File name: Pandora63s1_LaPorteTX_20240702_L2Fit_fout2c9d20230718p1-8.txt File generation date: 20250505T120736.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Tom Hanisco Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 63 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora63_OF_v2d20210219.txt Instrument calibration file used: Pandora63s1_CF_v9d20230718.txt Level 1 file used: Pandora63s1_LaPorteTX_20240702_L1_smca1c9d20230718p1-8.txt Full location name: University Of Houston Trailer Short location name: LaPorteTX Country of location: United States Location latitude [deg]: 29.6721 Location longitude [deg]: -95.0647 Location altitude [m]: 22 Local noon date: 20240702 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 141 283 Nominal wavelengths inside fitting window [nm]: 305.0040 305.1453 305.2866 305.4279 305.5692 305.7105 305.8517 305.9930 306.1342 306.2754 306.4166 306.5578 306.6990 306.8402 306.9814 307.1225 307.2637 307.4048 307.5459 307.6870 307.8281 307.9692 308.1103 308.2514 308.3924 308.5335 308.6745 308.8156 308.9566 309.0976 309.2386 309.3795 309.5205 309.6615 309.8024 309.9434 310.0843 310.2252 310.3661 310.5070 310.6479 310.7888 310.9296 311.0705 311.2113 311.3521 311.4930 311.6338 311.7746 311.9154 312.0561 312.1969 312.3376 312.4784 312.6191 312.7598 312.9005 313.0412 313.1819 313.3226 313.4633 313.6039 313.7446 313.8852 314.0258 314.1664 314.3070 314.4476 314.5882 314.7287 314.8693 315.0098 315.1504 315.2909 315.4314 315.5719 315.7124 315.8529 315.9933 316.1338 316.2742 316.4147 316.5551 316.6955 316.8359 316.9763 317.1167 317.2570 317.3974 317.5377 317.6781 317.8184 317.9587 318.0990 318.2393 318.3796 318.5198 318.6601 318.8003 318.9406 319.0808 319.2210 319.3612 319.5014 319.6416 319.7817 319.9219 320.0621 320.2022 320.3423 320.4824 320.6225 320.7626 320.9027 321.0428 321.1828 321.3229 321.4629 321.6029 321.7429 321.8829 322.0229 322.1629 322.3029 322.4428 322.5828 322.7227 322.8626 323.0025 323.1424 323.2823 323.4222 323.5621 323.7019 323.8418 323.9816 324.1214 324.2613 324.4011 324.5408 324.6806 324.8204 324.9601 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240702T122509.4Z 8949.517470 151 1 48.80 2 78.72 69.86 39.10 89.22 0.00 1 0.00 1 0 25 2.541e-01 1.399e-02 1.874e-01 3.296e-03 5.364189e-01 1.830477e-03 7.890064e-03 -6.000000e+00 1.575474e-01 230.39 -2.00 3.24 -2.00 320.92 0.00e+00 6.038280e-03 8.728326e-04 9.360310e-03 -6.000000e+00 8.867859e-03 293.57 -2.00 20.00 -2.00 320.17 0.00e+00 4.935 0.001 302.00 328.00 3 2.9065e+00 6.3503e-03 7.1863e-02 -6.0000e+00 3.9458e-01 -1.4567e-01 8.5359e-03 6.6039e-02 -6.0000e+00 4.3187e-01 7.1498e-02 8.0607e-03 2.3340e-02 -6.0000e+00 2.4540e-01 -3.4395e-02 3.9072e-03 3.9522e-03 -6.0000e+00 1.0744e-01 1.3278e-04 9.8592e-04 9.6477e-05 