File name: Pandora143s1_LibertyTX_20210612_L2Fit_fout2c12d20210527p1-8.txt File generation date: 20250128T105558.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c12p1-8 Local principal investigator: Yuxuan Wang Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 143 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora143_OF_v2d20210326.txt Instrument calibration file used: Pandora143s1_CF_v12d20210527.txt Level 1 file used: Pandora143s1_LibertyTX_20210612_L1_smca1c12d20210527p1-8.txt Full location name: University of Houston Trailer Short location name: LibertyTX Country of location: United States Location latitude [deg]: 30.0965 Location longitude [deg]: -94.7635 Location altitude [m]: 3 Local noon date: 20210612 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.0723 305.2131 305.3540 305.4948 305.6356 305.7764 305.9172 306.0580 306.1988 306.3395 306.4803 306.6210 306.7617 306.9024 307.0431 307.1838 307.3245 307.4651 307.6058 307.7464 307.8870 308.0276 308.1682 308.3088 308.4494 308.5899 308.7305 308.8710 309.0115 309.1520 309.2925 309.4330 309.5735 309.7139 309.8544 309.9948 310.1352 310.2756 310.4160 310.5564 310.6967 310.8371 310.9774 311.1178 311.2581 311.3984 311.5387 311.6789 311.8192 311.9595 312.0997 312.2399 312.3801 312.5203 312.6605 312.8007 312.9409 313.0810 313.2211 313.3613 313.5014 313.6415 313.7816 313.9216 314.0617 314.2017 314.3418 314.4818 314.6218 314.7618 314.9018 315.0418 315.1817 315.3217 315.4616 315.6015 315.7414 315.8813 316.0212 316.1611 316.3010 316.4408 316.5806 316.7205 316.8603 317.0001 317.1398 317.2796 317.4194 317.5591 317.6988 317.8386 317.9783 318.1180 318.2577 318.3973 318.5370 318.6766 318.8163 318.9559 319.0955 319.2351 319.3747 319.5142 319.6538 319.7933 319.9329 320.0724 320.2119 320.3514 320.4909 320.6303 320.7698 320.9092 321.0487 321.1881 321.3275 321.4669 321.6063 321.7456 321.8850 322.0243 322.1637 322.3030 322.4423 322.5816 322.7209 322.8602 322.9994 323.1387 323.2779 323.4171 323.5563 323.6955 323.8347 323.9739 324.1130 324.2522 324.3913 324.5304 324.6695 324.8086 324.9477 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210612T121911.5Z 7833.513328 37 1 36.01 2 78.58 69.69 97.48 55.32 0.00 1 0.00 1 0 25 7.338e-01 9.052e-02 3.108e-01 2.440e-02 6.314001e-01 1.343926e-02 6.480290e-03 -6.000000e+00 4.294214e-01 231.07 -2.00 3.25 -2.00 320.99 0.00e+00 -8.369024e-03 4.433256e-03 4.138855e-04 -6.000000e+00 1.848550e-02 292.32 -2.00 20.00 -2.00 320.63 0.00e+00 4.878 0.001 302.00 328.00 3 5.5871e+00 3.9767e-02 5.7659e-02 -6.0000e+00 1.0886e+00 4.8273e-01 4.8735e-02 3.0828e-02 -6.0000e+00 1.1911e+00 -5.7149e-01 4.4618e-02 1.6180e-02 -6.0000e+00 6.9003e-01 2.1248e-01 2.3114e-02 5.1080e-03 -6.0000e+00 2.8550e-01 7.0501e-06 2.5891e-04 