File name: Pandora87s1_LapwaiID_20241222_L2Fit_fout2c2d20240715p1-8.txt File generation date: 20241223T074957.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 87 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora87_OF_v2d20240227.txt Instrument calibration file used: Pandora87s1_CF_v2d20240715.txt Level 1 file used: Pandora87s1_LapwaiID_20241222_L1_smca1c2d20240715p1-8.txt Full location name: Nez Perce Tribe cell tower site near Lapwai Idaho Short location name: LapwaiID Country of location: United States Location latitude [deg]: 46.3806 Location longitude [deg]: -116.8064 Location altitude [m]: 564 Local noon date: 20241222 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0760 305.2167 305.3574 305.4980 305.6386 305.7793 305.9199 306.0605 306.2011 306.3416 306.4822 306.6228 306.7633 306.9039 307.0444 307.1849 307.3254 307.4659 307.6064 307.7468 307.8873 308.0277 308.1682 308.3086 308.4490 308.5894 308.7298 308.8702 309.0105 309.1509 309.2912 309.4316 309.5719 309.7122 309.8525 309.9928 310.1331 310.2734 310.4136 310.5539 310.6941 310.8343 310.9745 311.1147 311.2549 311.3951 311.5353 311.6754 311.8156 311.9557 312.0958 312.2359 312.3760 312.5161 312.6562 312.7963 312.9363 313.0764 313.2164 313.3564 313.4965 313.6365 313.7764 313.9164 314.0564 314.1964 314.3363 314.4762 314.6162 314.7561 314.8960 315.0359 315.1757 315.3156 315.4555 315.5953 315.7351 315.8750 316.0148 316.1546 316.2944 316.4342 316.5739 316.7137 316.8534 316.9932 317.1329 317.2726 317.4123 317.5520 317.6917 317.8313 317.9710 318.1106 318.2503 318.3899 318.5295 318.6691 318.8087 318.9483 319.0878 319.2274 319.3669 319.5065 319.6460 319.7855 319.9250 320.0645 320.2040 320.3435 320.4829 320.6224 320.7618 320.9012 321.0406 321.1800 321.3194 321.4588 321.5982 321.7375 321.8769 322.0162 322.1555 322.2948 322.4341 322.5734 322.7127 322.8520 322.9912 323.1305 323.2697 323.4089 323.5481 323.6873 323.8265 323.9657 324.1048 324.2440 324.3831 324.5223 324.6614 324.8005 324.9396 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241222T190309.7Z 9122.793863 391 1 54.46 2 70.49 169.53 84.43 263.40 0.00 1 0.00 1 0 25 2.105e-02 7.343e-03 3.877e-03 9.840e-04 3.479974e-01 4.891894e-04 4.565614e-03 -6.000000e+00 1.174207e-02 221.80 -2.00 3.63 -2.00 317.56 0.00e+00 9.564307e-04 7.202883e-05 2.667137e-04 -6.000000e+00 4.957296e-04 268.93 -2.00 20.00 -2.00 317.12 0.00e+00 2.962 0.000 302.00 328.00 3 2.6002e+00 1.2745e-03 3.2951e-02 -6.0000e+00 2.8962e-02 3.5272e-02 1.4268e-03 1.8467e-02 -6.0000e+00 3.1443e-02 -2.6856e-02 9.1763e-04 9.3397e-03 -6.0000e+00 1.8640e-02 1.0058e-02 4.8826e-04 2.7763e-03 -6.0000e+00 8.2443e-03 1.6352e-03 -6.3402e-03 2.6119e-05 2.9359e-05 -6.0000e+00 5.3685e-04 -1.5341e-01 1.1763e-04 