File name: Pandora143s1_LibertyTX_20210602_L2Fit_fout2c12d20210527p1-8.txt File generation date: 20250128T105346.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c12p1-8 Local principal investigator: Yuxuan Wang Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 143 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora143_OF_v2d20210326.txt Instrument calibration file used: Pandora143s1_CF_v12d20210527.txt Level 1 file used: Pandora143s1_LibertyTX_20210602_L1_smca1c12d20210527p1-8.txt Full location name: University of Houston Trailer Short location name: LibertyTX Country of location: United States Location latitude [deg]: 30.0965 Location longitude [deg]: -94.7635 Location altitude [m]: 3 Local noon date: 20210602 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.0723 305.2131 305.3540 305.4948 305.6356 305.7764 305.9172 306.0580 306.1988 306.3395 306.4803 306.6210 306.7617 306.9024 307.0431 307.1838 307.3245 307.4651 307.6058 307.7464 307.8870 308.0276 308.1682 308.3088 308.4494 308.5899 308.7305 308.8710 309.0115 309.1520 309.2925 309.4330 309.5735 309.7139 309.8544 309.9948 310.1352 310.2756 310.4160 310.5564 310.6967 310.8371 310.9774 311.1178 311.2581 311.3984 311.5387 311.6789 311.8192 311.9595 312.0997 312.2399 312.3801 312.5203 312.6605 312.8007 312.9409 313.0810 313.2211 313.3613 313.5014 313.6415 313.7816 313.9216 314.0617 314.2017 314.3418 314.4818 314.6218 314.7618 314.9018 315.0418 315.1817 315.3217 315.4616 315.6015 315.7414 315.8813 316.0212 316.1611 316.3010 316.4408 316.5806 316.7205 316.8603 317.0001 317.1398 317.2796 317.4194 317.5591 317.6988 317.8386 317.9783 318.1180 318.2577 318.3973 318.5370 318.6766 318.8163 318.9559 319.0955 319.2351 319.3747 319.5142 319.6538 319.7933 319.9329 320.0724 320.2119 320.3514 320.4909 320.6303 320.7698 320.9092 321.0487 321.1881 321.3275 321.4669 321.6063 321.7456 321.8850 322.0243 322.1637 322.3030 322.4423 322.5816 322.7209 322.8602 322.9994 323.1387 323.2779 323.4171 323.5563 323.6955 323.8347 323.9739 324.1130 324.2522 324.3913 324.5304 324.6695 324.8086 324.9477 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210602T124524.8Z 7823.531538 175 1 35.49 2 73.23 73.59 41.57 179.55 0.00 1 0.00 1 0 17 1.197e-01 1.091e-02 5.761e-02 4.247e-03 4.517503e-01 2.127868e-03 4.850547e-03 -6.000000e+00 6.750978e-02 231.07 -2.00 3.25 -2.00 319.37 0.00e+00 -1.718514e-03 4.915730e-04 1.782307e-04 -6.000000e+00 2.682165e-03 291.49 -2.00 20.00 -2.00 319.04 0.00e+00 3.412 0.000 302.00 328.00 3 4.9084e+00 5.8652e-03 4.0607e-02 -6.0000e+00 1.7046e-01 1.7289e-02 6.7576e-03 2.1917e-02 -6.0000e+00 1.8551e-01 -8.2702e-03 5.6697e-03 1.1032e-02 -6.0000e+00 1.0876e-01 -5.6389e-03 3.0631e-03 3.2565e-03 -6.0000e+00 4.5345e-02 7.5929e-05 -4.6410e-04 1.1538e-04 3.1227e-05 -6.0000e+00 3.0216e-03 -8.3711e-03 -1.0448e-04 12 8 8 10 0 0 -14.96 24.14 0.28 -0.00837 -0.01186 10 7 4 8 0 3548.470 20.00 24.14 31.39 27.35 27.35 12.4 890.92 -16607 -14428 -4334 -21623 -20600 -47778 36271 13465 4257 -66337 -59557 4540 -35477 -2608 4829 7742 25749 -14066 30008 1693 -19369 30518 710 25138 -1842 6340 -1568 2109 -9838 14045 7714 18749 -1683 724 -7803 -8257 -1582 3031 -1376 5832 -5752 -2161 3841 1900 3040 4846 -6012 -2893 -4044 263 -1484 2058 5960 41 3782 1494 -729 1656 -5714 2004 1069 -368 -1075 -971 1160 1042 -624 -388 -1456 -18 1540 1285 3338 -995 1368 -485 2756 3414 -1671 1489 -1337 -2912 1759 543 -175 -944 -56 -505 -175 1894 -934 -225 -1821 -344 -808 -1348 827 -188 1322 -748 -750 -428 -1471 -293 -843 -907 -1067 -608 1163 -34 833 368 369 -415 15 -29 37 -348 -479 -136 254 157 870 411 913 91 693 138 -43 570 264 430 -79 252 410 -453 -93 -164 155 -664 -132 -153 -297 -352 -337 -97 -542 -462 -1361 521 278 110 -3547 -3036 136 -1812 -117 239 423 1281 -1086 1632 126 -1805 1788 58 1779 -182 618 -166 204 -1011 1176 764 1898 -231 102 -1127 -1174 -233 506 -292 1363 -1645 -632 1105 561 891 1409 -1920 -900 -1283 83 -516 757 2271 17 1637 683 -349 775 -2776 901 497 -185 -598 -586 703 600 -349 -217 -883 -13 1115 966 2461 -731 927 -305 1571 1896 -1030 1011 -1039 -2515 1556 503 -172 -986 -60 -560 -193 2011 -957 -216 -1680 -313 -787 -1447 955 -238 1754 -1004 -960 -509 -1667 -336 -1033 -1157 -1409 -832 1645 -52 1327 603 599 -652 23 -42 53 -515 -744 -219 412 250 1350 626 1341 132 958 194 -65 911 442 742 -140 458 776 -896 -186 -332 315 -1333 -256 -288 -547 SS 20210602T125227.1Z 7823.536424 177 1 33.75 2 71.77 74.34 41.57 182.11 0.00 1 0.00 1 0 25 8.489e-02 1.063e-02 3.479e-02 3.711e-03 4.209636e-01 1.852214e-03 4.567271e-03 -6.000000e+00 4.788666e-02 231.07 -2.00 3.25 -2.00 319.01 0.00e+00 -6.932834e-04 3.854718e-04 1.453762e-04 -6.000000e+00 1.902265e-03 291.49 -2.00 20.00 -2.00 318.68 0.00e+00 3.154 0.000 302.00 328.00 3 4.9208e+00 5.0619e-03 3.7641e-02 -6.0000e+00 1.2091e-01 2.0689e-02 5.7527e-03 2.0398e-02 -6.0000e+00 1.3158e-01 -1.8180e-02 4.4402e-03 1.0162e-02 -6.0000e+00 7.7140e-02 2.5572e-03 2.3944e-03 2.9534e-03 -6.0000e+00 3.2166e-02 9.9306e-05 -3.5304e-04 1.0085e-04 2.8587e-05 -6.0000e+00 2.1426e-03 -7.8055e-03 -2.9745e-05 12 8 8 10 0 0 -22.64 24.15 0.32 -0.00781 -0.01046 11 8 4 8 0 3067.320 20.01 24.15 32.23 27.35 27.35 12.4 895.61 -39726 -12354 24435 -24132 2405 -42609 -15058 -16267 -3626 -47982 -1311 7271 -30028 1231 -4067 2627 1847 -8720 8754 2186 -12332 12775 6625 10107 1040 12000 -3310 7592 -3229 5586 3022 7073 1876 1748 963 -11035 -5058 1160 1339 -2394 -2294 220 71 2506 1485 2596 -2598 -2674 -2706 -1753 -604 28 4115 458 2062 2707 -1652 2411 -4995 