File name: Pandora143s1_LibertyTX_20240120_L2Fit_fout2c8d20230920p1-8.txt File generation date: 20240426T133558.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Yuxuan Wang Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 143 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora143_OF_v1d20230920.txt Instrument calibration file used: Pandora143s1_CF_v8d20230920.txt Level 1 file used: Pandora143s1_LibertyTX_20240120_L1_smca1c8d20230920p1-8.txt Full location name: Sam Houston Regional Library and Research Center Short location name: LibertyTX Country of location: United States Location latitude [deg]: 30.0965 Location longitude [deg]: -94.7635 Location altitude [m]: 3 Local noon date: 20240120 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 7 First and last pixel inside fitting window: 242 384 Nominal wavelengths inside fitting window [nm]: 305.0091 305.1500 305.2909 305.4317 305.5726 305.7134 305.8542 305.9950 306.1358 306.2766 306.4174 306.5581 306.6989 306.8396 306.9803 307.1211 307.2618 307.4025 307.5432 307.6838 307.8245 307.9651 308.1058 308.2464 308.3870 308.5276 308.6682 308.8088 308.9494 309.0900 309.2305 309.3710 309.5116 309.6521 309.7926 309.9331 310.0736 310.2140 310.3545 310.4950 310.6354 310.7758 310.9162 311.0566 311.1970 311.3374 311.4778 311.6181 311.7585 311.8988 312.0392 312.1795 312.3198 312.4601 312.6003 312.7406 312.8809 313.0211 313.1614 313.3016 313.4418 313.5820 313.7222 313.8624 314.0025 314.1427 314.2828 314.4230 314.5631 314.7032 314.8433 314.9834 315.1235 315.2635 315.4036 315.5436 315.6836 315.8237 315.9637 316.1037 316.2437 316.3836 316.5236 316.6635 316.8035 316.9434 317.0833 317.2232 317.3631 317.5030 317.6429 317.7827 317.9226 318.0624 318.2022 318.3421 318.4819 318.6217 318.7614 318.9012 319.0410 319.1807 319.3204 319.4602 319.5999 319.7396 319.8792 320.0189 320.1586 320.2982 320.4379 320.5775 320.7171 320.8567 320.9963 321.1359 321.2755 321.4150 321.5546 321.6941 321.8337 321.9732 322.1127 322.2522 322.3916 322.5311 322.6706 322.8100 322.9494 323.0889 323.2283 323.3677 323.5071 323.6464 323.7858 323.9252 324.0645 324.2038 324.3431 324.4824 324.6217 324.7610 324.9003 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240120T133143.2Z 8785.563695 83 1 48.01 2 87.51 115.07 126.66 349.54 0.00 1 0.00 1 0 49 1.414e+00 6.520e-01 7.065e-01 3.937e-01 -1.746980e-01 2.979286e-01 6.642275e-03 -6.000000e+00 1.039124e+00 224.48 -2.00 3.25 -2.00 313.31 0.00e+00 1.675069e-02 2.159582e-02 2.586127e-04 -6.000000e+00 4.507374e-02 284.75 -2.00 20.00 -2.00 312.69 0.00e+00 14.763 0.039 302.00 328.00 3 -1.8808e+00 7.4822e-01 1.5339e-01 -6.0000e+00 2.6037e+00 1.1791e+00 7.8091e-01 3.5274e-02 -6.0000e+00 2.8007e+00 2.0307e-01 4.6406e-01 9.3310e-03 -6.0000e+00 1.6557e+00 -2.7963e-01 2.2683e-01 4.9595e-03 -6.0000e+00 7.2336e-01 4.2033e-07 -6.5878e-02 1.5807e-02 8.0771e-05 -6.0000e+00 4.7891e-02 -8.5381e-03 0.0000e+00 12 9 8 11 32 0 -15.47 20.64 18.96 -0.00854 -0.50357 12 3 5 8 0 4000.000 19.99 20.64 3.93 24.96 25.28 9.2 934.22 74121 900000 -64937 55036 900000 211054 900000 -42711 71951 14215 350138 -7687 900000 76056 900000 900000 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900000 24784 900000 -33423 900000 900000 900000 900000 900000 38898 900000 900000 900000 21253 6329 900000 -860 900000 31978 900000 900000 900000 900000 53324 900000 51102 -47137 900000 900000 900000 900000 41448 900000 900000 -69599 900000 13740 900000 -31315 45265 35952 900000 14086 900000 66729 11368 900000 900000 900000 303 900000 900000 48004 101780 -102644 900000 140840 900000 21356 900000 34140 131069 -20257 900000 4846 57664 55149 54657 900000 900000 