File name: Pandora87s1_LapwaiID_20241210_L2Fit_fout2c2d20240715p1-8.txt File generation date: 20241211T074519.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 87 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora87_OF_v2d20240227.txt Instrument calibration file used: Pandora87s1_CF_v2d20240715.txt Level 1 file used: Pandora87s1_LapwaiID_20241210_L1_smca1c2d20240715p1-8.txt Full location name: Nez Perce Tribe cell tower site near Lapwai Idaho Short location name: LapwaiID Country of location: United States Location latitude [deg]: 46.3806 Location longitude [deg]: -116.8064 Location altitude [m]: 564 Local noon date: 20241210 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0760 305.2167 305.3574 305.4980 305.6386 305.7793 305.9199 306.0605 306.2011 306.3416 306.4822 306.6228 306.7633 306.9039 307.0444 307.1849 307.3254 307.4659 307.6064 307.7468 307.8873 308.0277 308.1682 308.3086 308.4490 308.5894 308.7298 308.8702 309.0105 309.1509 309.2912 309.4316 309.5719 309.7122 309.8525 309.9928 310.1331 310.2734 310.4136 310.5539 310.6941 310.8343 310.9745 311.1147 311.2549 311.3951 311.5353 311.6754 311.8156 311.9557 312.0958 312.2359 312.3760 312.5161 312.6562 312.7963 312.9363 313.0764 313.2164 313.3564 313.4965 313.6365 313.7764 313.9164 314.0564 314.1964 314.3363 314.4762 314.6162 314.7561 314.8960 315.0359 315.1757 315.3156 315.4555 315.5953 315.7351 315.8750 316.0148 316.1546 316.2944 316.4342 316.5739 316.7137 316.8534 316.9932 317.1329 317.2726 317.4123 317.5520 317.6917 317.8313 317.9710 318.1106 318.2503 318.3899 318.5295 318.6691 318.8087 318.9483 319.0878 319.2274 319.3669 319.5065 319.6460 319.7855 319.9250 320.0645 320.2040 320.3435 320.4829 320.6224 320.7618 320.9012 321.0406 321.1800 321.3194 321.4588 321.5982 321.7375 321.8769 322.0162 322.1555 322.2948 322.4341 322.5734 322.7127 322.8520 322.9912 323.1305 323.2697 323.4089 323.5481 323.6873 323.8265 323.9657 324.1048 324.2440 324.3831 324.5223 324.6614 324.8005 324.9396 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20241210T165812.4Z 9110.707088 804 1 54.67 2 78.47 142.37 123.21 27.49 0.00 1 0.00 1 0 25 3.250e-01 1.990e-02 1.265e-01 5.429e-03 6.128410e-01 2.819134e-03 7.733526e-03 -6.000000e+00 1.821762e-01 221.51 -2.00 3.63 -2.00 320.46 0.00e+00 4.359830e-03 9.526976e-04 3.705761e-04 -6.000000e+00 7.690946e-03 269.90 -2.00 20.00 -2.00 320.07 0.00e+00 4.845 0.002 302.00 328.00 3 3.3838e+00 8.1304e-03 5.5503e-02 -6.0000e+00 4.4939e-01 2.6640e-01 1.0113e-02 3.3212e-02 -6.0000e+00 4.8865e-01 -3.4907e-01 9.7936e-03 1.7715e-02 -6.0000e+00 2.8985e-01 1.5309e-01 5.0972e-03 5.6675e-03 -6.0000e+00 1.2758e-01 9.6045e-05 -7.5205e-03 1.4096e-04 6.0622e-05 -6.0000e+00 8.3119e-03 -1.5085e-01 -2.0013e-05 