File name: Pandora143s1_LibertyTX_20240415_L2Fit_fwvt1c8d20230920p1-8.txt File generation date: 20240426T125917.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c8p1-8 Local principal investigator: Yuxuan Wang Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 143 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora143_OF_v1d20230920.txt Instrument calibration file used: Pandora143s1_CF_v8d20230920.txt Level 1 file used: Pandora143s1_LibertyTX_20240415_L1_smca1c8d20230920p1-8.txt Full location name: Sam Houston Regional Library and Research Center Short location name: LibertyTX Country of location: United States Location latitude [deg]: 30.0965 Location longitude [deg]: -94.7635 Location altitude [m]: 3 Local noon date: 20240415 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 7 First and last pixel inside fitting window: 1663 1812 Nominal wavelengths inside fitting window [nm]: 492.1080 492.2291 492.3501 492.4712 492.5922 492.7133 492.8343 492.9552 493.0762 493.1972 493.3181 493.4390 493.5599 493.6808 493.8017 493.9225 494.0434 494.1642 494.2850 494.4058 494.5265 494.6473 494.7680 494.8887 495.0094 495.1301 495.2508 495.3714 495.4921 495.6127 495.7333 495.8539 495.9744 496.0950 496.2155 496.3361 496.4566 496.5770 496.6975 496.8180 496.9384 497.0588 497.1792 497.2996 497.4199 497.5403 497.6606 497.7809 497.9012 498.0215 498.1418 498.2620 498.3823 498.5025 498.6227 498.7429 498.8630 498.9832 499.1033 499.2234 499.3435 499.4636 499.5836 499.7037 499.8237 499.9437 500.0637 500.1837 500.3037 500.4236 500.5435 500.6634 500.7833 500.9032 501.0231 501.1429 501.2627 501.3826 501.5023 501.6221 501.7419 501.8616 501.9813 502.1010 502.2207 502.3404 502.4601 502.5797 502.6993 502.8189 502.9385 503.0581 503.1776 503.2972 503.4167 503.5362 503.6557 503.7752 503.8946 504.0140 504.1335 504.2529 504.3723 504.4916 504.6110 504.7303 504.8496 504.9689 505.0882 505.2075 505.3267 505.4459 505.5652 505.6843 505.8035 505.9227 506.0418 506.1610 506.2801 506.3992 506.5182 506.6373 506.7563 506.8754 506.9944 507.1134 507.2323 507.3513 507.4702 507.5892 507.7081 507.8270 507.9458 508.0647 508.1835 508.3023 508.4211 508.5399 508.6587 508.7774 508.8962 509.0149 509.1336 509.2523 509.3709 509.4896 509.6082 509.7268 509.8454 509.9640 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240415T130703.8Z 8871.546571 93 1 4.92 2 74.63 87.13 123.22 10.83 0.00 1 0.00 1 0 22 1.860e-03 1.853e-03 1.296e-04 1.295e-04 6.562293e+03 8.679677e+00 4.468033e+02 -6.000000e+00 1.072578e+02 287.87 -2.00 20.00 -2.00 505.29 0.00e+00 5.836744e-04 3.641666e-06 4.493454e-05 -6.000000e+00 5.320399e-05 287.87 -2.00 20.00 -2.00 500.54 0.00e+00 2.136941e-01 2.574075e-03 4.315198e-02 -6.000000e+00 3.714289e-02 229.48 -2.00 3.25 -2.00 502.12 0.00e+00 3.703 0.001 489.00 513.00 1 1.3182e+00 1.9772e-04 6.5464e-03 -6.0000e+00 2.8554e-03 -9.3459e-03 5.0353e-05 1.0787e-03 -6.0000e+00 7.3628e-04 2.9828e-01 3.8194e-04 1.3105e-05 4.7121e-05 -6.0000e+00 1.9821e-04 1.9415e-03 -1.8071e-04 10 0 0 10 0 0 91.37 27.22 1.18 0.00194 0.00459 498 498 1 2 0 9.860 20.01 27.22 27.40 25.79 26.00 12.8 1084.28 -90 -116 -44 42 118 335 373 313 371 210 205 106 -20 -46 -71 -93 -92 73 11 -135 7 132 111 194 227 96 71 115 -82 -241 -66 -107 -58 99 -76 -211 -58 21 -62 -55 19 15 36 154 150 145 100 2 -60 -218 -355 -369 -432 -292 -166 -186 -180 -110 57 150 247 229 138 147 120 65 -52 -70 -110 -244 -203 -165 -176 -91 -110 -312 -296 -153 -76 -207 -231 -212 -243 -84 -71 -131 -88 -79 -32 39 52 171 235 117 72 75 -51 -95 -157 -393 -369 -367 -253 -141 -340 -375 -212 -115 -21 91 23 30 129 245 298 370 462 324 189 180 190 102 217 274 71 82 215 79 131 229 