File name: Pandora87s1_LapwaiID_20241127_L2Fit_fout2c2d20240715p1-8.txt File generation date: 20241202T212759.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 87 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora87_OF_v2d20240227.txt Instrument calibration file used: Pandora87s1_CF_v2d20240715.txt Level 1 file used: Pandora87s1_LapwaiID_20241127_L1_smca1c2d20240715p1-8.txt Full location name: Nez Perce Tribe cell tower site near Lapwai Idaho Short location name: LapwaiID Country of location: United States Location latitude [deg]: 46.3806 Location longitude [deg]: -116.8064 Location altitude [m]: 564 Local noon date: 20241127 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0760 305.2167 305.3574 305.4980 305.6386 305.7793 305.9199 306.0605 306.2011 306.3416 306.4822 306.6228 306.7633 306.9039 307.0444 307.1849 307.3254 307.4659 307.6064 307.7468 307.8873 308.0277 308.1682 308.3086 308.4490 308.5894 308.7298 308.8702 309.0105 309.1509 309.2912 309.4316 309.5719 309.7122 309.8525 309.9928 310.1331 310.2734 310.4136 310.5539 310.6941 310.8343 310.9745 311.1147 311.2549 311.3951 311.5353 311.6754 311.8156 311.9557 312.0958 312.2359 312.3760 312.5161 312.6562 312.7963 312.9363 313.0764 313.2164 313.3564 313.4965 313.6365 313.7764 313.9164 314.0564 314.1964 314.3363 314.4762 314.6162 314.7561 314.8960 315.0359 315.1757 315.3156 315.4555 315.5953 315.7351 315.8750 316.0148 316.1546 316.2944 316.4342 316.5739 316.7137 316.8534 316.9932 317.1329 317.2726 317.4123 317.5520 317.6917 317.8313 317.9710 318.1106 318.2503 318.3899 318.5295 318.6691 318.8087 318.9483 319.0878 319.2274 319.3669 319.5065 319.6460 319.7855 319.9250 320.0645 320.2040 320.3435 320.4829 320.6224 320.7618 320.9012 321.0406 321.1800 321.3194 321.4588 321.5982 321.7375 321.8769 322.0162 322.1555 322.2948 322.4341 322.5734 322.7127 322.8520 322.9912 323.1305 323.2697 323.4089 323.5481 323.6873 323.8265 323.9657 324.1048 324.2440 324.3831 324.5223 324.6614 324.8005 324.9396 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20241127T174810.6Z 9097.741790 1851 1 3.63 2 71.88 153.84 60.44 195.02 0.00 1 0.00 1 0 25 7.472e-02 9.629e-03 3.296e-02 4.889e-03 4.491613e-01 2.443902e-03 5.946487e-03 -6.000000e+00 4.150402e-02 221.68 -2.00 3.63 -2.00 318.38 0.00e+00 2.625462e-03 4.585179e-04 5.258779e-04 -6.000000e+00 1.775915e-03 271.40 -2.00 20.00 -2.00 317.90 0.00e+00 3.174 0.001 302.00 328.00 3 2.4935e+00 6.4686e-03 3.7957e-02 -6.0000e+00 1.0224e-01 3.0625e-02 7.3058e-03 2.4091e-02 -6.0000e+00 1.1114e-01 -4.2583e-02 5.2270e-03 1.2207e-02 -6.0000e+00 6.5995e-02 2.1129e-02 2.8667e-03 3.6368e-03 -6.0000e+00 2.9121e-02 1.2850e-03 -9.6716e-03 1.2782e-04 3.9957e-05 -6.0000e+00 1.9109e-03 -1.3240e-01 -3.8141e-04 