900000 900000 900000 3066 -97964 -38797 14560 900000 900000 900000 50918 32984 75675 900000 44315 40103 6521 20757 52291 900000 63465 900000 900000 900000 222136 900000 19618 15562 900000 900000 94301 -157864 51653 900000 55725 900000 61683 50321 50204 51884 50119 900000 61598 -70000 -2009 39264 -43727 107893 71412 20153 SS 20240120T134223.9Z 8785.571110 89 1 48.01 2 85.43 116.47 126.98 352.44 0.00 1 0.00 1 0 33 1.193e+00 2.332e-01 4.753e-01 1.012e-01 5.833780e-01 5.814313e-02 6.184233e-03 -6.000000e+00 7.100237e-01 224.48 -2.00 3.25 -2.00 319.24 0.00e+00 -2.820007e-02 9.186539e-03 4.758615e-03 -6.000000e+00 3.683768e-02 284.75 -2.00 20.00 -2.00 317.84 0.00e+00 10.468 0.014 302.00 328.00 3 2.9298e-01 1.5988e-01 1.1668e-01 -6.0000e+00 1.7797e+00 1.9301e+00 1.8931e-01 7.5558e-02 -6.0000e+00 1.9615e+00 -1.4169e+00 1.0564e-01 1.4098e-02 -6.0000e+00 1.1493e+00 2.7509e-01 5.2468e-02 1.9348e-02 -6.0000e+00 5.0301e-01 4.9397e-06 1.0475e-02 3.2389e-03 2.2788e-04 -6.0000e+00 3.4161e-02 -1.0391e-02 0.0000e+00 12 9 8 11 32 0 12.17 20.63 1.29 -0.01039 0.06833 12 3 5 8 0 4000.000 20.00 20.63 4.50 24.96 25.28 9.1 939.38 900000 900000 41127 900000 -5229 75561 52908 -52238 900000 -3665 900000 75775 263802 -15627 171538 417650 -11833 900000 900000 900000 193432 900000 -16094 306355 6686 900000 -1246 900000 900000 900000 900000 900000 900000 900000 900000 -11981 900000 14623 900000 69623 368885 90261 92749 421318 10149 900000 8686 900000 9128 900000 168023 365291 105367 97289 308235 251417 900000 -36897 900000 -424 900000 -30085 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12376 900000 5470 21272 -16212 24807 -5359 900000 15370 20130 3028 4648 21629 15489 18861 17709 26431 -30573 3839 -25827 9839 17428 22089 -69542 -3199 -4023 1048 30400 -15483 27358 -10862 14398 -9982 48857 -25638 44814 17362 23863 31685 -641 4664 -5249 49625 21643 38045 -65026 19488 21592 -3725 25473 8706 27255 -27649 9989 -34250 51907 -8871 9755 -10505 777 -33062 14350 25668 -8323 SS 20240120T142018.5Z 8785.597436 95 1 47.54 2 78.27 121.80 127.21 2.86 0.00 1 0.00 1 0 17 1.562e-01 4.637e-03 6.642e-02 1.422e-03 5.636115e-01 7.180951e-04 6.003587e-03 -6.000000e+00 8.529394e-02 224.48 -2.00 3.25 -2.00 320.41 0.00e+00 1.529789e-03 2.768319e-04 3.027652e-04 -6.000000e+00 3.836052e-03 284.74 -2.00 20.00 -2.00 319.78 0.00e+00 4.760 0.001 302.00 328.00 3 1.7915e-01 2.2016e-03 5.4452e-02 -6.0000e+00 2.1053e-01 5.3131e-03 2.8464e-03 2.7365e-02 -6.0000e+00 2.2890e-01 -4.1709e-03 2.7706e-03 1.4250e-02 -6.0000e+00 1.3671e-01 -5.1875e-03 1.4026e-03 5.0767e-03 -6.0000e+00 6.0202e-02 2.1407e-03 4.9083e-05 3.6471e-05 4.2472e-05 -6.0000e+00 3.7668e-03 -1.0401e-02 0.0000e+00 10 0 0 10 0 0 18.63 20.62 0.20 -0.01040 -0.01003 226 59 5 8 0 210.340 20.00 20.62 6.76 24.96 25.28 9.2 959.00 900000 11168 -42211 -45108 51046 -51052 -46983 -80688 -53092 -45828 -49708 -56468 -38177 -31207 -12561 -28752 -17866 -8855 9382 -7132 736 -3891 -6454 -7968 -12571 931 -7624 1160 -4446 -3211 -6025 2747 791 5708 1263 -3644 -4425 -2179 763 -1145 -56 -1710 -469 -2547 260 805 104 1534 -679 -940 913 1372 707 1198 669 1618 1301 -370 1403 -735 773 414 945 2111 1836 -293 1150 -848 -840 842 848 1094 169 76 592 -20 -238 -925 -835 35 -450 -940 -1477 -1886 -1300 -1124 -61 62 148 645 841 859 644 329 426 299 -89 432 692 22 137 -415 -870 -295 -127 -639 -412 -657 -606 -8 141 418 258 127 29 -122 381 108 171 -49 -363 -241 127 182 89 449 -164 319 567 255 122 -232 -398 -224 -164 -7 -284 270 362 82 156 -214 -322 900000 46 -333 -375 149 -382 -352 -984 -581 -521 -613 -783 -529 -519 -221 -663 -423 -211 205 -196 20 -110 -189 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