48 -58 44 -17 -11 157 64 -81 72 136 74 191 226 104 63 -26 -148 -271 -291 -217 -88 -112 -43 43 120 347 384 325 383 215 211 107 -20 -45 -71 -93 -93 74 11 -139 7 136 115 202 237 100 73 120 -83 -243 -66 -107 -59 100 -79 -221 -61 22 -63 -55 19 16 37 160 154 149 104 2 -61 -219 -354 -361 -420 -288 -165 -186 -184 -113 58 154 253 235 142 152 122 65 -52 -69 -108 -239 -198 -161 -174 -91 -108 -311 -290 -148 -74 -202 -222 -205 -238 -83 -69 -129 -87 -78 -31 38 51 172 234 116 72 73 -49 -91 -148 -367 -346 -352 -247 -140 -338 -375 -210 -113 -21 89 23 30 128 245 299 374 469 330 191 180 190 101 214 270 70 82 214 78 130 226 47 -56 43 -16 -11 152 63 -80 72 137 74 191 228 105 63 -26 -148 -266 -283 -211 SQ 20240415T130708.8Z 8871.546629 93 2 4.95 2 74.62 87.14 123.22 10.85 0.00 1 0.00 1 0 22 1.858e-03 1.849e-03 1.301e-04 1.300e-04 6.565976e+03 8.716497e+00 4.461484e+02 -6.000000e+00 1.071932e+02 287.87 -2.00 20.00 -2.00 505.28 0.00e+00 5.916053e-04 3.654688e-06 4.533854e-05 -6.000000e+00 5.317191e-05 287.87 -2.00 20.00 -2.00 500.53 0.00e+00 2.134540e-01 2.582364e-03 4.306499e-02 -6.000000e+00 3.712046e-02 229.48 -2.00 3.25 -2.00 502.11 0.00e+00 3.699 0.001 489.00 513.00 1 1.3269e+00 1.9838e-04 6.5395e-03 -6.0000e+00 2.8537e-03 -9.6063e-03 5.0519e-05 1.0754e-03 -6.0000e+00 7.3584e-04 2.9585e-01 3.9065e-04 1.3169e-05 4.7398e-05 -6.0000e+00 1.9809e-04 1.9306e-03 -1.8057e-04 10 0 0 10 0 0 56.07 27.22 1.18 0.00193 0.00464 498 498 1 2 0 9.860 20.01 27.22 27.40 25.79 26.00 12.8 1084.28 -93 -143 -31 50 105 357 367 320 364 200 197 117 -5 -72 -100 -94 -91 51 40 -139 -14 151 113 216 246 124 51 99 -104 -227 -76 -155 -36 119 -68 -215 -58 11 -71 -48 -7 26 65 170 137 160 97 31 -50 -210 -336 -343 -429 -287 -157 -199 -170 -115 49 117 256 206 158 114 109 52 -33 -28 -75 -258 -224 -173 -204 -92 -128 -293 -306 -145 -85 -216 -216 -201 -222 -102 -62 -163 -85 -57 -33 28 41 174 220 95 99 104 -58 -111 -184 -382 -387 -368 -221 -141 -389 -339 -206 -101 -12 87 57 19 143 217 302 344 439 366 181 163 173 118 210 306 69 88 195 112 116 258 66 -90 43 -13 16 162 58 -74 63 131 99 174 189 108 62 -32 -163 -265 -289 -212 -90 -138 -31 50 106 368 377 330 375 204 202 118 -5 -72 -101 -93 -92 52 41 -146 -15 158 116 223 255 129 53 103 -106 -228 -75 -155 -36 123 -71 -225 -60 11 -73 -50 -7 27 66 176 143 168 101 31 -51 -210 -334 -334 -416 -281 -155 -202 -173 -117 50 119 261 211 163 117 110 52 -33 -28 -73 -252 -217 -169 -201 -91 -129 -291 -299 -142 -83 -210 -210 -194 -216 -101 -61 -160 -84 -56 -32 28 40 174 222 96 98 102 -55 -106 -173 -355 -361 -352 -214 -139 -385 -338 -203 -100 -12 87 57 20 144 217 302 346 445 371 183 162 172 116 206 301 68 87 193 111 114 254 64 -86 41 -12 15 156 57 -73 63 131 99 175 190 109 63 -32 -163 -259 -285 -209 SQ 20240415T130713.8Z 8871.546687 93 3 4.95 2 74.60 87.15 123.21 10.87 0.00 1 0.00 1 0 22 1.854e-03 1.849e-03 1.296e-04 1.294e-04 6.537206e+03 8.692941e+00 4.448937e+02 -6.000000e+00 1.069449e+02 287.87 -2.00 20.00 -2.00 505.29 0.00e+00 5.975263e-04 3.642077e-06 4.519887e-05 -6.000000e+00 5.304900e-05 287.87 -2.00 20.00 -2.00 500.53 0.00e+00 2.180580e-01 2.574199e-03 4.308754e-02 -6.000000e+00 3.703610e-02 229.48 -2.00 3.25 -2.00 502.11 0.00e+00 3.695 0.001 489.00 513.00 1 1.3176e+00 1.9772e-04 6.5340e-03 -6.0000e+00 2.8472e-03 -9.5900e-03 5.0327e-05 1.0758e-03 -6.0000e+00 7.3420e-04 2.9867e-01 4.7992e-04 1.3115e-05 4.6691e-05 -6.0000e+00 1.9764e-04 1.9312e-03 -1.8423e-04 10 0 0 10 0 0 15.59 27.22 1.18 0.00193 0.00526 498 498 1 2 0 9.860 20.01 27.22 27.40 25.79 26.00 12.8 1084.28 -118 -151 -38 30 111 344 361 316 332 220 179 117 7 -76 -79 -78 -60 66 1 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