12 9 8 11 44 0 99.98 24.36 -0.08 -0.15085 -0.20736 26 3 1 5 0 2102.600 33.00 19.99 24.36 5.34 0.0 858.03 900000 -58639 -124095 -9125 -148841 -56707 725 -72276 -54890 -10649 -87101 -111145 -130543 -139712 -4524 -32010 -10924 900000 -52750 27526 -42971 -21522 59109 -8189 83626 26067 5419 -10770 -24289 82172 -39630 -15911 15606 15959 19405 26012 15196 -10350 826 8782 22867 -668 11343 9121 4602 -5052 5674 6963 6616 5723 5712 1828 14923 13939 3764 18672 10265 1265 9987 496 11122 10532 1611 12168 8020 -847 10444 -7173 -4271 7893 -151 3190 2120 -752 1464 1648 -3326 -2449 -2273 -3481 -1717 2320 -247 -796 -4820 626 -2473 -1066 15 -454 177 -726 3123 -1452 -1912 -5026 -3089 -1497 104 618 -146 -1443 -1143 -1116 -841 -845 -276 -1815 -71 -2464 -257 114 1493 -111 -177 -289 993 180 467 306 677 188 1026 1270 1636 1107 2066 -222 1128 237 313 298 353 -337 203 76 -151 -227 1038 -317 -466 -640 -1858 900000 -790 -3821 -97 -6302 -846 6 -1182 -819 -124 -2351 -3882 -5803 -8281 -89 -1033 -347 900000 -3127 787 -2592 -1071 1283 -347 1505 883 235 -564 -1414 1566 -2601 -952 809 954 1253 1528 925 -854 69 818 2239 -95 1531 1323 721 -874 895 1102 1068 963 1001 361 2890 2973 962 4387 2705 375 2727 144 2808 2681 480 3671 2869 -362 3930 -3086 -1793 3083 -73 1695 1210 -405 811 842 -1595 -1050 -941 -1547 -879 1348 -154 -559 -3740 486 -2126 -955 14 -426 162 -627 2397 -1097 -1424 -4155 -2881 -1588 114 767 -189 -1813 -1309 -1239 -882 -948 -331 -2113 -86 -3310 -374 185 2396 -185 -287 -482 1533 273 730 507 1094 312 1630 2096 2608 1695 3018 -318 1561 363 545 529 677 -680 427 158 -336 -521 2382 -749 -1077 -1394 -3848 SU 20241210T171033.8Z 9110.715669 825 1 20.73 2 77.21 144.97 122.16 30.75 0.00 1 0.00 1 0 25 2.129e-01 1.044e-02 5.507e-02 3.314e-03 5.612120e-01 1.682876e-03 7.138767e-03 -6.000000e+00 1.185963e-01 221.51 -2.00 3.63 -2.00 319.64 0.00e+00 2.137652e-03 4.688523e-04 4.916488e-04 -6.000000e+00 5.033888e-03 269.90 -2.00 20.00 -2.00 319.24 0.00e+00 4.400 0.002 302.00 328.00 3 2.3429e+00 4.6196e-03 5.0497e-02 -6.0000e+00 2.9223e-01 6.7509e-02 5.4941e-03 3.0185e-02 -6.0000e+00 3.1731e-01 -1.0558e-01 5.0356e-03 1.5687e-02 -6.0000e+00 1.8826e-01 4.6795e-02 2.7180e-03 4.8937e-03 -6.0000e+00 8.3353e-02 4.4858e-04 -6.0213e-03 8.4680e-05 4.9356e-05 -6.0000e+00 5.4302e-03 -1.5163e-01 9.2114e-05 12 9 9 12 5 1 99.92 24.36 0.21 -0.15163 -0.19688 15 4 1 5 0 1295.290 32.75 19.99 24.36 5.85 0.0 861.10 900000 -73540 -86883 -63414 -69438 -59176 -15385 -73189 -73541 -56393 -64921 -65063 -58067 -71449 -39968 -25051 -10814 7968 -12863 -13378 -6778 -14502 3550 -4052 21610 -2163 -4530 -5749 -17616 -3576 -18546 -6380 4873 6279 -2795 -8146 -6196 -6645 -2526 659 2612 926 3375 2855 791 -643 1833 3719 2398 1184 474 984 3464 3623 1811 