File name: Pandora143s1_LibertyTX_20211001_L2Fit_fwvt1c12d20210527p1-8.txt File generation date: 20250128T112127.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c12p1-8 Local principal investigator: Yuxuan Wang Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 143 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora143_OF_v6d20210326.txt Instrument calibration file used: Pandora143s1_CF_v12d20210527.txt Level 1 file used: Pandora143s1_LibertyTX_20211001_L1_smca1c12d20210527p1-8.txt Full location name: University of Houston Trailer Short location name: LibertyTX Country of location: United States Location latitude [deg]: 30.0965 Location longitude [deg]: -94.7635 Location altitude [m]: 3 Local noon date: 20211001 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1684 1833 Nominal wavelengths inside fitting window [nm]: 492.1137 492.2344 492.3551 492.4757 492.5964 492.7170 492.8377 492.9583 493.0788 493.1994 493.3200 493.4405 493.5610 493.6815 493.8020 493.9225 494.0429 494.1634 494.2838 494.4042 494.5246 494.6450 494.7653 494.8856 495.0060 495.1263 495.2466 495.3668 495.4871 495.6073 495.7275 495.8477 495.9679 496.0881 496.2082 496.3284 496.4485 496.5686 496.6887 496.8087 496.9288 497.0488 497.1688 497.2889 497.4088 497.5288 497.6488 497.7687 497.8886 498.0085 498.1284 498.2483 498.3681 498.4879 498.6078 498.7276 498.8473 498.9671 499.0868 499.2066 499.3263 499.4460 499.5657 499.6853 499.8050 499.9246 500.0442 500.1638 500.2834 500.4030 500.5225 500.6420 500.7616 500.8811 501.0005 501.1200 501.2394 501.3589 501.4783 501.5977 501.7171 501.8364 501.9558 502.0751 502.1944 502.3137 502.4330 502.5522 502.6715 502.7907 502.9099 503.0291 503.1483 503.2674 503.3866 503.5057 503.6248 503.7439 503.8630 503.9820 504.1011 504.2201 504.3391 504.4581 504.5770 504.6960 504.8149 504.9339 505.0528 505.1717 505.2905 505.4094 505.5282 505.6470 505.7658 505.8846 506.0034 506.1221 506.2409 506.3596 506.4783 506.5970 506.7156 506.8343 506.9529 507.0715 507.1901 507.3087 507.4273 507.5458 507.6644 507.7829 507.9014 508.0199 508.1383 508.2568 508.3752 508.4936 508.6120 508.7304 508.8487 508.9671 509.0854 509.2037 509.3220 509.4403 509.5586 509.6768 509.7950 509.9132 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20211001T225544.4Z 7944.955375 165 1 48.42 2 76.21 257.51 106.51 307.51 0.00 1 0.00 1 0 15 2.051e-03 2.053e-03 7.218e-04 7.195e-04 1.112846e+04 5.125818e+01 7.182579e+02 -6.000000e+00 1.174500e+02 292.29 -2.00 20.00 -2.00 505.27 0.00e+00 7.552679e-04 2.026818e-05 6.364295e-05 -6.000000e+00 5.875716e-05 292.29 -2.00 20.00 -2.00 500.37 0.00e+00 3.479291e-01 1.426089e-02 6.554946e-02 -6.000000e+00 4.028101e-02 227.70 -2.00 3.25 -2.00 501.97 0.00e+00 4.096 0.001 489.00 513.00 1 6.8758e+00 1.0961e-03 8.2232e-03 -6.0000e+00 3.0980e-03 1.1337e-02 2.8004e-04 1.6094e-03 -6.0000e+00 8.0395e-04 1.0679e-03 -3.8946e-04 6.5810e-05 6.5047e-05 -6.0000e+00 2.0339e-04 4.2260e-02 -2.6100e-05 11 1 0 11 4 0 98.68 17.01 1.74 0.04226 0.03956 20 4 1 2 0 2420.600 15.01 17.01 30.59 19.75 20.56 18.0 899.71 -36 66 -23 69 385 343 141 264 120 104 -58 -92 46 -148 -134 -80 180 -104 0 -143 157 242 257 240 269 231 -79 -235 -106 -139 -97 129 -312 -297 -340 36 -32 80 -59 -32 -52 7 172 42 211 162 59 -16 -204 -412 -252 -225 -131 -82 -209 -290 -72 116 239 428 291 206 139 48 28 105 -34 -243 -175 -31 -194 49 -217 -118 -262 -266 -196 -66 -103 -277 -208 -188 -174 -152 -256 -302 -204 -47 74 135 215 -1 -69 7 219 128 -33 -12 -330 -216 -40 -93 -421 -415 -596 -411 41 284 197 189 44 199 209 460 439 580 390 145 114 161 69 169 172 -75 -169 89 17 -59 -102 -265 -153 138 135 20 177 -10 -137 18 270 129 1 256 222 -12 -158 -180 146 -35 -90 -111 -36 66 -24 72 406 363 151 284 128 109 -60 -96 47 -151 -137 -82 185 -110 0 -153 167 258 274 257 289 247 -84 -245 -109 -141 -98 130 -322 -310 -361 38 -34 84 -62 -33 -54 8 179 44 224 171 61 -17 -209 -418 -253 -221 -129 -81 -209 -298 -74 120 245 437 299 213 143 50 29 107 -34 -241 -174 -31 -190 48 -214 -117 -261 -261 -191 -63 -99 -265 -200 -182 -170 -147 -251 -298 -201 -46 73 132 212 -1 -68 7 211 122 -31 -11 -301 -196 -36 -86 -402 -406 -589 -407 40 273 190 183 44 195 205 452 433 576 386 145 113 159 67 163 165 -73 -164 87 17 -57 -98 -253 -146 130 128 19 167 -9 -131 17 261 127 1 255 218 -12 -155 -178 141 -34 -85 -105 SQ 20211001T234551.1Z 7944.990175 183 1 19.88 2 86.91 264.06 114.36 315.99 0.00 1 0.00 1 0 22 3.581e-03 3.539e-03 1.155e-04 1.152e-04 3.149358e+04 9.432721e+00 1.938418e+03 -6.000000e+00 2.050652e+02 292.29 -2.00 20.00 -2.00 505.37 0.00e+00 2.236375e-03 3.267378e-06 1.663566e-04 -6.000000e+00 1.025941e-04 292.29 -2.00 20.00 -2.00 500.58 0.00e+00 1.132321e+00 2.268018e-03 1.580610e-01 -6.000000e+00 7.036942e-02 227.70 -2.00 3.25 -2.00 502.14 0.00e+00 13.267 0.029 489.00 513.00 1 8.8111e-01 1.7409e-04 2.4029e-02 -6.0000e+00 5.4116e-03 -1.3878e-02 4.3597e-05 4.1764e-03 -6.0000e+00 1.4051e-03 1.0345e-01 1.1556e-03 8.8833e-06 1.5602e-04 -6.0000e+00 3.5533e-04 1.3289e-02 1.2119e-04 11 1 0 11 4 0 48.68 16.99 1.75 0.01329 0.02130 633 125 2 2 0 29.480 14.99 16.99 30.47 19.64 20.56 18.0 899.11 -198 22 242 549 810 879 696 617 540 321 89 -155 -216 -275 -291 -79 21 44 64 143 207 203 281 299 329 254 -19 -244 -336 -394 -466 -346 -115 -236 -231 -108 -77 -262 -267 -219 -150 5 144 220 195 246 120 -154 -378 -604 -657 -688 -550 -362 -244 -104 52 206 367 440 448 348 323 249 182 80 -97 -305 -362 -359 -347 -312 -206 -211 -331 -378 -319 -411 -331 -289 -224 -204 -169 -186 -370 -460 -305 -55 160 332 301 202 185 243 404 373 147 -261 -745 -752 -594 -667 -695 -627 -439 -178 58 219 217 -39 -231 -62 180 506 875 1077 729 235 -9 -159 -113 68 319 365 330 286 247 42 -106 -313 -348 -126 -96 -188 -80 22 -16 278 430 230 164 225 285 395 429 309 16 -201 -322 -223 -190 21 239 550 819 897 712 633 551 328 90 -155 -215 -273 -289 -78 21 45 66 147 214 210 292 310 342 264 -20 -251 -339 -394 -464 -346 -118 -245 -243 -113 -79 -270 -276 -226 -154 5 150 231 205 258 125 -160 -389 -613 -656 -684 -547 -364 -248 -107 54 213 379 455 465 360 334 257 188 82 -99 -309 -363 -357 -344 -311 -208 -214 -335 -377 -314 -402 -324 -281 -218 -200 -166 -183 -369 -456 -303 -54 157 324 293 198 179 233 377 337 131 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19.64 20.56 18.0 899.11 -197 25 292 570 812 899 723 638 571 378 93 -186 -197 -286 -272 -78 25 26 66 108 211 217 299 330 365 254 -37 -271 -384 -459 -485 -356 -127 -232 -228 -93 -87 -267 -264 -221 -147 -17 111 212 197 246 109 -172 -395 -617 -698 -712 -564 -378 -254 -119 58 228 396 462 438 392 319 229 170 82 -107 -312 -378 -361 -331 -283 -196 -219 -348 -378 -335 -405 -312 -260 -246 -212 -183 -153 -346 -457 -283 -68 154 344 316 212 197 254 401 379 161 -267 -722 -758 -585 -680 -733 -636 -450 -185 74 207 218 -63 -236 -53 160 490 855 1055 734 247 -20 -173 -112 59 301 377 337 286 252 47 -119 -288 -341 -162 -135 -225 -73 -15 -22 295 428 226 153 251 297 430 477 330 42 -192 -318 -210 -189 24 287 570 820 916 739 654 581 385 94 -185 -196 -284 -270 -77 25 26 68 112 218 225 311 342 379 263 -38 -278 -387 -458 -483 -356 -130 -240 -239 -97 -90 -275 -273 -228 -151 -18 116 223 207 257 113 -178 -406 -626 -698 -708 -562 -379 -258 -123 60 236 409 477 455 406 331 237 176 83 -108 -317 -380 -359 -329 -283 -196 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