11 9 0 11 12 0 99.99 24.50 0.26 -0.15341 -0.20106 154 15 1 5 0 353.590 33.00 20.02 24.50 12.69 0.0 895.13 900000 -3296 -4997 -1660 -5386 -5113 -6323 -6384 -6124 -1591 -5190 -8566 -9014 -6955 -2331 690 600 1546 493 1835 824 1613 1572 2173 2558 2038 358 -122 -1100 -1394 -2585 337 778 939 209 -3188 -4127 -3263 -2023 -799 342 -237 -518 -292 332 68 481 490 226 -578 -488 892 1012 822 1280 1330 1466 782 559 213 432 592 1285 1466 2375 1217 -142 -910 -875 306 671 538 777 200 485 330 -835 -995 -2315 -1798 -1375 -1370 -1317 -1916 -2171 -1187 -719 -42 239 921 831 651 460 -504 -512 -364 -430 -126 869 1002 183 -207 -665 -856 -549 -236 -1085 -865 -651 -402 511 813 825 502 378 34 -9 75 7 283 386 146 190 608 708 458 460 -563 279 182 23 -71 -370 -375 -322 -113 74 -149 360 266 -23 -295 -702 900000 -249 -441 -151 -499 -418 -483 -507 -538 -151 -558 -963 -1024 -875 -332 102 102 282 96 371 175 352 341 470 587 500 94 -33 -290 -342 -623 84 215 287 64 -978 -1297 -986 -691 -323 152 -121 -261 -153 177 36 257 261 119 -305 -258 488 603 491 811 887 999 550 398 149 295 408 934 1096 1933 994 -112 -710 -659 233 542 492 713 188 441 300 -694 -787 -1731 -1351 -1157 -1246 -1271 -1937 -2309 -1321 -818 -50 284 1106 982 758 518 -526 -531 -368 -483 -151 1101 1339 253 -273 -851 -1048 -650 -287 -1437 -1136 -900 -559 754 1241 1270 771 576 50 -12 103 10 405 568 225 290 900 1060 653 655 -770 365 253 34 -107 -586 -585 -514 -190 129 -258 630 477 -41 -520 -1193 SS 20241222T191324.3Z 9122.800975 397 1 36.94 2 70.21 172.00 86.17 265.19 0.00 1 0.00 1 0 25 2.990e-02 7.919e-03 9.397e-03 2.187e-03 3.417939e-01 1.087287e-03 4.458336e-03 -6.000000e+00 1.669171e-02 221.80 -2.00 3.63 -2.00 317.72 0.00e+00 1.107140e-03 1.678791e-04 2.693432e-04 -6.000000e+00 7.040633e-04 268.93 -2.00 20.00 -2.00 317.29 0.00e+00 2.922 0.000 302.00 328.00 3 3.7049e+00 2.8385e-03 3.2463e-02 -6.0000e+00 4.1173e-02 4.1639e-02 3.1809e-03 1.8128e-02 -6.0000e+00 4.4689e-02 -2.4764e-02 2.0855e-03 9.1860e-03 -6.0000e+00 2.6492e-02 9.7645e-03 1.1153e-03 2.7304e-03 -6.0000e+00 1.1725e-02 5.6361e-04 -5.6428e-03 5.8269e-05 2.8355e-05 -6.0000e+00 7.6242e-04 -1.5494e-01 2.6764e-04 12 9 1 12 37 1 99.99 24.51 0.33 -0.15494 -0.19734 18 3 1 5 0 1943.710 33.00 20.01 24.51 13.20 0.0 897.83 900000 -5110 -8313 -5093 -15881 -347 -6673 -5083 -8163 -2645 -8350 -11683 -11205 -10563 -2500 1128 1017 5012 -1920 4272 -2611 700 4223 1280 3522 1469 1441 -915 -1244 -250 -4663 -87 1465 3602 1139 -1024 -3774 -3167 -2477 691 801 -739 -459 249 215 -1465 -93 -434 196 -618 -485 545 1583 1183 1038 1605 1453 826 1417 72 808 801 1529 2340 2369 781 252 -1439 -841 118 148 320 706 -82 288 347 -450 -1328 -1560 -1424 -1425 -1147 -947 -1837 -2425 -993 -700 47 113 713 1074 606 553 -722 -566 -551 -783 -338 766 1122 -39 -5 -899 -712 -47 -358 -1191 -1066 -780 -280 385 737 843 363 479 -153 79 145 206 346 481 94 99 750 721 845 592 -608 308 335 -99 34 -345 -344 -209 -230 300 -286 390 184 -159 -280 -807 900000 -354 -684 -432 -1477 -24 -461 -358 -656 -227 -830 -1213 -1161 -1225 -317 162 169 864 -338 822 -510 137 790 247 706 320 329 -220 -290 -53 -1010 -19 353 938 332 -294 -1034 -911 -808 262 335 -356 -234 131 108 -744 -47 -219 105 -331 -259 279 874 701 656 1062 986 537 925 50 547 547 1023 1704 1895 624 207 -1108 -621 88 125 284 665 -79 269 306 -387 -1031 -1131 -1039 -1168 -1004 -930 -1875 -2610 -1048 -795 56 134 851 1256 707 591 -762 -561 -562 -887 -403 957 1464 -52 -6 -1136 -865 -56 -456 -1557 -1449 -1055 -397 550 1136 1300 559 735 -230 110 205 282 502 714 145 152 1118 1097 1218 817 -853 412 476 -146 51 -547 -559 -332 -385 509 -506 697 338 -289 -488 -1417 SS 20241222T195126.7Z 9122.827392 414 1 25.95 2 69.82 181.28 92.67 271.80 0.00 1 0.00 1 0 17 4.252e-02 2.560e-02 1.387e-02 3.155e-03 3.571958e-01 1.569436e-03 4.725286e-03 -6.000000e+00 2.371707e-02 221.80 -2.00 3.63 -2.00 317.77 0.00e+00 7.703056e-04 2.462916e-04 5.396235e-04 -6.000000e+00 1.001579e-03 268.93 -2.00 20.00 -2.00 317.34 0.00e+00 2.870 0.000 302.00 328.00 3 3.9633e+00 4.1021e-03 3.2606e-02 -6.0000e+00 5.8497e-02 1.0517e-01 4.6028e-03 1.9115e-02 -6.0000e+00 6.3514e-02 -4.0236e-02 3.0262e-03 9.6353e-03 -6.0000e+00 3.7653e-02 6.7258e-03 1.6214e-03 2.8730e-03 -6.0000e+00 1.6650e-02 4.3379e-04 -5.9901e-03 8.4032e-05 3.1118e-05 -6.0000e+00 1.0847e-03 -1.5320e-01 6.3634e-05 12 9 9 12 5 1 99.61 24.51 0.36 -0.15320 -0.19821 7 2 1 5 0 3243.050 33.00 19.96 24.51 14.14 0.0 901.86 900000 -1673 -7632 -5922 -11983 2632 -9773 -13954 -12108 -4718 -15928 -17471 -15402 -12359 -3200 1463 2208 4252 -1235 3333 -2642 -2372 884 5354 2939 2344 -1469 -755 -4053 311 -6051 -1568 2883 4456 211 -624 -4451 -1575 -869 -32 1324 -71 1070 395 -1081 -1523 -458 -1395 17 -625 -1072 -664 1823 1926 2197 1957 2817 1027 2200 201 1282 1235 676 3187 2957 153 -171 -1711 -211 866 1323 469 1255 425 588 -662 -1680 -1420 -2319 -1754 -712 -510 -156 -1293 -2021 -337 -452 -416 325 530 -86 -287 345 -1507 -1245 -657 -203 137 1465 1507 237 318 -1287 -1715 -796 -759 -1869 -1768 -1288 -1478 272 453 577 70 38 -585 -221 -148 373 81 713 -832 -147 -626 -747 21014 -584 -1738 -691 -76 -515 -203 -1067 -424 -106 577 388 -313 442 -274 -633 -548 -1659 900000 -108 -596 -483 -1014 170 -661 -1026 -972 -398 -1636 -1838 -1601 -1414 -396 203 351 713 -230 625 -498 -460 180 1051 630 489 -334 -175 -933 70 -1407 -375 664 1118 60 -171 -1185 -433 -271 -12 536 -33 521 201 -572 -806 -241 -738 8 -321 -554 -359 1050 1093 1324 1244 1816 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