-01 2.8906e-02 2.9429e-02 6.1287e-02 -6.0000e+00 3.5682e-01 5.8549e-04 1.2886e-02 6.6997e-03 -6.0000e+00 1.8416e-01 4.9377e-05 1.4907e-03 1.8581e-04 3.4696e-04 -6.0000e+00 1.0384e-02 1.6841e-03 0.0000e+00 12 8 8 10 0 0 94.48 20.67 0.56 0.00168 0.01289 43 10 1 5 0 1137.050 20.67 15.00 17.48 31.28 28.1 1031.03 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 -13166 900000 900000 900000 900000 165047 254345 1703 900000 -26484 900000 53563 40910 32059 74577 15147 26003 36254 -13670 48212 57787 15395 -24213 21123 12590 14789 1153 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636 326 -819 -1885 -2080 -1186 -1155 392 -1314 939 1202 3280 3263 4426 3731 2241 -1200 -1955 -1680 -1392 657 880 2526 800 954 2742 872 -481 -2766 -4782 -3566 -603 -2003 -553 -3534 -2606 -2150 -612 2263 2429 3453 1963 1047 -128 -1196 -1002 SS 20240520T122355.0Z 8906.516608 165 1 49.10 2 78.72 73.11 127.74 279.70 0.00 1 0.00 1 0 17 3.236e-01 1.586e-02 3.079e-02 1.528e-03 5.451093e-01 8.130836e-04 8.171226e-03 -6.000000e+00 1.903684e-01 231.00 -2.00 3.24 -2.00 320.76 0.00e+00 4.926559e-03 3.535644e-04 9.163831e-03 -6.000000e+00 8.737867e-03 290.59 -2.00 20.00 -2.00 320.04 0.00e+00 4.936 0.001 302.00 328.00 3 1.3655e+00 2.6772e-03 7.0876e-02 -6.0000e+00 4.7557e-01 -1.9308e-02 3.4271e-03 6.4131e-02 -6.0000e+00 5.1446e-01 -1.2964e-01 2.9043e-03 2.2678e-02 -6.0000e+00 3.0726e-01 5.7111e-02 1.4222e-03 3.9004e-03 -6.0000e+00 1.2910e-01 6.0478e-04 7.5684e-04 4.3150e-05 1.2709e-04 -6.0000e+00 8.8445e-03 1.1776e-03 0.0000e+00 12 8 8 10 0 0 94.15 20.67 0.17 0.00118 0.00686 197 44 1 5 0 249.230 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