File name: Pandora87s1_LapwaiID_20250512_L2Fit_fout2c2d20240715p1-8.txt File generation date: 20250731T125217.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 87 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora87_OF_v2d20240227.txt Instrument calibration file used: Pandora87s1_CF_v2d20240715.txt Level 1 file used: Pandora87s1_LapwaiID_20250512_L1_smca1c2d20240715p1-8.txt Full location name: Nez Perce Tribe cell tower site near Lapwai Idaho Short location name: LapwaiID Country of location: United States Location latitude [deg]: 46.3806 Location longitude [deg]: -116.8064 Location altitude [m]: 564 Local noon date: 20250512 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0760 305.2167 305.3574 305.4980 305.6386 305.7793 305.9199 306.0605 306.2011 306.3416 306.4822 306.6228 306.7633 306.9039 307.0444 307.1849 307.3254 307.4659 307.6064 307.7468 307.8873 308.0277 308.1682 308.3086 308.4490 308.5894 308.7298 308.8702 309.0105 309.1509 309.2912 309.4316 309.5719 309.7122 309.8525 309.9928 310.1331 310.2734 310.4136 310.5539 310.6941 310.8343 310.9745 311.1147 311.2549 311.3951 311.5353 311.6754 311.8156 311.9557 312.0958 312.2359 312.3760 312.5161 312.6562 312.7963 312.9363 313.0764 313.2164 313.3564 313.4965 313.6365 313.7764 313.9164 314.0564 314.1964 314.3363 314.4762 314.6162 314.7561 314.8960 315.0359 315.1757 315.3156 315.4555 315.5953 315.7351 315.8750 316.0148 316.1546 316.2944 316.4342 316.5739 316.7137 316.8534 316.9932 317.1329 317.2726 317.4123 317.5520 317.6917 317.8313 317.9710 318.1106 318.2503 318.3899 318.5295 318.6691 318.8087 318.9483 319.0878 319.2274 319.3669 319.5065 319.6460 319.7855 319.9250 320.0645 320.2040 320.3435 320.4829 320.6224 320.7618 320.9012 321.0406 321.1800 321.3194 321.4588 321.5982 321.7375 321.8769 322.0162 322.1555 322.2948 322.4341 322.5734 322.7127 322.8520 322.9912 323.1305 323.2697 323.4089 323.5481 323.6873 323.8265 323.9657 324.1048 324.2440 324.3831 324.5223 324.6614 324.8005 324.9396 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250512T155540.8Z 9263.663666 317 1 10.31 2 54.25 101.21 130.27 278.96 0.00 1 0.00 1 0 25 2.273e-02 1.701e-02 1.193e-02 4.508e-03 3.062623e-01 2.320747e-03 4.042471e-03 -6.000000e+00 1.310617e-02 230.36 -2.00 3.63 -2.00 316.73 0.00e+00 -1.197717e-04 2.775360e-04 3.383438e-04 -6.000000e+00 5.530902e-04 276.81 -2.00 20.00 -2.00 316.17 0.00e+00 1.707 0.000 302.00 328.00 3 4.5819e+00 6.0687e-03 2.3417e-02 -6.0000e+00 3.2877e-02 7.9427e-02 6.7229e-03 1.6870e-02 -6.0000e+00 3.5429e-02 -2.1577e-02 4.0121e-03 8.2734e-03 -6.0000e+00 2.0960e-02 3.9305e-03 2.0121e-03 2.5133e-03 -6.0000e+00 9.1645e-03 6.9477e-04 -7.9795e-03 1.1938e-04 2.7878e-05 -6.0000e+00 5.8104e-04 -1.6231e-01 -1.0686e-04 