1.2455e-04 -6.0000e+00 7.5014e-03 3.4037e-03 0.0000e+00 12 9 8 11 8 0 -4.71 20.67 0.62 0.00340 0.01081 44 10 1 5 0 1108.970 20.67 15.00 17.62 36.00 29.7 1029.01 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 35937 900000 900000 81803 900000 56373 57561 7032 105697 26218 205681 12139 58675 57428 31977 30986 13672 -7429 -5270 1810 -16557 4945 16976 -6539 -9187 1529 -5550 11302 -393 290 9900 -5336 4437 4871 9648 -924 -4917 815 2717 1294 1264 5708 -1353 6028 1139 2672 1838 -3682 -926 117 693 4517 5631 1483 4485 -3288 -986 -657 -299 511 626 9 -1740 -965 -2729 -3547 -4689 -5365 -6618 -1281 -1668 -1092 -2318 -1858 -16 919 4850 1502 1416 1273 1225 -753 -1908 -2619 -853 19 -979 399 543 -542 -1654 -1883 -2039 -400 -273 -1203 598 947 2391 2205 2821 1690 1236 -45 -445 -1288 -770 -431 685 1178 890 1415 1093 768 -989 -1522 -3389 -2085 -1765 -1009 -1338 -1378 -1076 -722 447 575 1276 877 1209 303 42 -575 -262 900000 900000 900000 900000 900000 900000 900000 900000 900000 900000 115 900000 900000 262 900000 361 419 94 585 344 659 198 616 653 513 533 287 -193 -135 45 -569 166 584 -316 -450 66 -278 570 -27 24 840 -527 463 529 1026 -114 -592 105 356 182 178 866 -242 1084 227 548 395 -843 -204 25 156 1076 1497 459 1439 -1116 -315 -212 -106 208 279 4 -835 -441 -1185 -1408 -1754 -2014 -2758 -598 -905 -618 -1458 -1233 -11 681 3683 1219 1146 1006 913 -535 -1293 -1820 -649 17 -973 410 609 -620 -1791 -1979 -2009 -398 -296 -1290 664 1112 3013 3096 4010 2534 1847 -65 -652 -1827 -1100 -645 1009 1817 1375 2255 1688 1161 -1470 -2197 -4750 -3013 -2861 -1698 -2437 -2623 -1998 -1429 935 1266 2847 1882 2758 679 90 -1163 -522 SS 20240702T123114.6Z 8949.521697 154 1 48.87 2 77.48 70.52 37.80 89.90 0.00 1 0.00 1 0 25 1.387e-01 1.362e-02 8.032e-02 2.251e-03 4.953303e-01 1.176885e-03 6.682232e-03 -6.000000e+00 8.138786e-02 230.39 -2.00 3.24 -2.00 320.51 0.00e+00 3.777249e-03 4.818932e-04 6.433718e-03 -6.000000e+00 3.792847e-03 293.57 -2.00 20.00 -2.00 319.70 0.00e+00 4.481 0.001 302.00 328.00 3 2.6160e+00 3.7956e-03 5.8896e-02 -6.0000e+00 2.0280e-01 -9.4667e-02 4.8201e-03 4.7356e-02 -6.0000e+00 2.1941e-01 3.4472e-03 4.0942e-03 1.7264e-02 -6.0000e+00 1.3135e-01 -6.8558e-03 2.0475e-03 3.4579e-03 -6.0000e+00 5.5405e-02 2.8330e-04 7.6540e-04 6.3654e-05 8.2415e-05 -6.0000e+00 3.7875e-03 4.0708e-03 0.0000e+00 12 8 8 10 0 0 78.15 20.67 0.39 0.00407 0.00982 76 17 1 5 0 642.970 20.67 15.00 17.62 36.20 29.6 1029.87 1596 -38859 32494 -10258 -57396 -72537 -48819 -13069 -52042 -15748 -66337 -17167 -43391 -22018 2059 9736 -17010 -24361 -4089 346 7744 -6495 -5133 6092 -5013 -4887 -9658 -8689 -6787 -12409 -7683 -11089 145 -7297 -5376 -8074 -6355 -1387 -5 -241 3241 3554 3456 3169 4144 2553 -565 2391 1302 -918 2895 3880 3345 3153 1991 1690 805 -870 232 1478 1446 