File name: Pandora143s1_LibertyTX_20210726_L2Fit_fout2c12d20210527p1-8.txt File generation date: 20250128T110949.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c12p1-8 Local principal investigator: Yuxuan Wang Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 143 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora143_OF_v2d20210326.txt Instrument calibration file used: Pandora143s1_CF_v12d20210527.txt Level 1 file used: Pandora143s1_LibertyTX_20210726_L1_smca1c12d20210527p1-8.txt Full location name: University of Houston Trailer Short location name: LibertyTX Country of location: United States Location latitude [deg]: 30.0965 Location longitude [deg]: -94.7635 Location altitude [m]: 3 Local noon date: 20210726 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 260 402 Nominal wavelengths inside fitting window [nm]: 305.0723 305.2131 305.3540 305.4948 305.6356 305.7764 305.9172 306.0580 306.1988 306.3395 306.4803 306.6210 306.7617 306.9024 307.0431 307.1838 307.3245 307.4651 307.6058 307.7464 307.8870 308.0276 308.1682 308.3088 308.4494 308.5899 308.7305 308.8710 309.0115 309.1520 309.2925 309.4330 309.5735 309.7139 309.8544 309.9948 310.1352 310.2756 310.4160 310.5564 310.6967 310.8371 310.9774 311.1178 311.2581 311.3984 311.5387 311.6789 311.8192 311.9595 312.0997 312.2399 312.3801 312.5203 312.6605 312.8007 312.9409 313.0810 313.2211 313.3613 313.5014 313.6415 313.7816 313.9216 314.0617 314.2017 314.3418 314.4818 314.6218 314.7618 314.9018 315.0418 315.1817 315.3217 315.4616 315.6015 315.7414 315.8813 316.0212 316.1611 316.3010 316.4408 316.5806 316.7205 316.8603 317.0001 317.1398 317.2796 317.4194 317.5591 317.6988 317.8386 317.9783 318.1180 318.2577 318.3973 318.5370 318.6766 318.8163 318.9559 319.0955 319.2351 319.3747 319.5142 319.6538 319.7933 319.9329 320.0724 320.2119 320.3514 320.4909 320.6303 320.7698 320.9092 321.0487 321.1881 321.3275 321.4669 321.6063 321.7456 321.8850 322.0243 322.1637 322.3030 322.4423 322.5816 322.7209 322.8602 322.9994 323.1387 323.2779 323.4171 323.5563 323.6955 323.8347 323.9739 324.1130 324.2522 324.3913 324.5304 324.6695 324.8086 324.9477 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210726T130537.7Z 7877.545575 172 1 35.79 2 72.09 77.63 79.06 245.65 0.00 1 0.00 1 0 25 7.927e-02 1.161e-02 3.021e-02 3.719e-03 4.138700e-01 1.846931e-03 4.503144e-03 -6.000000e+00 4.451050e-02 230.02 -2.00 3.25 -2.00 318.85 0.00e+00 -9.093175e-04 3.686416e-04 1.360350e-04 -6.000000e+00 1.775550e-03 294.38 -2.00 20.00 -2.00 318.53 0.00e+00 3.207 0.000 302.00 328.00 3 4.9443e+00 5.0163e-03 3.7776e-02 -6.0000e+00 1.1210e-01 4.6289e-02 5.6948e-03 1.9950e-02 -6.0000e+00 1.2212e-01 -1.9491e-02 4.2695e-03 9.9313e-03 -6.0000e+00 7.1654e-02 5.5757e-03 2.2948e-03 2.8836e-03 -6.0000e+00 2.9927e-02 9.2212e-05 -4.9636e-04 1.0083e-04 2.8141e-05 -6.0000e+00 2.0010e-03 -5.8157e-03 -1.4605e-04 12 8 8 10 0 0 8.49 23.92 0.32 -0.00582 -0.00955 9 6 2 8 0 3975.460 19.98 23.92 35.39 27.15 27.26 15.5 921.56 -45116 -33233 -21292 -28227 -13319 -7120 -10891 4311 -8923 -31430 -23202 4958 -7979 -4519 -12532 -4054 15785 -5005 20220 -1101 -11602 14148 9743 -4480 -3080 1146 -5214 6726 7377 -13078 4087 7417 -1770 4970 -8128 -6444 5504 -1389 2190 1702 -891 934 -799 5536 1243 3563 -3893 -1872 495 741 593 380 4389 -675 2752 1744 -1446 70 -1992 -569 -1745 -432 1145 1907 1144 197 -2138 60 215 149 131 2158 1739 1730 -222 389 1799 -19 -3499 578 -3280 -4435 257 -1387 -177 -369 -441 881 910 1221 146 1448 -1203 -1522 -407 166 970 509 366 -370 -914 476 -755 -1282 354 -444 -476 -829 194 486 729 801 561 -652 -733 -998 -400 -749 -979 -1155 199 128 527 671 343 997 354 596 197 -54 805 -144 843 278 783 2346 -39 -273 -291 -1271 -682 114 -1307 -2076 -1523 -911 -1221 -452 -223 -386 153 -405 -1880 -1296 225 -477 -310 -1086 -366 1262 -516 1740 -121 -1440 1375 1027 -586 -429 161 -781 852 881 -1909 565 1112 -321 887 -1527 -1176 987 -311 574 521 -305 330 -296 1965 457 1294 -1496 -705 184 282 242 169 2001 -340 1397 918 -801 38 -1082 -302 -958 -251 716 1272 777 128 -1354 37 142 110 105 1750 1411 1358 -167 267 1134 -12 -2384 427 -2764 -4112 242 -1373 -183 -402 -499 1010 1044 1362 156 1438 -1154 -1454 -409 182 1146 654 495 -499 -1181 570 -869 -1509 439 -572 -634 -1147 279 737 1158 1299 897 -1012 -1082 -1420 -566 -1094 -1502 -1843 317 201 809 1006 498 1404 482 821 289 -84 1305 -241 1421 484 1418 4355 -75 -529 -565 -2442 -1268 205 -2321 SS 20210726T131305.0Z 7877.550752 174 1 35.57 2 70.51 78.45 80.48 246.70 0.00 1 0.00 1 0 25 5.934e-02 9.526e-03 1.910e-02 3.041e-03 3.843001e-01 1.508544e-03 4.197876e-03 -6.000000e+00 3.332718e-02 230.02 -2.00 3.25 -2.00 318.48 0.00e+00 -5.677927e-04 2.712588e-04 1.117577e-04 -6.000000e+00 1.329333e-03 294.38 -2.00 20.00 -2.00 318.16 0.00e+00 2.963 0.000 302.00 328.00 3 4.8763e+00 4.0691e-03 3.4938e-02 -6.0000e+00 8.3938e-02 2.7755e-02 4.5903e-03 1.8475e-02 -6.0000e+00 9.1429e-02 -8.1759e-03 3.2295e-03 9.1479e-03 -6.0000e+00 5.3646e-02 2.8875e-03 1.7176e-03 2.6326e-03 -6.0000e+00 2.2411e-02 1.3035e-04 -8.1672e-05 8.2405e-05 2.5665e-05 -6.0000e+00 1.4975e-03 -6.6182e-03 -9.5504e-05 12 8 8 10 0 0 -13.16 23.92 0.35 -0.00662 -0.00723 11 8 2 8 0 3232.660 20.00 23.92 35.77 27.15 27.26 15.5 923.71 -27321 -20577 -18114 -19296 -17326 -20267 -8806 8540 -21861 -26408 -14598 787 -11272 -7502 -804 1202 6428 -193 4999 -409 -10239 7542 3391 132 2857 -1312 -781 3436 -946 -2345 1541 7478 -455 2708 -3313 -3765 746 1374 646 -1229 832 3027 -1249 1564 -186 1583 -797 -756 -1564 501 434 1849 2477 -239 2203 1349 -1458 185 -1383 916 -866 452 1729 1073 1491 192 -758 -813 -593 -1045 1062 566 2067 665 633 -458 2763 409 -2759 329 -1395 -3963 -426 -1526 -549 -617 -754 446 -462 1103 79 1023 -596 -716 -244 356 639 433 386 262 -542 -288 -965 -209 -331 -388 -696 -421 174 143 884 935 940 -652 -940 -895 -390 -372 -677 -528 -243 -96 747 465 366 510 384 826 668 341 336 136 135 344 -364 2024 363 -35 112 -837 -729 -317 -1253 -1440 -1132 -1011 -1031 -815 -955 -406 386 -1476 -1979 -981 48 -897 -677 -80 130 705 -24 621 -56 -1559 971 470 20 461 -231 -137 549 -149 -378 263 1343 -97 583 -705 -791 165 351 199 -444 322 1203 -529 654 -79 667 -339 -320 -665 215 198 899 1267 -132 1231 778 -879 110 -814 524 -515 284 1164 774 1085 134 -506 -541 -420 -827 884 489 1760 553 497 -335 1836 270 -1969 255 -1206 -3781 -418 -1557 -583 -689 -876 525 -546 1261 86 1046 -585 -696 -250 393 763 558 523 352 -701 -348 -1122 -246 -414 -503 -933 -583 248 216 1390 1499 1479 -998 -1372 -1257 -545 -536 -1021 -828 -384 -150 1133 692 528 715 518 1121 962 520 533 221 223 584 -645 3656 670 -66 211 -1556 -1318 -556 -2170 SS 20210726T132617.2Z 7877.559921 176 1 34.58 2 67.71 79.91 83.01 248.51 0.00 1 0.00 1 0 25 2.712e-02 6.663e-03 9.028e-03 2.000e-03 3.413103e-01 9.935579e-04 3.769110e-03 -6.000000e+00 1.524151e-02 230.02 -2.00 3.25 -2.00 317.91 0.00e+00 1.406607e-04 1.518109e-04 8.187306e-05 -6.000000e+00 6.077210e-04 294.38 -2.00 20.00 -2.00 317.58 0.00e+00 2.613 0.000 302.00 328.00 3 4.5132e+00 2.6539e-03 3.0890e-02 -6.0000e+00 3.8388e-02 -6.0059e-03 2.9735e-03 1.6415e-02 -6.0000e+00 4.1805e-02 -6.0210e-04 1.9357e-03 8.0943e-03 -6.0000e+00 2.4529e-02 1.8374e-04 1.0054e-03 2.3089e-03 -6.0000e+00 1.0253e-02 2.8239e-04 -3.9411e-04 5.4194e-05 2.3052e-05 -6.0000e+00 6.8435e-04 -1.0416e-02 -8.6410e-05 11 9 0 11 8 0 92.27 23.92 0.25 -0.01042 -0.01338 20 14 2 8 0 1728.480 20.00 23.92 36.30 27.15 27.26 15.5 926.82 -18473 -3108 -5794 -4166 -8263 -2514 -6522 247 -8334 -13968 -4375 -2198 -2182 -2747 2340 814 2499 -1477 3083 3594 -1600 6281 2067 -1126 -54 465 -737 502 -1153 -2266 860 2680 -823 402 -3074 -3029 -2113 -1025 -703 136 -706 -52 -85 1623 369 964 -1089 138 -1148 -1286 536 839 1017 771 1740 1184 -163 755 -888 496 -318 770 1826 1088 1286 -184 -639 -1004 139 620 797 641 1194 512 -267 114 134 -651 -1689 -892 -978 -1926 -1024 -1563 -592 -624 -268 422 146 780 -72 385 -391 -1095 -468 30 706 591 481 96 -641 -535 -950 -321 -618 -555 -407 -404 246 464 777 1075 817 155 -492 -688 -192 -623 -552 -89 -278 44 643 518 311 219 31 327 430 406 470 34 -69 -5 462 395 90 24 -192 -327 -205 -409 -652 -1423 -229 -455 -303 -560 -156 -450 18 -747 -1392 -397 -203 -231 -342 322 125 400 -257 539 653 -311 1128 394 -236 -12 107 -172 110 -243 -482 192 647 -224 112 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