2073 901 126 515 -494 2334 2137 -342 -157 -1369 -1196 1959 581 2127 172 883 -746 753 1307 -1465 519 -827 -1281 557 -1100 -1055 -595 85 593 -10 1130 297 -186 -1280 -372 -855 -1150 949 1044 641 -455 -1095 -532 -1527 -370 -1279 -1527 -554 -1235 854 -42 937 753 238 4 -151 -448 -188 -158 -283 93 -50 206 795 892 142 332 877 349 527 -46 482 151 814 477 1417 -2545 429 -3 219 -812 -239 -20 -439 -1531 -413 608 -899 63 -1654 -492 -619 -139 -2987 -53 288 -1969 72 -293 201 152 -847 765 212 -1406 1151 657 1053 127 1395 -447 881 -391 633 389 986 305 299 156 -1951 -930 236 329 -710 -746 74 25 861 515 899 -935 -965 -979 -647 -237 12 1791 218 1008 1355 -881 1241 -2673 1033 465 70 311 -324 1522 1327 -207 -95 -888 -872 1498 466 1685 133 641 -503 467 787 -957 374 -669 -1138 516 -1070 -1079 -638 95 673 -11 1245 312 -185 -1217 -348 -854 -1255 1110 1326 860 -612 -1415 -641 -1759 -429 -1588 -1982 -736 -1707 1214 -63 1487 1223 383 7 -223 -637 -266 -231 -433 148 -81 325 1226 1343 209 474 1202 484 776 -73 790 255 1389 842 2590 -4929 828 -5 432 -1580 -451 -37 -786 SS 20210602T130639.8Z 7823.546294 179 1 35.78 2 68.80 75.83 41.77 187.26 0.00 1 0.00 1 0 25 3.970e-02 7.579e-03 1.489e-02 2.665e-03 3.634210e-01 1.326740e-03 3.972001e-03 -6.000000e+00 2.238970e-02 231.07 -2.00 3.25 -2.00 318.32 0.00e+00 -1.047984e-04 2.260147e-04 9.936559e-05 -6.000000e+00 8.894954e-04 291.49 -2.00 20.00 -2.00 317.99 0.00e+00 2.739 0.000 302.00 328.00 3 4.8874e+00 3.5757e-03 3.2595e-02 -6.0000e+00 5.6533e-02 6.4646e-04 4.0179e-03 1.7534e-02 -6.0000e+00 6.1522e-02 -1.1947e-02 2.7451e-03 8.6505e-03 -6.0000e+00 3.6068e-02 1.5533e-03 1.4481e-03 2.4734e-03 -6.0000e+00 1.5039e-02 1.6678e-04 -2.8633e-04 7.2389e-05 2.4078e-05 -6.0000e+00 1.0020e-03 -8.1427e-03 -7.1018e-05 11 8 0 10 0 0 51.97 24.15 0.29 -0.00814 -0.01029 15 11 4 8 0 2366.940 19.99 24.15 33.72 27.35 27.35 12.3 903.71 -16150 -6939 -9152 -7992 -15835 -13052 -5655 -12134 -5360 -25030 -2248 -7993 -6219 -2273 5900 -1292 2820 -4290 4352 4663 -2958 6263 502 -386 817 2983 -1706 -1344 -1888 1970 -79 3885 -198 436 -1334 -5701 -2483 -1078 1786 -1079 -1248 1337 216 2 624 2288 -1987 -867 -1400 -931 1312 2094 2517 -49 1293 1260 -232 1766 -2862 2322 740 1149 1002 304 1076 258 -520 -86 -251 -605 1282 957 723 -216 25 -7 337 -830 -1313 21 -1276 -1790 -840 -652 -639 -323 -538 172 -35 1093 -93 -340 -545 -973 -355 -764 652 503 870 -273 -352 -716 -1249 -361 -356 -767 -403 -572 369 241 797 641 496 39 211 -345 -288 -56 -137 39 -243 308 484 576 200 236 413 194 689 200 191 -9 279 249 943 -1889 360 -37 236 -369 -321 27 -470 -920 -402 -560 -459 -878 -684 -298 -776 -364 -2155 -157 -613 -538 -223 623 -163 363 -622 611 683 -474 917 80 -67 149 558 -333 -248 -330 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