7.1716e-04 5.5872e-05 -6.0000e+00 1.9629e-02 -6.2465e-03 -1.4263e-04 12 8 8 10 0 0 45.57 24.10 1.23 -0.00625 -0.00430 9 6 2 8 0 4000.000 20.00 24.10 32.22 27.35 27.35 12.9 895.38 -136954 900000 -88353 213986 483340 900000 900000 900000 -38633 -136895 -129780 900000 900000 900000 6443 900000 900000 -64704 900000 -16153 -4560 900000 235929 6220 900000 22100 157179 98494 -36900 900000 30351 900000 49272 165461 74436 14939 900000 99988 32088 19097 29071 6344 17230 4521 114801 154222 -16488 56132 3887 17406 121130 68884 221042 14245 56151 8682 7870 105898 47068 84610 12329 14646 16867 -38456 61163 30617 16743 4507 1679 -31342 48921 9484 46876 1930 17743 -20814 67358 47378 20333 54670 -13179 -29604 40594 16476 19488 4064 -10560 7070 -16069 10600 -7096 11618 -4174 -2590 -1573 -19405 4766 3435 14925 -4806 -1550 4483 -10673 -5214 -5722 -3300 426 -3781 1699 -3339 1396 2022 -6917 -238 7905 -5065 6448 2595 -2052 674 7468 60 3149 2128 1856 2157 834 5147 2278 -3067 -326 -2317 11111 3514 18608 -15695 746 -667 575 -4460 -2045 3502 2552 -8438 900000 -3753 5076 11466 900000 900000 900000 -1219 -11664 -10470 900000 900000 900000 236 900000 900000 -5730 900000 -965 -244 900000 5597 353 900000 1259 3729 2441 -2989 900000 1492 900000 2584 3925 2963 1016 900000 4023 2989 2377 3644 1027 2562 742 6599 6067 -3119 5443 624 2596 7598 7756 6495 3098 8736 2191 2071 11088 8090 9896 2832 3549 4460 -18741 12149 7707 4687 1444 610 -17792 14358 4159 14302 844 6097 -9142 12187 10327 6281 14277 -7452 -22034 17115 9133 11174 2862 -8885 5166 -14435 7173 -5263 6803 -2713 -1703 -1137 -18844 4198 3468 14643 -5611 -1643 4066 -10272 -4879 -5822 -3461 452 -4434 2051 -4679 2058 3113 -11482 -360 10533 -7264 8361 3653 -3188 1066 11026 91 4519 2995 2523 2821 1059 6512 3304 -5182 -583 -4442 19613 6998 34649 -41195 1724 -1585 1354 -10586 -4513 6956 4952 SS 20210612T123922.0Z 7833.527338 45 1 36.01 2 74.46 71.88 93.98 57.96 0.00 1 0.00 1 0 17 1.745e-01 1.616e-02 1.007e-01 5.276e-03 4.627775e-01 2.653461e-03 4.889990e-03 -6.000000e+00 9.840052e-02 231.07 -2.00 3.25 -2.00 319.63 0.00e+00 -8.953124e-04 6.554683e-04 2.010217e-04 -6.000000e+00 3.909276e-03 292.32 -2.00 20.00 -2.00 319.31 0.00e+00 3.663 0.001 302.00 328.00 3 4.9978e+00 7.3738e-03 4.2927e-02 -6.0000e+00 2.4846e-01 1.6152e-02 8.5701e-03 2.2376e-02 -6.0000e+00 2.7039e-01 -1.1843e-02 7.4808e-03 1.1310e-02 -6.0000e+00 1.5852e-01 2.8814e-03 4.0247e-03 3.3724e-03 -6.0000e+00 6.6090e-02 5.3893e-05 -5.5263e-04 1.4502e-04 3.1866e-05 -6.0000e+00 4.4036e-03 -7.0105e-03 -3.8309e-05 12 8 8 10 0 0 54.25 24.10 0.38 -0.00701 -0.01116 9 6 2 8 0 4000.000 20.00 24.10 33.93 27.35 27.35 13.1 907.06 -62822 24676 45467 -59413 -85331 -11948 78495 -36634 -54780 -43746 -53128 54933 15991 13111 5572 -12579 -12672 -5144 27034 -3825 -18157 14715 10934 31636 10523 -13632 2060 7384 -8552 26412 -2712 6718 -14573 79 -1420 -6377 6622 1043 -201 -3494 -1088 -2352 -3580 -3611 5926 6307 -1640 -6947 -2835 -1238 4437 3434 13576 329 4761 551 -3164 5110 -11303 5118 1420 1074 1954 -2163 5794 1124 288 -1823 -1942 -2489 3263 2009 3966 710 1288 -958 5695 1799 970 2913 -3464 -5567 2456 -235 400 -1505 -1342 352 -997 1563 -384 1691 440 -429 -2036 -1723 201 1037 1026 -1111 -552 -492 -3300 -1384 -916 -168 -505 -982 752 144 1010 88 -49 -557 -328 -977 -319 579 -534 187 1168 479 1013 1232 519 251 667 912 -297 -758 -938 -341 627 -689 1468 3646 -588 202 -968 -961 -879 -116 -767 -1671 326 521 -1749 -2892 -201 614 -983 -1994 -1544 -2085 841 416 422 228 -698 -760 -310 1283 -255 -1423 849 682 1784 783 -1349 178 577 -739 1681 -254 655 -1957 10 -168 -778 786 154 -37 -777 -262 -606 -969 -992 1495 1605 -450 -2003 -799 -357 1315 1129 4365 128 1859 230 -1410 2118 -5269 2044 600 492 980 -1220 3142 602 149 -961 -1108 -1617 2195 1417 2749 487 822 -569 2956 947 552 1857 -2617 -4714 2083 -211 379 -1530 -1421 379 -1084 1623 -382 1554 387 -378 -1954 -1817 230 1294 1359 -1486 -701 -580 -3747 -1577 -1111 -211 -660 -1339 1066 219 1618 147 -80 -886 -494 -1417 -461 860 -838 305 1902 769 1582 1880 770 363 925 1274 -449 -1236 -1609 -602 1123 -1285 2821 7174 -1207 420 -2035 -1979 -1748 -223 -1442 SS 20210612T124803.0Z 7833.533368 48 1 33.53 2 72.67 72.80 92.43 59.05 0.00 1 0.00 1 0 17 1.152e-01 1.187e-02 4.417e-02 4.322e-03 4.345876e-01 2.163524e-03 4.700122e-03 -6.000000e+00 6.496187e-02 231.07 -2.00 3.25 -2.00 319.18 0.00e+00 7.290112e-05 4.679379e-04 1.564360e-04 -6.000000e+00 2.581228e-03 292.32 -2.00 20.00 -2.00 318.85 0.00e+00 3.308 0.000 302.00 328.00 3 4.9968e+00 5.9277e-03 3.9265e-02 -6.0000e+00 1.6403e-01 4.5165e-02 6.7620e-03 2.1067e-02 -6.0000e+00 1.7852e-01 -3.9055e-02 5.3273e-03 1.0525e-02 -6.0000e+00 1.0466e-01 1.2550e-02 2.8706e-03 3.0729e-03 -6.0000e+00 4.3625e-02 7.7433e-05 -1.0199e-03 1.1791e-04 2.9624e-05 -6.0000e+00 2.9086e-03 -6.6414e-03 -1.0797e-04 12 9 8 11 8 0 44.35 24.10 0.41 -0.00664 -0.01431 9 7 2 8 0 3725.400 20.00 24.10 34.93 27.35 27.35 13.1 913.96 -54289 17795 -9332 -16917 -51862 -32722 27901 -33679 -33362 -49237 -43323 14337 -27940 10965 8976 -1195 -11853 -17420 11315 -6193 -878 15150 3411 9711 -1441 -3503 -1969 4779 -7309 20085 1401 10401 -1446 -4803 -1744 -11400 4290 2614 3641 -881 197 1151 189 -36 133 8578 -3740 -5115 -1160 -2788 4162 3136 6899 2606 1200 1998 -488 2011 -6144 1610 -552 -552 3040 -164 4019 -56 281 164 96 -3605 1575 1062 3684 -572 1501 -2406 3513 -193 -934 3130 -2745 -3805 686 -50 762 -1542 -845 -353 -282 884 -563 182 -175 -189 -730 -780 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