File name: Pandora87s1_LapwaiID_20250104_L2Fit_fout2c2d20240715p1-8.txt File generation date: 20250105T075720.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 87 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora87_OF_v2d20240227.txt Instrument calibration file used: Pandora87s1_CF_v2d20240715.txt Level 1 file used: Pandora87s1_LapwaiID_20250104_L1_smca1c2d20240715p1-8.txt Full location name: Nez Perce Tribe cell tower site near Lapwai Idaho Short location name: LapwaiID Country of location: United States Location latitude [deg]: 46.3806 Location longitude [deg]: -116.8064 Location altitude [m]: 564 Local noon date: 20250104 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0760 305.2167 305.3574 305.4980 305.6386 305.7793 305.9199 306.0605 306.2011 306.3416 306.4822 306.6228 306.7633 306.9039 307.0444 307.1849 307.3254 307.4659 307.6064 307.7468 307.8873 308.0277 308.1682 308.3086 308.4490 308.5894 308.7298 308.8702 309.0105 309.1509 309.2912 309.4316 309.5719 309.7122 309.8525 309.9928 310.1331 310.2734 310.4136 310.5539 310.6941 310.8343 310.9745 311.1147 311.2549 311.3951 311.5353 311.6754 311.8156 311.9557 312.0958 312.2359 312.3760 312.5161 312.6562 312.7963 312.9363 313.0764 313.2164 313.3564 313.4965 313.6365 313.7764 313.9164 314.0564 314.1964 314.3363 314.4762 314.6162 314.7561 314.8960 315.0359 315.1757 315.3156 315.4555 315.5953 315.7351 315.8750 316.0148 316.1546 316.2944 316.4342 316.5739 316.7137 316.8534 316.9932 317.1329 317.2726 317.4123 317.5520 317.6917 317.8313 317.9710 318.1106 318.2503 318.3899 318.5295 318.6691 318.8087 318.9483 319.0878 319.2274 319.3669 319.5065 319.6460 319.7855 319.9250 320.0645 320.2040 320.3435 320.4829 320.6224 320.7618 320.9012 321.0406 321.1800 321.3194 321.4588 321.5982 321.7375 321.8769 322.0162 322.1555 322.2948 322.4341 322.5734 322.7127 322.8520 322.9912 323.1305 323.2697 323.4089 323.5481 323.6873 323.8265 323.9657 324.1048 324.2440 324.3831 324.5223 324.6614 324.8005 324.9396 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250104T173337.0Z 9135.731679 108 1 43.86 2 75.83 147.18 100.00 90.76 0.00 1 0.00 1 0 25 2.855e-01 1.115e-02 5.079e-02 2.487e-03 6.150601e-01 1.268065e-03 7.800749e-03 -6.000000e+00 1.596764e-01 222.33 -2.00 3.63 -2.00 319.88 0.00e+00 2.571674e-03 3.751240e-04 3.570061e-04 -6.000000e+00 6.700798e-03 268.19 -2.00 20.00 -2.00 319.51 0.00e+00 3.998 0.001 302.00 328.00 3 2.7938e+00 3.5272e-03 4.9557e-02 -6.0000e+00 3.9442e-01 7.6550e-02 4.2975e-03 3.3176e-02 -6.0000e+00 4.2797e-01 -1.2513e-01 4.1686e-03 1.7556e-02 -6.0000e+00 2.5349e-01 5.7501e-02 2.2269e-03 5.5919e-03 -6.0000e+00 1.1205e-01 3.7621e-04 -6.4778e-03 6.2166e-05 5.4314e-05 -6.0000e+00 7.2780e-03 -1.5864e-01 2.0710e-04 12 