File name: Pandora87s1_LapwaiID_20250816_L2Fit_fwvt1c2d20240715p1-8.txt File generation date: 20250817T075628.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Julie Simpson Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 87 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora87_OF_v3d20240227.txt Instrument calibration file used: Pandora87s1_CF_v2d20240715.txt Level 1 file used: Pandora87s1_LapwaiID_20250816_L1_smca1c2d20240715p1-8.txt Full location name: Nez Perce Tribe cell tower site near Lapwai Idaho Short location name: LapwaiID Country of location: United States Location latitude [deg]: 46.3806 Location longitude [deg]: -116.8064 Location altitude [m]: 564 Local noon date: 20250816 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 1620 1770 Nominal wavelengths inside fitting window [nm]: 492.0017 492.1225 492.2433 492.3641 492.4849 492.6056 492.7264 492.8471 492.9678 493.0885 493.2092 493.3299 493.4505 493.5711 493.6917 493.8123 493.9329 494.0535 494.1740 494.2945 494.4150 494.5355 494.6560 494.7765 494.8969 495.0173 495.1377 495.2581 495.3785 495.4989 495.6192 495.7395 495.8598 495.9801 496.1004 496.2207 496.3409 496.4611 496.5813 496.7015 496.8217 496.9418 497.0620 497.1821 497.3022 497.4223 497.5424 497.6624 497.7825 497.9025 498.0225 498.1425 498.2625 498.3824 498.5023 498.6223 498.7422 498.8621 498.9819 499.1018 499.2216 499.3414 499.4612 499.5810 499.7008 499.8205 499.9403 500.0600 500.1797 500.2994 500.4190 500.5387 500.6583 500.7779 500.8975 501.0171 501.1367 501.2562 501.3757 501.4953 501.6148 501.7342 501.8537 501.9731 502.0926 502.2120 502.3314 502.4508 502.5701 502.6895 502.8088 502.9281 503.0474 503.1667 503.2859 503.4052 503.5244 503.6436 503.7628 503.8820 504.0011 504.1202 504.2394 504.3585 504.4776 504.5966 504.7157 504.8347 504.9537 505.0727 505.1917 505.3107 505.4296 505.5486 505.6675 505.7864 505.9053 506.0241 506.1430 506.2618 506.3806 506.4994 506.6182 506.7370 506.8557 506.9744 507.0931 507.2118 507.3305 507.4492 507.5678 507.6864 507.8050 507.9236 508.0422 508.1608 508.2793 508.3978 508.5163 508.6348 508.7533 508.8717 508.9902 509.1086 509.2270 509.3454 509.4637 509.5821 509.7004 509.8187 509.9370 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250816T125549.9Z 9359.538771 190 1 7.11 2 89.53 70.68 24.43 151.31 0.00 1 0.00 1 0 22 8.796e-03 8.553e-03 2.587e-03 2.573e-03 3.909320e+04 2.091252e+02 2.362353e+03 -6.000000e+00 4.783268e+02 283.79 -2.00 20.00 -2.00 505.45 0.00e+00 3.491755e-03 7.154629e-05 2.818273e-04 -6.000000e+00 2.456303e-04 283.79 -2.00 20.00 -2.00 500.88 0.00e+00 1.992091e+00 5.053408e-02 2.202481e-01 -6.000000e+00 1.754672e-01 231.76 -2.00 3.63 -2.00 502.40 0.00e+00 19.713 0.154 489.00 513.00 1 4.2619e+00 3.8379e-03 3.8986e-02 -6.0000e+00 1.3378e-02 -8.0899e-02 9.8940e-04 5.8815e-03 -6.0000e+00 3.5875e-03 1.5341e-03 -8.9112e-03 1.7558e-04 2.3813e-04 -6.0000e+00 8.1651e-04 -2.9847e-02 -7.7951e-04 12 9 9 12 5 1 999.00 24.37 5.03 -0.02985 -0.09166 2 2 1 4 0 2369.560 33.00 19.98 24.37 27.87 0.0 962.55 900000 900000 -596 -144 814 1920 1784 1908 2136 1717 1765 877 1093 482 145 -744 -12 -495 -187 186 317 322 -108 291 617 -710 671 519 743 -71 -643 -1229 -1420 -920 -1156 -310 181 642 312 -538 -240 -918 -924 -580 -625 -38 46 10 -57 216 -212 -913 -1630 -1943 -1738 -1557 -1098 -50 -364 -443 262 538 349 -386 690 222 92 333 -5 -279 -432 -1228 -1093 -711 -553 317 477 -22 -266 -430 -37 -296 -195 102 447 590 652 17 169 -164 -202 245 736 1685 1660 1622 1276 940 797 804 -397 -1326 -2130 -2310 -1428 -1084 -1199 -425 -434 -496 -948 -682 -1111 -991 -473 -1036 34 523 1317 1266 771 99 -833 -433 -437 265 875 