12 9 9 12 5 1 58.18 24.50 0.26 -0.13240 -0.20508 3 6 1 5 0 907.200 33.00 20.00 24.50 12.83 0.0 895.51 900000 -27203 -11033 -25420 -30897 -22818 -31864 -31716 1608 -16365 -24457 -5719 -26723 -17501 -4245 -9109 3271 -1910 -1871 3116 -2558 -693 3417 -4113 7273 -3438 5984 -2537 -5249 -6946 -3067 6484 -6300 2671 1289 -2891 -4466 -2787 -1625 480 1957 1191 535 200 2826 1079 802 -426 931 1137 389 -93 1227 3166 2745 1482 184 1109 1609 -706 -253 996 818 2694 1748 1290 850 829 -1227 514 1834 -74 1435 -799 1078 689 -1771 -2550 -1967 -2408 -941 -726 -676 -2435 -2101 -1788 -1371 -178 -39 -49 595 491 759 -869 -35 -307 -983 -416 818 789 498 -426 -1409 -26 -215 -930 -1087 -683 -938 -508 931 549 881 -157 353 75 284 232 497 181 1001 444 376 692 650 598 1159 -663 1049 177 223 -255 -492 -545 -60 -506 -59 -230 250 449 -164 -617 -645 900000 -1193 -479 -1369 -1723 -1044 -1504 -1572 64 -874 -1539 -303 -1821 -1293 -338 -925 346 -213 -224 379 -346 -95 444 -585 990 -554 923 -439 -901 -1144 -489 1054 -1330 583 313 -700 -1037 -684 -416 146 651 453 218 86 1216 474 333 -180 389 481 169 -43 627 1710 1494 863 111 685 994 -435 -152 599 496 1785 1226 965 612 562 -837 359 1448 -63 1214 -698 939 561 -1406 -1840 -1428 -1720 -763 -643 -642 -2463 -2119 -1906 -1495 -203 -46 -56 694 535 794 -901 -34 -322 -1113 -486 1027 1055 681 -558 -1778 -31 -256 -1156 -1390 -907 -1268 -726 1370 857 1398 -252 559 111 403 335 709 275 1551 686 590 1049 992 867 1667 -924 1461 258 334 -401 -822 -907 -102 -893 -107 -430 474 838 -310 -1116 -1148 SU 20241127T174939.8Z 9097.742822 1854 1 3.01 2 71.77 154.18 60.51 195.42 0.00 1 0.00 1 0 25 6.846e-02 1.020e-02 3.215e-02 4.807e-03 4.468226e-01 2.403754e-03 5.910228e-03 -6.000000e+00 3.808113e-02 221.68 -2.00 3.63 -2.00 318.30 0.00e+00 1.527044e-03 4.434479e-04 7.749250e-04 -6.000000e+00 1.627015e-03 271.40 -2.00 20.00 -2.00 317.84 0.00e+00 3.156 0.001 302.00 328.00 3 2.3146e+00 6.3457e-03 3.7773e-02 -6.0000e+00 9.3824e-02 1.0752e-02 7.1748e-03 2.4128e-02 -6.0000e+00 1.0190e-01 -3.0545e-02 5.1087e-03 1.2124e-02 -6.0000e+00 6.0500e-02 1.6410e-02 2.7997e-03 3.6507e-03 -6.0000e+00 2.6809e-02 1.5850e-03 -7.7178e-03 1.2526e-04 3.8263e-05 -6.0000e+00 1.7492e-03 -1.7728e-01 -1.3744e-03 12 9 9 12 5 1 72.71 24.50 0.31 -0.17728 -0.23528 3 7 1 5 0 751.450 33.00 19.96 24.50 12.85 0.0 895.67 900000 -16621 1877 2554 -28893 -19006 -37185 -19035 -35722 -11719 -14206 -16794 -17311 -19609 954 -10184 -2751 -2728 4732 -5544 -6219 -1470 175 405 666 2195 -69 -3193 -3746 -6584 -4033 3795 65 3762 3035 -3225 -1682 -2200 2333 2444 -1162 -761 377 924 2085 1857 2406 164 -1631 -251 667 2681 1280 2352 2233 2482 2568 1384 82 -391 -740 478 873 2042 3297 272 -1328 554 -675 1500 1110 1723 103 -877 711 -1255 -1792 -1337 -2665 -2154 -1045 -1778 -1608 -2014 -2939 -116 -1551 69 216 1071 865 112 440 -228 -877 -358 -177 48 884 766 116 -306 -1434 -1433 -556 -986 -1834 -1109 -43 435 631 1087 1154 1324 298 -119 352 221 -67 850 505 13 601 624 693 1107 959 -96 -182 -186 -666 -556 -477 -74 -902 -586 109 -245 192 147 323 -315 -262 900000 -686 74 107 -1598 -846 -1900 -865 -2160 -632 -852 -1047 -1144 -1581 76 -1103 -294 -319 550 -763 -904 -210 24 58 102 354 -12 -588 -666 -1133 -684 668 13 853 691 -743 -396 -517 608 772 -424 -313 151 386 884 790 1032 72 -732 -112 303 1285 641 1256 1285 1411 1501 844 51 -237 -441 286 559 1354 2401 204 -966 395 -480 1094 880 1447 88 -767 619 -1039 -1414 -1003 -1932 -1619 -846 -1588 -1542 -2036 -3006 -123 -1711 80 247 1228 1014 124 465 -235 -878 -378 -201 56 1120 1036 160 -405 -1828 -1718 -670 -1240 -2392 -1439 -59 602 912 1653 1795 2130 464 -179 509 311 -97 1253 770 20 925 964 1037 1626 1353 -135 -250 -266 -1021 -891 -783 -125 -1534 -1022 195 -454 360 272 606 -581 -461 SU 20241127T175133.7Z 9097.744140 1857 1 41.40 2 71.63 154.62 60.60 195.93 0.00 1 0.00 1 0 25 5.409e-02 7.974e-03 4.066e-03 6.747e-04 4.409858e-01 3.363011e-04 5.722759e-03 -6.000000e+00 3.014670e-02 221.68 -2.00 3.63 -2.00 318.16 0.00e+00 1.323132e-03 5.967962e-05 3.685235e-04 -6.000000e+00 1.287089e-03 271.40 -2.00 20.00 -2.00 317.68 0.00e+00 3.133 0.001 302.00 328.00 3 1.3506e+00 8.8551e-04 3.7258e-02 -6.0000e+00 7.4272e-02 3.3204e-03 9.9896e-04 2.3356e-02 -6.0000e+00 8.0631e-02 -2.4393e-02 6.9639e-04 1.1879e-02 -6.0000e+00 4.7874e-02 1.2312e-02 3.8020e-04 3.5457e-03 -6.0000e+00 2.1201e-02 4.2919e-03 -5.6830e-03 1.7566e-05 3.6388e-05 -6.0000e+00 1.3804e-03 -1.4792e-01 8.0983e-05 12 9 1 12 5 1 99.99 24.49 0.31 -0.14792 -0.19063 229 30 1 5 0 179.960 33.00 20.00 24.49 12.92 0.0 896.25 900000 -14458 -17079 -13847 -14923 -18758 -24880 -21997 -17079 -12417 -16359 -15731 -15989 -11978 -6584 -1998 -752 943 1236 2055 1958 2212 1947 2199 1785 1442 242 -307 -1801 -1672 -3157 406 402 1559 248 -2962 -3864 -3692 -1903 -881 482 10 254 356 86 966 945 666 558 129 245 1220 1236 1645 1653 1348 1289 956 471 188 -131 826 1539 1867 2623 1278 46 -403 -753 195 624 541 765 167 333 -122 -843 -1451 -2407 -1971 -1780 -1633 -1406 -2320 -2076 -1376 -638 101 334 893 1002 653 456 -455 -372 -388 -510 -27 989 738 40 -376 -880 -835 -509 -749 -1257 -956 -663 -15 617 842 833 652 395 159 -21 94 179 291 282 73 277 645 673 489 260 -466 388 315 153 3 -376 -283 -400 -103 47 -96 436 203 -162 -340 -753 900000 -638 -901 -761 -817 -951 -1262 -1145 -949 -749 -1126 -1097 -1160 -982 -624 -218 -87 118 165 291 291 340 298 341 300 261 47 -62 -355 -308 -590 81 84 364 65 -764 -948 -970 -567 -290 176 4 106 155 39 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