12 9 9 12 5 1 999.00 24.52 0.41 -0.16231 -0.22227 2 2 1 5 0 3434.600 33.00 20.03 24.52 17.09 0.0 916.12 900000 4583 -5773 -1862 -8714 -3480 3427 -4039 -5673 769 -1365 -5335 -5385 -6670 -1896 202 -1660 4103 -4 1128 28 469 567 -2301 4871 3100 1171 -2561 -813 -686 -3786 900 1396 2406 1465 -2612 -3404 -1168 -715 69 775 153 992 433 -873 -1432 -283 -1717 -37 -515 -733 1864 1887 1643 1896 533 1730 1237 1837 -65 259 851 133 2751 2368 910 -84 -1587 -1859 253 799 471 549 328 516 305 -1119 -2294 -2803 -2200 -799 -1055 -310 -1026 -2363 -851 -104 -352 -30 603 150 264 -301 -22 -716 -194 114 207 1134 1460 -205 1241 -1190 -1566 -726 -1173 -1446 -1540 -771 -664 -70 733 170 410 1086 -269 -187 505 222 -731 -261 -386 -278 285 -140 12612 -17 -1481 221 750 -477 -100 -862 -187 -980 527 281 -583 688 -82 -704 -500 -1202 900000 540 -860 -282 -1390 -467 390 -509 -805 116 -230 -947 -944 -1299 -370 44 -425 1062 -1 327 8 147 176 -734 1530 1054 390 -911 -274 -231 -1249 296 497 846 565 -1016 -1229 -431 -298 34 423 89 605 275 -574 -942 -184 -1123 -23 -318 -449 1151 1261 1172 1333 399 1308 962 1436 -51 197 644 106 2340 2064 846 -75 -1315 -1569 210 692 464 543 332 509 303 -1024 -2015 -2276 -1751 -693 -980 -301 -1101 -2542 -949 -125 -425 -37 766 189 312 -345 -24 -737 -200 129 245 1409 1899 -278 1669 -1518 -1929 -854 -1411 -1889 -2093 -1035 -934 -98 1100 258 615 1605 -391 -249 671 302 -1006 -385 -571 -409 408 -205 16194 -24 -1977 277 972 -646 -144 -1249 -275 -1481 824 448 -974 1155 -136 -1162 -827 -1923 SS 20250512T162722.7Z 9263.685679 336 1 3.32 2 48.95 108.04 135.45 285.46 0.00 1 0.00 1 0 25 1.210e-02 7.567e-03 3.152e-03 1.830e-03 2.649333e-01 9.495267e-04 3.519737e-03 -6.000000e+00 6.969922e-03 230.36 -2.00 3.63 -2.00 315.64 0.00e+00 4.690984e-04 8.746478e-05 1.228913e-04 -6.000000e+00 2.944445e-04 276.82 -2.00 20.00 -2.00 315.11 0.00e+00 1.520 0.000 302.00 328.00 3 2.3732e+00 2.4542e-03 2.0505e-02 -6.0000e+00 1.7483e-02 2.8742e-02 2.7019e-03 1.4478e-02 -6.0000e+00 1.8847e-02 -7.3122e-03 1.5636e-03 7.1611e-03 -6.0000e+00 1.1151e-02 3.1468e-03 7.4102e-04 2.0299e-03 -6.0000e+00 4.8702e-03 8.1951e-03 -9.6057e-03 4.8314e-05 2.5285e-05 -6.0000e+00 3.0950e-04 -1.5830e-01 -2.6313e-04 12 9 1 12 5 1 59.56 24.52 0.28 -0.15830 -0.23048 8 15 1 5 0 367.920 33.00 19.97 24.52 18.70 0.0 924.65 900000 653 -961 988 -3185 -4474 -2889 -2074 -816 -1013 -882 -3109 -3910 -697 -496 3142 590 477 1303 411 2188 1011 428 880 2097 2199 1138 592 425 -1293 -481 1482 1507 1770 1050 -3168 -3698 -2206 -1528 -233 -104 -810 -1301 16 -107 -318 116 -792 -93 -812 -624 698 972 480 1325 450 276 1398 543 172 -127 224 1035 1307 1953 1246 -369 -126 -1167 -148 552 93 675 348 424 420 -359 -448 -1463 -1439 -955 -1486 -1108 -1948 -1809 -1409 -1029 