4333 4259 3578 2733 -503 22 -927 -682 1927 112 276 -514 -535 -2013 -3152 -4319 -4688 -4810 -2686 -2206 -1334 -2308 -1901 -76 616 2989 1318 1394 1822 829 -129 -2193 -2725 -1022 -1057 -384 423 52 -752 -1430 -2084 -1674 -715 -428 -817 115 832 2069 2827 2519 2004 1050 137 -556 -1178 -711 -385 382 955 1035 1232 1232 331 -619 -1196 -3083 -1621 -1426 -1249 -1273 -1540 -1233 -394 341 679 1156 1301 1132 512 165 -903 -500 8 -367 164 -81 -680 -955 -525 -112 -754 -173 -1267 -215 -848 -435 40 207 -534 -817 -135 12 255 -248 -197 223 -204 -211 -445 -431 -328 -651 -389 -688 9 -547 -387 -586 -486 -120 -1 -30 438 519 534 510 671 433 -100 422 239 -180 592 879 762 775 522 462 230 -255 66 415 420 1335 1468 1376 1122 -207 8 -368 -295 940 61 158 -296 -296 -1057 -1516 -1946 -2092 -2332 -1493 -1406 -880 -1683 -1461 -61 530 2674 1240 1304 1654 716 -105 -1705 -2151 -876 -1034 -422 481 64 -950 -1704 -2251 -1822 -793 -478 -970 142 1083 2878 4029 3909 3248 1697 213 -815 -1786 -1084 -574 602 1579 1716 1980 1910 504 -985 -1848 -4616 -2484 -2276 -2218 -2276 -2875 -2387 -807 742 1457 2523 2884 2527 1119 343 -1915 -1041 SS 20240702T123634.8Z 8949.525402 157 1 49.10 2 76.39 71.09 36.67 90.52 0.00 1 0.00 1 0 25 1.323e-01 1.353e-02 3.294e-02 1.735e-03 4.640019e-01 9.017505e-04 6.047708e-03 -6.000000e+00 7.763462e-02 230.39 -2.00 3.24 -2.00 320.17 0.00e+00 2.827223e-03 3.247985e-04 4.998169e-03 -6.000000e+00 3.617964e-03 293.57 -2.00 20.00 -2.00 319.32 0.00e+00 4.145 0.001 302.00 328.00 3 2.5279e+00 2.7757e-03 5.2061e-02 -6.0000e+00 1.9345e-01 -7.6930e-02 3.4186e-03 3.8284e-02 -6.0000e+00 2.0929e-01 -1.2251e-02 2.7413e-03 1.4586e-02 -6.0000e+00 1.2529e-01 -1.3489e-04 1.3959e-03 3.1116e-03 -6.0000e+00 5.2850e-02 4.3720e-04 6.3833e-04 4.9503e-05 6.0402e-05 -6.0000e+00 3.6128e-03 4.1056e-03 0.0000e+00 12 8 8 10 0 0 1.53 20.67 0.28 0.00411 0.00890 93 21 1 5 0 527.950 20.67 15.00 17.64 36.23 29.6 1030.14 -45106 -35371 -29751 -32744 -49980 -50107 -40716 -34172 -49362 -49066 -50947 -34812 -15063 -18083 -4441 -11706 -5765 -14684 4706 -433 188 -3015 -1337 1155 -2903 -4834 -7666 -7550 -10235 -9689 -12617 -4841 -1457 -4010 -3404 -10327 -5844 -3320 125 698 2068 2261 3162 2347 4482 3239 648 2082 604 886 774 3076 2507 3090 1793 2159 1503 518 862 1170 2318 4040 4483 3172 2946 -552 -569 -610 369 1639 458 1000 -616 -406 -1335 -3103 -4524 -5658 -4484 -3083 -2764 -1882 -1794 -1900 -63 295 2566 1228 1432 1461 743 -25 -2162 -2245 -1284 -715 -255 502 254 -723 -1476 -1748 -1665 -1040 -235 -1041 527 789 1971 2183 2686 1769 1397 235 -652 -973 -477 -374 459 782 1073 1113 1098 494 -401 -1182 -2934 -1649 -1391 -1178 -1299 -1524 -1020 -480 334 780 1119 1123 1214 345 42 -622 -554 -626 -527 -453 -521 -879 -839 -641 -572 -1102 -1187 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