770 871 544 329 373 -584 -1145 -531 -589 -258 -710 -271 -89 339 519 800 329 263 770 1338 1318 1130 106 273 900000 900000 -520 -127 737 1746 1633 1787 2043 1629 1678 833 1051 462 137 -702 -11 -467 -178 177 310 312 -106 285 606 -711 669 522 747 -72 -638 -1186 -1383 -895 -1118 -309 182 654 317 -546 -241 -922 -930 -589 -629 -39 48 10 -60 223 -216 -921 -1649 -1922 -1695 -1523 -1097 -50 -376 -455 269 549 357 -401 716 232 96 342 -5 -287 -440 -1244 -1095 -712 -559 321 488 -22 -270 -428 -37 -291 -190 99 439 585 641 17 170 -164 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4.30 0.01816 -0.04183 107 11 1 4 0 511.510 33.00 20.01 24.36 27.80 0.0 962.36 900000 900000 -397 -61 656 1253 1432 1748 1850 1657 1202 906 769 435 -205 -496 -446 -269 -52 249 276 133 167 232 247 330 534 601 625 190 -684 -1283 -1211 -918 -621 -30 201 47 -326 -557 -701 -815 -709 -446 -210 66 154 190 82 34 -324 -853 -1431 -1684 -1640 -1268 -754 -355 -137 -2 72 60 148 361 429 405 150 -52 -136 -154 -472 -896 -921 -552 -217 19 53 -56 -129 -110 -161 -231 51 394 563 398 248 133 -141 -333 -228 228 812 1251 1325 1156 1132 1164 1164 715 -392 -1513 -1818 -1693 -1325 -1100 -961 -547 -311 -407 -591 -549 -677 -878 -848 -545 -88 447 1011 1121 723 76 -359 -507 -254 256 525 537 786 698 319 -34 -448 -806 -661 -638 -695 -668 -354 -97 380 540 401 365 455 708 1179 1220 1013 510 11 900000 900000 -350 -54 589 1168 1345 1640 1774 1615 1154 882 740 416 -195 -466 -417 -253 -49 238 271 130 164 230 245 329 537 596 620 189 -682 -1245 -1177 -893 -600 -29 204 47 -330 -558 -712 -824 -717 -446 -213 68 157 195 84 35 -335 -867 -1421 -1668 -1604 -1242 -754 -359 -140 -2 75 62 154 376 442 419 155 -54 -139 -157 -474 -910 -926 -555 -220 19 54 -57 -129 -110 -158 -228 50 385 554 388 246 131 -140 -330 -226 222 789 1224 1306 1129 1084 1074 1055 635 -343 -1320 -1588 -1479 -1190 -1040 -937 -548 -312 -409 -591 -550 -691 -893 -861 -559 -90 454 1020 1170 764 81 -376 -527 -255 259 533 541 800 719 330 -35 -457 -829 -669 -647 -713 -683 -372 -102 404 575 438 399 502 784 1296 1333 1100 550 12 SQ 20250816T130156.2Z 9359.543011 198 1 54.54 2 88.53 71.78 23.94 154.40 0.00 1 0.00 1 0 22 5.998e-03 5.865e-03 2.098e-04 2.091e-04 3.222362e+04 1.630838e+01 1.983917e+03 -6.000000e+00 3.261157e+02 283.79 -2.00 20.00 -2.00 505.40 0.00e+00 2.769082e-03 5.805789e-06 2.212295e-04 -6.000000e+00 1.675823e-04 283.79 -2.00 20.00 -2.00 500.76 0.00e+00 1.762993e+00 4.125312e-03 1.851351e-01 -6.000000e+00 1.197905e-01 231.76 -2.00 3.63 -2.00 502.30 0.00e+00 17.443 0.107 489.00 513.00 1 2.0954e+00 3.1341e-04 3.2040e-02 -6.0000e+00 9.1303e-03 -6.0116e-02 8.1349e-05 4.8856e-03 -6.0000e+00 2.4528e-03 1.8816e-02 -7.3801e-03 1.5008e-05 2.1354e-04 -6.0000e+00 5.5650e-04 1.0528e-02 -1.1319e-03 12 9 8 11 4 0 80.65 24.36 3.09 0.01053 -0.04066 242 24 1 4 0 225.350 33.00 20.00 24.36 27.78 0.0 962.25 900000 900000 -464 -106 453 916 1086 1365 1529 1289 931 618 547 240 -227 -486 -455 -355 -82 203 237 106 125 220 143 233 397 515 573 212 -598 -1065 -954 -679 -413 71 195 70 -164 -371 -570 -588 -538 -331 -122 119 240 250 141 37 -226 -679 -1178 -1390 -1276 -959 -569 -275 -139 -8 -1 46 147 307 367 308 177 39 -72 -96 -374 -725 -705 -425 -131 -1 37 -99 -111 -88 -191 -243 -93 226 336 222 119 57 -191 -341 -199 246 706 1072 1129 980 907 1011 1017 641 -338 -1266 -1516 -1269 -1060 -949 -823 -558 -273 -321 -442 -417 -468 -615 -567 -383 -45 477 897 926 576 46 -238 -335 -78 251 367 398 566 460 273 17 -402 -674 -522 -510 -596 -532 -337 -85 299 412 306 222 352 574 928 1046 767 327 -59 900000 900000 -416 -96 416 857 1030 1323 1487 1253 910 600 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