File name: Pandora143s1_LibertyTX_20210621_L2Fit_fout2c12d20210527p1-8.txt File generation date: 20250128T105740.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c12p1-8 Local principal investigator: Yuxuan Wang Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 143 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora143_OF_v2d20210326.txt Instrument calibration file used: Pandora143s1_CF_v12d20210527.txt Level 1 file used: Pandora143s1_LibertyTX_20210621_L1_smca1c12d20210527p1-8.txt Full location name: University of Houston Trailer Short location name: LibertyTX Country of location: United States Location latitude [deg]: 30.0965 Location longitude [deg]: -94.7635 Location altitude [m]: 3 Local noon date: 20210621 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.0723 305.2131 305.3540 305.4948 305.6356 305.7764 305.9172 306.0580 306.1988 306.3395 306.4803 306.6210 306.7617 306.9024 307.0431 307.1838 307.3245 307.4651 307.6058 307.7464 307.8870 308.0276 308.1682 308.3088 308.4494 308.5899 308.7305 308.8710 309.0115 309.1520 309.2925 309.4330 309.5735 309.7139 309.8544 309.9948 310.1352 310.2756 310.4160 310.5564 310.6967 310.8371 310.9774 311.1178 311.2581 311.3984 311.5387 311.6789 311.8192 311.9595 312.0997 312.2399 312.3801 312.5203 312.6605 312.8007 312.9409 313.0810 313.2211 313.3613 313.5014 313.6415 313.7816 313.9216 314.0617 314.2017 314.3418 314.4818 314.6218 314.7618 314.9018 315.0418 315.1817 315.3217 315.4616 315.6015 315.7414 315.8813 316.0212 316.1611 316.3010 316.4408 316.5806 316.7205 316.8603 317.0001 317.1398 317.2796 317.4194 317.5591 317.6988 317.8386 317.9783 318.1180 318.2577 318.3973 318.5370 318.6766 318.8163 318.9559 319.0955 319.2351 319.3747 319.5142 319.6538 319.7933 319.9329 320.0724 320.2119 320.3514 320.4909 320.6303 320.7698 320.9092 321.0487 321.1881 321.3275 321.4669 321.6063 321.7456 321.8850 322.0243 322.1637 322.3030 322.4423 322.5816 322.7209 322.8602 322.9994 323.1387 323.2779 323.4171 323.5563 323.6955 323.8347 323.9739 324.1130 324.2522 324.3913 324.5304 324.6695 324.8086 324.9477 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210621T125333.1Z 7842.537189 125 1 34.40 2 71.82 72.93 144.83 288.58 0.00 1 0.00 1 0 25 6.903e-02 7.821e-03 2.480e-02 3.026e-03 4.015159e-01 1.508409e-03 4.356303e-03 -6.000000e+00 3.890742e-02 230.91 -2.00 3.25 -2.00 318.79 0.00e+00 3.678858e-04 2.959291e-04 1.302405e-04 -6.000000e+00 1.546738e-03 292.90 -2.00 20.00 -2.00 318.47 0.00e+00 3.163 0.000 302.00 328.00 3 4.5823e+00 4.1009e-03 3.7134e-02 -6.0000e+00 9.8201e-02 2.5291e-02 4.6399e-03 1.9412e-02 -6.0000e+00 1.0688e-01 -1.0864e-02 3.4448e-03 9.6293e-03 -6.0000e+00 6.2671e-02 4.5555e-04 1.8515e-03 2.7850e-03 -6.0000e+00 2.6137e-02 1.4124e-04 -4.4537e-04 