File name: Pandora87s1_LapwaiID_20241209_L2Fit_fout2c2d20240715p1-8.txt File generation date: 20241210T074439.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 87 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora87_OF_v2d20240227.txt Instrument calibration file used: Pandora87s1_CF_v2d20240715.txt Level 1 file used: Pandora87s1_LapwaiID_20241209_L1_smca1c2d20240715p1-8.txt Full location name: Nez Perce Tribe cell tower site near Lapwai Idaho Short location name: LapwaiID Country of location: United States Location latitude [deg]: 46.3806 Location longitude [deg]: -116.8064 Location altitude [m]: 564 Local noon date: 20241209 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0760 305.2167 305.3574 305.4980 305.6386 305.7793 305.9199 306.0605 306.2011 306.3416 306.4822 306.6228 306.7633 306.9039 307.0444 307.1849 307.3254 307.4659 307.6064 307.7468 307.8873 308.0277 308.1682 308.3086 308.4490 308.5894 308.7298 308.8702 309.0105 309.1509 309.2912 309.4316 309.5719 309.7122 309.8525 309.9928 310.1331 310.2734 310.4136 310.5539 310.6941 310.8343 310.9745 311.1147 311.2549 311.3951 311.5353 311.6754 311.8156 311.9557 312.0958 312.2359 312.3760 312.5161 312.6562 312.7963 312.9363 313.0764 313.2164 313.3564 313.4965 313.6365 313.7764 313.9164 314.0564 314.1964 314.3363 314.4762 314.6162 314.7561 314.8960 315.0359 315.1757 315.3156 315.4555 315.5953 315.7351 315.8750 316.0148 316.1546 316.2944 316.4342 316.5739 316.7137 316.8534 316.9932 317.1329 317.2726 317.4123 317.5520 317.6917 317.8313 317.9710 318.1106 318.2503 318.3899 318.5295 318.6691 318.8087 318.9483 319.0878 319.2274 319.3669 319.5065 319.6460 319.7855 319.9250 320.0645 320.2040 320.3435 320.4829 320.6224 320.7618 320.9012 321.0406 321.1800 321.3194 321.4588 321.5982 321.7375 321.8769 322.0162 322.1555 322.2948 322.4341 322.5734 322.7127 322.8520 322.9912 323.1305 323.2697 323.4089 323.5481 323.6873 323.8265 323.9657 324.1048 324.2440 324.3831 324.5223 324.6614 324.8005 324.9396 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20241209T181249.6Z 9109.758908 1464 1 53.27 2 72.05 158.95 114.68 60.60 0.00 1 0.00 1 0 17 3.042e-01 4.813e-02 1.323e-01 6.811e-03 5.063966e-01 3.513567e-03 6.505212e-03 -6.000000e+00 1.708548e-01 221.52 -2.00 3.63 -2.00 319.72 0.00e+00 4.545138e-04 9.672587e-04 2.318367e-04 -6.000000e+00 7.452391e-03 270.01 -2.00 20.00 -2.00 319.32 0.00e+00 3.202 0.001 302.00 328.00 3 5.2014e+00 9.6710e-03 4.0164e-02 -6.0000e+00 4.2030e-01 1.1576e-01 1.1468e-02 2.7166e-02 -6.0000e+00 4.5655e-01 -1.3078e-01 1.0090e-02 1.4277e-02 -6.0000e+00 2.6985e-01 6.0631e-02 5.4373e-03 4.7154e-03 -6.0000e+00 1.1930e-01 7.4935e-05 -6.0302e-03 1.8212e-04 4.6436e-05 -6.0000e+00 7.8533e-03 -1.5129e-01 1.8661e-04 12 9 8 11 12 0 99.98 24.45 1.58 -0.15129 -0.19660 19 2 1 5 0 2803.450 33.00 20.04 24.45 13.43 0.0 897.93 900000 80644 -77588 8461 -115743 900000 900000 -78124 -98910 59652 -75006 -8510 -52332 -92446 -14193 -7427 1223 83489 -23707 18842 -33174 -6738 24012 16573 32850 32079 4732 -9400 -7117 56826 -21804 -18888 11671 20766 -2825 16387 14875 -12843 -13770 9049 8473 -3311 7771 8679 -436 -8740 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-617 2171 -162 3300 -2481 -2429 642 262 -2792 -3292 -474 -3254 -890 1352 1932 -2033 -1464 -747 638 1064 992 68 583 -265 1479 -191 1596 50691 2802 -1969 1544 1032 -799 1767 427 -1571 2538 559 484 -2418 1838 -1153 -1040 -949 -3430 SU 20241209T191820.6Z 9109.804405 2040 1 54.61 2 69.47 174.69 104.44 73.35 0.00 1 0.00 1 0 25 9.134e-02 1.030e-02 3.054e-02 3.280e-03 4.231940e-01 1.640021e-03 5.491015e-03 -6.000000e+00 5.088569e-02 221.52 -2.00 