9 9 12 13 1 99.99 24.47 0.18 -0.15864 -0.20732 33 4 1 5 0 1289.690 33.00 20.00 24.47 8.02 0.0 871.21 900000 -73058 -118434 -103400 -108235 -48596 -57833 -86665 -78692 -50136 -93255 -97377 -86022 -93841 -72231 -18520 -25588 36248 -29370 -17104 -24444 -18503 1714 -14911 857 3046 -5089 -16390 -24785 -3304 -21543 -11135 -1241 421 4996 122 2481 -11078 -6140 -902 1954 -1992 1779 3884 2849 -2795 1579 1777 1923 1879 1923 3590 6246 4048 4650 6398 4833 1226 2682 1512 2305 1414 1847 3697 4868 1178 2791 -1835 -765 795 755 305 1711 396 368 587 -2079 -2090 -3771 -2751 -345 -1105 -1106 -2311 -2643 -986 -1152 77 185 1020 1165 122 1292 -460 -906 -1321 -1328 -688 345 896 -175 1 -778 -866 -1341 -857 -1241 -1527 -661 -476 559 759 987 518 343 83 -44 3 48 306 358 -116 190 893 447 1264 733 -504 660 502 8 125 -128 -12 -270 -88 -74 -121 293 175 -166 -379 -857 900000 -850 -2642 -2206 -2467 -554 -673 -1408 -1316 -717 -2284 -2597 -2169 -3117 -2487 -471 -862 756 -1303 -734 -1197 -888 67 -694 37 140 -269 -1013 -1641 -168 -1337 -718 -87 34 436 11 206 -1112 -674 -114 295 -364 340 769 539 -564 310 356 392 398 426 851 1623 1182 1471 2142 1711 466 1020 566 829 513 712 1574 2143 592 1373 -908 -376 404 439 188 1111 264 236 378 -1231 -1114 -1969 -1499 -214 -756 -872 -1928 -2353 -913 -1147 74 186 1035 1160 123 1194 -407 -786 -1231 -1324 -787 422 1160 -239 2 -995 -986 -1539 -977 -1527 -1965 -896 -652 835 1197 1600 865 560 136 -67 5 73 493 579 -192 304 1440 700 1879 1114 -743 938 780 14 219 -232 -23 -533 -176 -151 -255 623 377 -351 -794 -1699 SS 20250104T174012.2Z 9135.736252 112 1 13.14 2 75.22 148.62 98.88 91.89 0.00 1 0.00 1 0 25 2.004e-01 9.639e-03 1.795e-02 1.380e-03 5.918467e-01 6.967619e-04 7.602643e-03 -6.000000e+00 1.121083e-01 222.33 -2.00 3.63 -2.00 319.20 0.00e+00 2.383848e-03 1.678269e-04 5.507473e-04 -6.000000e+00 4.705444e-03 268.19 -2.00 20.00 -2.00 318.82 0.00e+00 3.845 0.001 302.00 328.00 3 8.1207e-01 1.8787e-03 4.7616e-02 -6.0000e+00 2.7692e-01 3.2052e-02 2.1820e-03 3.1732e-02 -6.0000e+00 3.0049e-01 -8.3905e-02 1.8668e-03 1.6343e-02 -6.0000e+00 1.7799e-01 4.0960e-02 1.0274e-03 4.9885e-03 -6.0000e+00 7.8657e-02 3.2534e-03 -6.5556e-03 3.4201e-05 5.1016e-05 -6.0000e+00 5.1110e-03 -1.5838e-01 1.6430e-04 12 9 9 12 5 1 97.11 24.47 0.32 -0.15838 -0.20764 62 26 1 5 0 208.480 33.00 19.98 24.47 8.05 0.0 872.06 900000 -73446 -68061 -58120 -59200 -65414 -81524 -72976 -65458 -55856 -54188 -55566 -52939 -49408 -27513 -21625 -15173 -8292 -8744 -10283 -5863 -2127 -5197 -7627 -5038 -3457 -4914 -2757 -7691 -5356 -12317 -5208 -752 190 329 -1784 -5469 -6248 -883 -220 1887 1165 1117 1179 1933 2288 2804 2064 1375 1067 1244 1833 2634 3244 2968 3116 2280 1903 682 -538 385 -141 1009 2104 3201 2291 1020 454 -424 60 