8.2073e-05 2.6913e-05 -6.0000e+00 1.7424e-03 -7.7449e-03 -8.7431e-05 11 8 0 10 0 0 97.06 24.05 0.31 -0.00774 -0.01109 16 12 2 8 0 2149.010 20.01 24.05 33.67 27.26 27.35 13.5 904.65 -44241 16024 -27803 5 10150 -26812 -2476 -12006 -19685 -12926 -24752 16552 -8642 6729 -3167 9317 4876 -9682 11791 -4709 1388 11086 -879 4238 -3133 10464 -7319 25 40 -1033 748 1004 4947 -1309 603 -12125 -4365 82 -1129 -90 -1358 140 -68 -620 1158 535 -302 -1968 -1056 -231 791 2286 2070 922 2654 195 -370 1261 979 -145 -143 1597 1458 666 366 649 -622 -658 122 -739 1406 729 856 125 790 -588 640 -438 -63 1281 -1670 -2053 -607 -1139 -644 -1344 -205 -170 793 1301 -602 832 -1227 443 -682 -532 326 426 702 -624 -147 -87 -1391 -679 -602 -461 -1058 -391 91 772 574 610 577 -281 -364 -654 117 -32 -493 133 -12 266 535 430 -257 288 811 634 385 -104 -23 302 505 681 -104 -593 313 230 11 -321 -399 -378 -501 -2145 497 -1356 0 297 -1077 -86 -521 -1035 -678 -1452 699 -541 433 -263 778 452 -1094 1156 -562 161 1165 -106 529 -448 1385 -1150 3 5 -140 110 166 874 -256 109 -2409 -882 19 -311 -28 -474 51 -25 -237 437 205 -116 -764 -408 -91 330 1021 980 466 1370 105 -205 689 526 -78 -79 928 923 454 254 427 -394 -415 82 -556 1118 602 705 100 594 -411 413 -278 -42 948 -1397 -1875 -579 -1128 -669 -1475 -232 -196 913 1457 -648 835 -1183 419 -688 -582 387 547 944 -843 -190 -105 -1608 -797 -750 -596 -1415 -539 131 1165 908 984 919 -433 -534 -926 164 -46 -750 210 -19 418 820 646 -375 408 1107 873 562 -163 -37 502 851 1179 -188 -1116 594 442 21 -613 -740 -681 -887 SS 20210621T131402.2Z 7842.551415 129 1 43.87 2 67.56 75.05 148.81 293.23 0.00 1 0.00 1 0 17 1.494e-02 5.156e-03 4.755e-03 1.192e-03 3.314463e-01 5.933810e-04 3.642288e-03 -6.000000e+00 8.422619e-03 230.90 -2.00 3.25 -2.00 317.70 0.00e+00 3.006492e-04 8.527341e-05 7.430896e-05 -6.000000e+00 3.347032e-04 292.90 -2.00 20.00 -2.00 317.37 0.00e+00 2.598 0.000 302.00 328.00 3 3.7815e+00 1.5821e-03 3.0521e-02 -6.0000e+00 2.1259e-02 -1.7156e-03 1.7681e-03 1.5944e-02 -6.0000e+00 2.3134e-02 1.3122e-03 1.1196e-03 7.8175e-03 -6.0000e+00 1.3565e-02 -2.1810e-03 5.7312e-04 2.2144e-03 -6.0000e+00 5.6599e-03 6.0278e-04 -1.3493e-04 3.2170e-05 2.1857e-05 -6.0000e+00 3.7692e-04 -9.5942e-03 -1.9247e-05 10 0 0 10 0 0 99.94 24.05 0.24 -0.00959 -0.01061 56 20 2 8 0 783.150 20.00 24.05 34.80 27.26 27.35 13.6 912.60 -6048 -3684 -2939 -4685 -7330 -4689 -4168 1961 -3922 -4371 -2013 -436 -3091 -300 9 -561 195 365 1507 1388 705 2060 363 361 170 754 -701 11 -670 -61 1023 1541 1391 -75 -1919 -3734 -2721 -1293 -309 -469 -383 -660 -364 -338 138 276 -413 -497 -848 -553 631 669 1178 804 1104 1004 403 512 -720 406 512 896 1509 1753 547 210 -527 -613 457 481 620 330 598 537 124 -191 -235 -723 -359 -487 -1000 -1326 -1389 -1487 -761 -721 -204 167 93 611 358 288 -156 -221 11 31 268 531 402 -169 -417 -635 -890 -409 -464 -512 -721 -585 40 172 558 551 362 109 -249 -150 -227 95 85 8 -27 3 502 382 441 165 336 451 397 304 180 171 -127 97 171 -230 119 79 123 -137 -279 -358 -661 -488 -323 -265 -406 -576 -344 -327 166 -399 -474 -211 -47 -363 -40 1 -99 36 71 307 295 155 441 81 81 41 188 -178 3 -150 -14 244 406 407 -23 -561 -1081 -856 -443 -128 -215 -194 -331 -188 -177 72 144 -215 -255 -433 -285 345 398 703 512 727 679 282 356 -494 273 354 633 1167 1393 445 167 -392 -447 355 410 553 308 556 480 108 -158 -176 -519 -272 -402 -900 -1274 -1434 -1537 -837 -818 -243 206 114 724 411 302 -157 -217 12 35 323 686 538 -225 -540 -781 -1023 -482 -576 -673 -954 -813 57 250 868 847 561 158 -346 -203 -306 134 123 12 -41 4 757 555 632 226 453 607 558 448 273 267 -203 155 283 -404 206 141 220 -239 -484 -595 -1106 SS 20210621T132037.2Z 7842.555987 133 1 51.48 2 66.19 75.72 150.05 294.91 0.00 1 0.00 1 0 17 1.128e-02 5.191e-03 1.608e-03 4.892e-04 3.146189e-01 2.443735e-04 3.487029e-03 -6.000000e+00 6.359843e-03 230.90 -2.00 3.25 -2.00 317.30 0.00e+00 3.182637e-04 3.157928e-05 6.074763e-05 -6.000000e+00 2.527427e-04 292.90 -2.00 20.00 -2.00 316.97 0.00e+00 2.458 0.000 302.00 328.00 3 2.3563e+00 6.4837e-04 2.8920e-02 -6.0000e+00 1.6052e-02 -1.2231e-02 7.2285e-04 1.5163e-02 -6.0000e+00 1.7469e-02 -4.5647e-03 4.4269e-04 7.4205e-03 -6.0000e+00 1.0243e-02 1.4134e-03 2.2164e-04 2.0903e-03 -6.0000e+00 4.2736e-03 2.9628e-03 -3.1061e-04 1.3189e-05 2.1708e-05 -6.0000e+00 2.8463e-04 -9.7536e-03 -3.8021e-05 10 0 0 10 0 0 99.08 24.05 0.24 -0.00975 -0.01209 285 56 1 8 0 175.080 20.00 24.05 35.23 27.26 27.35 13.7 915.82 -3241 -442 -1977 -2851 -5158 -4216 -3571 -249 -1140 -2927 -2668 -3235 -2338 -409 -109 351 -294 137 532 870 825 689 751 831 659 620 290 -252 -937 -88 450 1434 987 82 -1647 -2807 -2056 -1251 -456 -483 -622 -453 -527 -335 74 -25 -199 -494 -827 -269 410 763 945 1032 974 853 774 605 155 450 725 1119 1541 1647 865 15 -505 -484 229 499 470 376 365 263 75 -48 -411 -881 -824 -797 -809 -1127 -1646 -1660 -1204 -544 -348 -87 267 541 300 78 -41 3 124 224 269 669 332 -9 -354 -530 -608 -298 -522 -484 -616 -434 -87 256 539 523 275 82 -299 -61 -74 7 -31 36 -150 9 230 315 405 410 406 515 546 485 272 211 -122 88 -15 15 35 107 8 -194 -329 -429 -635 -323 -48 -223 -305 -497 -385 -348 -27 -140 -388 -348 -438 -360 -67 -21 74 -66 32 130 221 216 178 198 218 185 182 86 -70 -246 -23 125 436 333 29 -551 -921 -735 -489 -202 -237 -336 -257 -309 -198 44 -15 -116 -285 -473 -155 236 477 628 688 674 605 564 440 111 317 524 829 1248 1373 733 13 -390 -365 184 439 435 365 353 245 68 -39 -319 -688 -644 -679 -748 -1113 -1680 -1771 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