3.63 -2.00 318.93 0.00e+00 1.078063e-03 3.629960e-04 1.732606e-04 -6.000000e+00 2.161122e-03 270.01 -2.00 20.00 -2.00 318.50 0.00e+00 2.824 0.000 302.00 328.00 3 4.6277e+00 4.3965e-03 3.4538e-02 -6.0000e+00 1.2538e-01 3.8136e-02 5.0418e-03 2.2586e-02 -6.0000e+00 1.3615e-01 -4.4010e-02 3.9316e-03 1.1590e-02 -6.0000e+00 8.0782e-02 2.0142e-02 2.1524e-03 3.5780e-03 -6.0000e+00 3.5760e-02 2.1502e-04 -6.5193e-03 8.7839e-05 3.6927e-05 -6.0000e+00 2.3304e-03 -1.5026e-01 8.5992e-05 12 9 8 11 4 0 99.99 24.46 0.32 -0.15026 -0.19925 41 4 1 5 0 1331.800 33.00 20.03 24.46 12.22 0.0 891.94 900000 -16405 -22348 -8977 -43591 570 5461 -40870 -15656 6405 -29720 -17966 -29811 -51609 -10674 -612 201 19776 -8790 4586 -6007 -8482 12676 6722 18533 6077 2429 -3076 -5287 6487 -8749 -1330 3826 7602 1163 2298 -2731 -7012 -2752 715 2452 -2364 -866 681 1355 -1881 946 -268 418 -1133 -606 392 2137 1416 1677 2420 3266 444 2902 121 1716 1945 247 3486 2655 -222 1555 -3020 -969 511 -302 824 630 436 595 464 -1678 -1190 -2870 -3049 -1855 -373 -1205 -2038 -2768 -457 -515 29 982 1429 750 542 1080 -809 -707 -1713 -1247 220 975 1543 134 197 -926 -1174 -462 -378 -656 -866 -318 -1160 -339 775 1344 151 146 -245 36 -340 52 -95 118 294 278 503 691 561 1026 -716 789 370 59 93 -228 -422 265 -106 -95 -218 539 169 -72 -363 -890 900000 -493 -829 -313 -2119 16 134 -1673 -556 207 -1511 -827 -1583 -3945 -655 -41 16 1379 -869 422 -644 -963 1155 656 1725 686 300 -414 -703 716 -1108 -171 530 1138 204 385 -450 -1280 -553 167 683 -716 -276 223 453 -649 320 -92 142 -393 -212 144 850 611 774 1173 1614 232 1495 63 851 969 134 2017 1718 -157 1039 -1974 -607 326 -221 617 502 353 465 340 -1232 -780 -1806 -1971 -1350 -283 -1043 -1966 -2827 -483 -541 32 1119 1646 854 578 1139 -804 -669 -1711 -1282 252 1254 2035 183 256 -1206 -1384 -522 -461 -864 -1189 -425 -1660 -519 1198 2185 249 229 -386 53 -481 76 -146 193 465 462 811 1076 831 1449 -978 1109 520 92 157 -381 -726 467 -199 -177 -423 1053 338 -142 -682 -1706 SU 20241209T192714.3Z 9109.810582 2061 1 0.94 2 69.36 176.88 102.99 74.97 0.00 1 0.00 1 0 25 5.599e-02 1.079e-02 3.552e-02 7.525e-03 4.211212e-01 3.747296e-03 5.515047e-03 -6.000000e+00 3.118786e-02 221.52 -2.00 3.63 -2.00 317.84 0.00e+00 2.104033e-03 6.030375e-04 1.928746e-04 -6.000000e+00 1.324893e-03 270.01 -2.00 20.00 -2.00 317.39 0.00e+00 2.809 0.000 302.00 328.00 3 2.0098e+00 9.7953e-03 3.4251e-02 -6.0000e+00 7.6848e-02 1.1489e-02 1.0992e-02 2.2216e-02 -6.0000e+00 8.3452e-02 -2.8694e-02 7.3071e-03 1.1324e-02 -6.0000e+00 4.9514e-02 1.7115e-02 3.9478e-03 3.3773e-03 -6.0000e+00 2.1919e-02 3.0088e-03 -6.5816e-03 1.9547e-04 3.6751e-05 -6.0000e+00 1.4290e-03 -1.5391e-01 -1.1040e-04 12 9 9 12 5 1 999.00 24.47 0.38 -0.15391 -0.20337 1 12 1 5 0 466.110 33.00 20.03 24.47 12.14 0.0 891.94 900000 -11499 -4414 -13496 5931 -13533 -22648 -24337 -22272 -16270 -4030 -17286 -26639 -13794 3316 -9697 8844 4662 -1698 862 4800 -1236 -5259 2993 -5063 421 -2746 3533 1319 532 -3571 300 2618 4192 1648 -1941 -6699 -2847 -4944 2337 434 3666 1764 2213 2506 -1323 657 475 370 2774 -237 1993 2965 1442 2894 794 2309 585 -627 -703 -848 377 908 1183 1896 1857 -1416 851 -1581 -2077 566 -387 578 -856 115 -187 73 -354 -3561 -1689 -862 -2008 -2057 -2572 -1842 -586 -501 -796 -225 367 2044 529 1229 -846 190 -351 415 -468 835 1718 109 -179 -118 -1587 -887 -25 -1741 -833 -1307 487 876 652 1115 50 202 521 92 -564 775 654 225 -682 -26 1099 700 643 858 -210 -244 323 74 -21 -615 -33 -636 329 204 -337 104 250 -317 -589 -278 900000 -700 -291 -954 374 -923 -1579 -1804 -1798 -1270 -334 -1511 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