17 143 563 815 261 837 -15 -1 -50 -11 -49 716 1135 433 -173 -649 -753 -513 -364 -1163 -808 -723 -242 449 626 904 802 579 245 -98 172 -175 188 311 69 -67 262 739 321 506 -261 -85 214 141 -82 -527 -374 -415 0 38 -174 172 203 -29 -150 -464 900000 150 -255 271 -833 -1121 -695 -469 -201 -281 -249 -903 -1120 -210 -161 1123 230 188 524 174 942 431 183 391 918 1016 554 283 207 -587 -216 675 701 843 545 -1659 -1788 -1094 -813 -139 -68 -560 -956 12 -79 -234 85 -582 -69 -588 -444 503 724 382 1063 369 231 1179 467 146 -106 187 900 1190 1797 1209 -346 -114 -1011 -131 505 91 682 362 430 417 -338 -400 -1252 -1246 -842 -1450 -1128 -2066 -2005 -1590 -1216 21 176 707 1010 314 964 -16 -1 -54 -12 -57 883 1463 565 -222 -797 -892 -601 -434 -1477 -1038 -948 -330 626 890 1309 1179 826 331 -128 218 -228 250 426 97 -94 371 1014 429 657 -333 -106 275 185 -112 -740 -534 -589 1 57 -268 268 319 -46 -231 -705 SS 20250512T165432.4Z 9263.704542 354 1 54.62 2 44.59 114.55 139.75 291.70 0.00 1 0.00 1 0 25 1.028e-02 7.215e-03 2.515e-04 1.543e-04 2.475998e-01 8.014874e-05 3.257906e-03 -6.000000e+00 5.932634e-03 230.36 -2.00 3.63 -2.00 315.42 0.00e+00 4.479042e-04 7.080410e-06 8.776655e-05 -6.000000e+00 2.501111e-04 276.82 -2.00 20.00 -2.00 314.91 0.00e+00 1.402 0.000 302.00 328.00 3 4.9906e-01 2.0678e-04 1.9032e-02 -6.0000e+00 1.4883e-02 1.3738e-02 2.2747e-04 1.3480e-02 -6.0000e+00 1.6034e-02 -5.6628e-03 1.3144e-04 6.6610e-03 -6.0000e+00 9.4860e-03 1.9106e-03 6.1641e-05 1.8768e-03 -6.0000e+00 4.1504e-03 6.1771e-02 -7.4600e-03 4.0814e-06 2.3232e-05 -6.0000e+00 2.6272e-04 -1.6144e-01 1.5345e-04 11 9 0 11 4 0 99.93 24.49 0.31 -0.16144 -0.21750 1947 193 1 5 0 28.050 33.00 20.03 24.49 19.59 0.0 928.77 900000 420 -524 180 -1693 -3465 -3163 -1983 -313 -49 -476 -2479 -2518 -1173 -652 530 861 338 989 1206 1668 1715 609 1470 1699 1370 870 675 -49 -632 -613 1155 1054 1668 611 -2556 -2933 -2620 -1660 -791 -153 -381 -594 -367 -397 -48 159 -281 -316 -712 -735 331 769 645 1030 773 905 942 424 163 168 400 1085 1285 1902 1181 -384 -507 -941 -120 553 263 576 347 562 326 -211 -638 -1554 -1312 -1059 -1462 -1234 -1902 -2130 -1351 -672 -79 142 721 938 643 442 -191 -121 -97 -159 -7 833 935 192 -160 -552 -702 -603 -321 -1078 -865 -728 -283 421 651 913 648 565 197 -19 105 -38 187 312 77 53 360 550 396 452 -416 216 331 109 -21 -393 -226 -420 -85 45 -185 287 245 7 -324 -657 900000 110 -146 53 -494 -975 -798 -502 -86 -14 -149 -799 -791 -391 -232 200 345 145 432 518 738 783 280 664 802 651 433 346 -24 -306 -279 530 520 835 318 -1331 -1475 -1363 -921 -471 -104 -273 -434 -277 -306 -37 121 -213 -232 -532 -539 246 587 505 845 643 765 812 359 141 142 339 928 1151 1777 1162 -365 -465 -818 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