887 834 995 485 464 -53 -1028 -1679 -2975 -2199 -1743 -1640 -1462 -1994 -2500 -1423 -965 -294 63 735 864 786 695 -652 -646 -942 -581 -381 460 866 238 -243 -1007 -956 -673 -771 -1377 -1003 -840 -121 547 721 844 619 491 147 -43 161 169 361 408 74 403 754 934 564 420 -377 242 627 287 155 -281 -195 -353 -284 -209 -297 353 280 18 -343 -855 900000 -1502 -1603 -1376 -1442 -1540 -2106 -1817 -1691 -1496 -1590 -1727 -1695 -1855 -1063 -992 -802 -469 -547 -714 -413 -151 -378 -576 -403 -295 -454 -260 -751 -487 -1218 -551 -82 24 47 -259 -771 -939 -145 -44 411 297 310 346 585 696 864 603 412 332 404 642 1029 1284 1283 1448 1037 901 332 -258 177 -66 495 1147 1842 1374 614 280 -264 37 615 624 753 375 345 -39 -723 -1070 -1847 -1424 -1236 -1299 -1264 -1855 -2372 -1412 -980 -314 66 786 947 809 691 -647 -624 -930 -625 -434 574 1169 324 -331 -1314 -1155 -797 -936 -1741 -1316 -1126 -167 795 1093 1342 1009 781 229 -64 243 254 552 662 120 650 1166 1442 835 619 -555 345 936 456 264 -487 -353 -648 -538 -412 -590 706 569 35 -667 -1616 SS 20250104T174511.1Z 9135.739712 115 1 54.58 2 74.78 149.72 98.03 92.74 0.00 1 0.00 1 0 25 1.713e-01 9.602e-03 4.526e-03 3.980e-04 5.758901e-01 2.006896e-04 7.410984e-03 -6.000000e+00 9.584086e-02 222.33 -2.00 3.63 -2.00 319.03 0.00e+00 2.443359e-03 4.562417e-05 4.904398e-04 -6.000000e+00 4.022341e-03 268.19 -2.00 20.00 -2.00 318.64 0.00e+00 3.740 0.001 302.00 328.00 3 -1.0053e-01 5.3953e-04 4.6299e-02 -6.0000e+00 2.3674e-01 2.3975e-02 6.1998e-04 3.0746e-02 -6.0000e+00 2.5689e-01 -7.9986e-02 5.0668e-04 1.5775e-02 -6.0000e+00 1.5216e-01 3.9560e-02 2.7959e-04 4.7630e-03 -6.0000e+00 6.7246e-02 9.0816e-03 -6.4021e-03 9.9009e-06 4.8846e-05 -6.0000e+00 4.3689e-03 -1.5816e-01 1.9311e-04 12 9 8 11 4 0 96.68 24.47 0.29 -0.15816 -0.20627 740 73 1 5 0 73.740 33.00 20.03 24.47 8.31 0.0 873.57 900000 -61114 -58177 -49031 -52890 -55899 -63743 -63973 -55986 -49713 -46940 -49929 -48015 -40114 -28095 -16866 -10871 -5811 -5762 -3029 -3574 -3027 -3674 -5106 -3368 -3473 -4494 -5476 -6732 -7998 -8624 -3831 -1694 1347 648 -2400 -4536 -4666 -2034 240 1964 1469 1715 1808 1673 2312 2261 2157 1756 1267 996 1924 2436 2389 2738 2330 2073 1727 978 74 -30 321 1371 2106 3249 2392 751 216 -467 257 745 641 935 509 348 -112 -1001 -1748 -3073 -2490 -1857 -1751 -1401 -2139 -2306 -1774 -923 -126 155 735 952 675 391 -617 -757 -819 -680 -337 706 792 158 -273 -731 -916 -696 -549 -1347 -1054 -768 -151 529 824 881 668 511 56 -70 176 134 297 324 191 285 813 949 529 456 -455 386 525 231 145 -305 -135 -432 -167 -40 -275 260 229 -27 -410 -768 900000 -1397 -1565 -1334 -1519 -1501 -1727 -1820 -1643 -1561 -1594 -1821 -1811 -1691 -1339 -902 -671 -389 -424 -236 -297 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