3594 4016 1659 -471 898 615 2870 2356 4120 5182 1073 1581 -1853 -1413 149 777 997 709 1159 375 -1187 -1233 -2742 -3274 -2469 -1612 -1084 -1079 -1787 -2904 -1428 -1124 225 803 1568 857 937 263 -501 -1320 -520 -1296 -163 1067 1405 -594 352 -930 -1136 -1072 -578 -1133 -1236 -525 -459 591 404 846 829 186 16 -146 -78 161 411 290 -120 759 503 980 748 711 -549 182 428 -184 -80 -449 -224 -361 -253 156 -118 415 286 36 -14 -1108 900000 -1307 -2105 -1332 -1548 -1071 -169 -1513 -1711 -1257 -1741 -1808 -1595 -2724 -1408 -947 -430 296 -644 -730 -366 -876 178 -223 998 -137 -312 -416 -1400 -235 -1438 -503 405 594 -324 -971 -683 -786 -331 102 484 183 700 628 184 -152 431 873 579 298 125 281 1080 1232 681 1422 1504 658 -193 353 236 1183 961 1856 2616 612 878 -1019 -775 85 466 676 513 845 264 -789 -735 -1624 -1881 -1487 -1038 -815 -864 -1608 -2612 -1341 -1132 237 818 1607 867 946 247 -445 -1237 -484 -1389 -186 1299 1806 -802 475 -1163 -1353 -1223 -706 -1405 -1602 -718 -636 845 645 1374 1366 299 25 -218 -113 242 651 465 -198 1200 811 1524 1112 1075 -803 259 631 -309 -139 -805 -417 -670 -499 313 -246 870 611 76 -30 -2184 SU 20241210T171222.2Z 9110.716923 828 1 33.57 2 77.03 145.36 122.00 31.22 0.00 1 0.00 1 0 25 2.107e-01 1.042e-02 4.310e-02 2.576e-03 5.518350e-01 1.305963e-03 7.047196e-03 -6.000000e+00 1.173548e-01 221.51 -2.00 3.63 -2.00 319.62 0.00e+00 1.955057e-03 3.623112e-04 5.780663e-04 -6.000000e+00 4.982518e-03 269.90 -2.00 20.00 -2.00 319.22 0.00e+00 4.344 0.002 302.00 328.00 3 2.4021e+00 3.5967e-03 4.9830e-02 -6.0000e+00 2.8917e-01 5.8523e-02 4.2765e-03 2.9840e-02 -6.0000e+00 3.1401e-01 -9.3606e-02 3.8846e-03 1.5406e-02 -6.0000e+00 1.8630e-01 4.1620e-02 2.0958e-03 4.8592e-03 -6.0000e+00 8.2469e-02 4.5004e-04 -6.4072e-03 6.6489e-05 5.0046e-05 -6.0000e+00 5.3753e-03 -1.5138e-01 3.4829e-05 12 9 9 12 5 1 99.97 24.36 0.25 -0.15138 -0.19952 30 5 1 5 0 1082.630 32.75 20.00 24.36 5.96 0.0 861.42 900000 -33695 -89454 -70044 -69019 -37964 -67682 -80168 -55735 -10563 -79700 -61140 -76700 -77510 -37223 -4134 -13444 12685 -16152 -5181 -15599 -11537 4715 -1278 9923 -3524 -7710 -10234 -14360 -5234 -8722 -8660 -135 1190 850 -627 -5221 -8142 -5167 -2736 3854 -20 -148 793 1485 571 820 2387 2831 349 1439 3315 2523 4508 3517 3171 3307 1573 1854 498 1287 2434 2169 3883 4403 1491 1114 -1136 -1202 415 1153 1196 1059 236 1187 -404 -1470 -2124 -2831 -2428 -1919 -1289 -1122 -2207 -2749 -1496 -717 -251 159 1493 838 744 667 -775 -849 -1324 -616 -350 660 654 -404 -233 -941 -1051 -489 -578 -1175 -1034 -986 -780 355 1006 1156 293 386 -74 -123 -1 245 429 353 150 615 995 844 734 587 -583 -97 74 254 108 -345 -381 -332 10 162 -261 514 132 -36 -172 -983 900000 -415 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